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    • 专利摘要:
    Mixture, Agrochemical Composition, Composition Preparation Set, Method for Control of Fungi and Plant Spread Material "The present invention relates to pesticide mixtures which comprise as active components the strain bacillus amy / oliquefaciens ssp. plantarum tj1000 and a pesticide as defined herein and their respective agricultural uses.
    公开号:BR102015011907A2
    申请号:R102015011907-0
    申请日:2015-05-22
    公开日:2018-01-23
    发明作者:Jabs Thorsten；Ranuva Giridhar；Filajdic Nenad
    申请人:Basf Se；
    IPC主号:
    专利说明:

    (54) Title: MIXTURE, AGRICULTURAL COMPOSITION, ASSEMBLY FOR THE PREPARATION OF A COMPOSITION, METHOD FOR THE CONTROL OF FUNGI AND VEGETABLE ADVERTISING MATERIAL (51) Int. Cl .: A01N 63/00; A01N 47/24; A01N 43/54; A01N 37/50; A01N 43/56; (...) (52) CPC: A01N 63/00, A01N 2300/00, A01N 47/24, A01N 43/54, A01N 37/50, A01N 43/56, A01N 43/40, A01N 43/653, A01N 43/78, A01N 47/12, A01N 47/02, A01N 51/00 (30) Unionist Priority: 01/07/2014 EP 14175145.3, 01/07/2014 EP 14175145.323 / 05/2014 US 62 / 002,204, 01 / 07/2014 EP 14175145.323 / 05/2014 US 62/002, 20426/05/2014 US 62 / 002,947 (73) Holder (s): BASF SE (72) Inventor (s): THORSTEN JABS; GIRIDHAR RANUVA; NENAD FILAJDIC (74) Attorney (s): PAOLA CALABRIA MATTIOLI DANTAS (57) Abstract: MIXTURE, AGRICULTURAL COMPOSITION, SET FOR THE PREPARATION OF A COMPOSITION, METHOD FOR THE CONTROL OF FUNGI AND VEGETABLE PROPAGATION MATERIAL The present invention refers to mixtures of pesticides comprising, as active components, the strain Bacillus amy / oliquefaciens ssp. plantarum TJ1000 and a pesticide, as defined herein, and their respective agricultural uses.
    1/79 “MIXTURE, AGRICULTURAL COMPOSITION, ASSEMBLY FOR THE PREPARATION OF A COMPOSITION, METHOD FOR THE CONTROL OF FUNGI AND VEGETABLE PROPAGATION MATERIAL” Field of the Invention [001] The present invention refers to mixtures that comprise, as active components, the Bacillus amyloliquefaciens ssp. plantarum TJ1000 and a pesticide.
    Background of the Invention [002] This microorganism of the strain B. amyloliquefaciens ssp. plantarum TJ1000 (also called strain 1 BE; obtained from American Type Culture Collection PO Box 1549, Manassas, VA 20108 USA under accession number ATCC BAA-390) is known for the QuickRoots® product from TJ Technologies, Watertown, SD, USA as microbial seed inoculant to increase production and intensify seed germination. Mixtures of this strain with a Trichderma virens GI-3 strain are known from WO 2013/158900 and CA 2471555 A1. B. amyliquefaciens ssp. plantarum TJ1000 was previously classified as B. subtilis or B. amyloliquefaciens.
    [003] A pesticide, in general, is a chemical or biological agent (such as a virus, bacterium, antimicrobial or disinfectant), which through its effect deters, disables, kills or otherwise discourages pests. Target pests can include insects, plant pathogens, weeds, mollusks, birds, mammals, fish, nematodes (worms), and microbes that destroy properties, cause discomfort, spread disease or are vectors of diseases.
    [004] Biopesticides have been defined as a form of pesticides based on microorganisms (bacteria, fungi, viruses, nematodes, and the like) or natural products (compounds, such as metabolites,
    2/79 proteins or extracts from natural biological or other sources) (U.S. Environmental Protection Agency: http://www.epa.gov/pesticides/biopesticides/). Biopesticides are found in two main classes of microbial and biochemical pesticides:
    (1) microbial pesticides consist of bacteria, fungi or viruses (and often include the metabolites that bacteria and fungi produce).
    (2) biochemical pesticides are naturally occurring substances or structurally or functionally similar and identical to a naturally occurring substance and extracted from biological sources that control pests or provide other crop protection uses, as defined below, but which they have a non-toxic mode of action and are relatively non-toxic to mammals.
    [005] Biopesticides for use against crop diseases have established themselves in a variety of cultures. For example, biopesticides play an important role in controlling downy mildew diseases. Its advantages include: a pre-harvest interval of Day 0, the ability to use under moderate to severe pressure of the disease, and the ability to use in a mixture or in a rotation program with other registered pesticides.
    [006] However, under certain conditions, biopesticides can also have disadvantages such as high specificity: which may require exact identification of the pest / pathogen and the use of multiple products to be used, the slow speed of action ( making them unsuitable if an outbreak of pests is an immediate threat to a crop), the variable efficacy, due to the influences of several biotic and abiotic factors (since biopesticides are living organisms, which present pest control / pathogen multiplying within the
    3/79 insect pest / target pathogen) and the development of resistance.
    [007] Practical agricultural experience has shown that repeated and exclusive application of an individual active compound to control fungi or insects or other harmful pests, in many cases, leads to a rapid selection of those fungal strains or isolated pests that have developed natural resistance or adapted against the active compound in question. Effective control of these fungi, insects or other pests with the active component in question, therefore, is no longer possible. Another typical problem that arises in the field of pest control is the need to reduce the dosage rates of the active ingredient in order to reduce or avoid unfavorable environmental or toxicological effects, while still allowing effective pest control.
    Brief Description of the Invention [008] It is an object of the present invention to overcome the disadvantages mentioned above and provide, with the objective of effectively managing the resistance and effective control of harmful phytopathogenic fungi, insects and other pests or for the regulation of effective plant growth, with application rates that are as low as possible, compositions that, in a reduced total amount of the active compounds applied, enhance the activity against harmful fungi, insects or other pests or enhance the activity of growth regulation vegetables (synergistic mixtures) and a broad spectrum of activity, especially for certain indications.
    [009] This is especially noticeable if the application rates for the pesticide mixtures mentioned above are used on individual components that have no activity or virtually no activity. The present invention can also result in advantageous behavior during formulation or during use, for example, during
    4/79 grinding, sifting, emulsifying, dissolving or dispensing; improved storage stability and light stability; advantageous residue formation; improved toxicological or ecotoxicological behavior; improved plant properties, for example, better growth, increased crop yield, a more developed root system, larger leaf area, greener leaves, stronger shoots, less seeds needed, less phytotoxicity, mobilization of the plant's defense system , good compatibility with vegetables.
    Detailed Description of the Invention [010] It was therefore an object of the present invention to provide mixtures of pesticides that solve the problems of reducing the dose rate and / or increasing the spectrum of activity and / or combining the activity of reduction with the prolonged control and / or the administration of resistance and / or promotion (increasing) of the health of vegetables.
    [011] Accordingly, it has been discovered that this object is achieved by the mixtures and compositions defined in the present, which comprise the B. amyloliquefaciens ssp. plantarum TJ1000.
    [012] Accordingly, the present invention relates to mixtures comprising, as active components (1) the strain B. amyloliquefaciens ssp. plantarum TJ1000 (ATCC
    BAA-390);
    and (2) at least one pesticide II from groups (A) to (O) selected from:
    (A) Breathing inhibitors
    - Complex III inhibitors at site Q o selected from: azoxystrobin (A. 1.1), coumetoxistrobin (A. 1.2), coumoxystrobin (A. 1.3), dimoxystrobin (A. 1.4), enestroburin (A. 1.5), phenaminstrobin (A. 1.6),
    5/79 phenoxystrobin / fluphenoxystrobin (A. 1.7), fluoxastrobin (A. 1.8), cresoxim-methyl (A. 1.9), mandestrobin (A. 1.10), metominostrobin (A. 1.11), orisastrobin (A. 1.12), picoxystrobin (A. 1.13), pyraclostrobin (A. 1.14), pyrametostrobin (A. 1.15), piraoxystrobin (A. 1.16), trifloxystrobin (A. 1.17), 2- (2- (3- (2,6-dichlorophenyl) - 1-methyl-alliliden-aminooxy-methyl) -phenyl) -2-methoxyimino-N-methylacetamide (A.1.18), pyribencarb (A.1.19), triclopiricarb / chlorodincarb (A.1.20), famoxadone (A.1.21), phenamidone (A.1.21), methyl-N- [2 - [(1,4-dimethyl-5-phenylpyrazol-3-yl) oxylmethyl] phenyl] -N-methoxy-carbamate (A. 1.22), 1- [3 -chloro-2 - [[[1- (4chlorophenyl) -1H-pyrazol-3-yl] oxy] methyl] phenyl] -1,4-dihydro-4-methyl-5H-tetrazol-5-one (A. 1.23 ), (2E, 3Z) -5 - [[1 - (2,4-dichlorophenyl) -1 H-pyrazol-3-yl] oxy] -2- (methoxyimino) -N, 3dimethyl-pent-3-enamide ( A. 1.24), (2E, 3Z) -5 - [[1 - (4-chloro-phenyl) -1 H-pyrazol-3-yl] oxy] 2- (methoxymin) -N, 3-dimethyl-pent- 3-enamide (A.1.25);
    - complex III inhibitors at the Q site, selected from: cyazofamide (A.2.1), amisulbrom (A.2.2), [(3S, 6S, 7R, 8R) 8-benzyl-3 - [(2S, 6S, 7R, 8R) 3-acetoxy-4-methoxy-pyridine-2-carbonyl) amino] -6-methyl-4,9-dioxo-1,5di-oxonan-7-yl] (A.2.3), 2-methylpropanoate [(3S, 6S, 7R, 8R-8-benzyl-3 - [[3 (acetoxymethoxy) -4-methoxy-pyridine-2-carbonyl] amino] -6-methyl-4,9-dioxo-1,5dioxonan-7-yl] (A.2.4), 2-methylpropanoate [(3S, 6S, 7R, 8R) -8-benzyl-3 - [(3-isobutoxycarbonyloxy-4-methoxy-carbonyl-2-pyridin) amino] -6-methyl-4 , 9-dioxo-1,5dioxonan-7-yl] (A.2.5), 2-methyl-propanoate [(3S, 6S, 7R, 8R) -8-benzyl-3 - [[3- (1,3benzodioxol- 5-ylmethoxy) -4-methoxy-pyridin-2-carbonyl] amino] -6-methyl-4,9-dioxo1,5-dioxonan-7-yl] (A.2.6); (3S, 6S, 7R , 8R) -3 - [[((3-hydroxy-4-methoxy-2pyridinyl) carbonyl] -amino] -6 methyl-4,9-dioxo-8- (phenyl-methyl) -1,5-dioxonan-7- yl-2methylpropanoate (A.2.7);
    - Complex II inhibitors selected from: benodanil (A.3.1), benzovindiflupir (A.3.2), bixafen (A.3.3), boscalide (A.3.4), carboxine (A.3.5), fenfuram (A.3.6 ), fluopyram (A.3.7), flutolanil (A.3.8), fluxpyroxad (A.3.9), furametpir (A.3.10), isofetamid (A.3.11), isopirazam (A.3.12), mepronil
    6/79 il) pyrazol-4-carboxamide, il) pyrazol-4-carboxamide il) pyrazol-4-carboxamide (A. 3.13), oxycarboxine (A.3.14), penflufen (A.3.14), pentiopirad (A .3.15), silkxane (A.3.16), keyboardoftalam (A.3.17), tifluzamide (A.3.18), N- (4'trifluoromethylthiobiphenyl-2-yl) -3-difluoromethyl-1-methyl-1H-pyrazol-4 -carboxamide (A.3.19), N- (2- (1,3,3-trimethyl-butyl) -phenyl) -1,3-dimethyl-5-fluoro-1 H-pyrazol-4carboxamide (A.3.20) , 3- (difluoromethyl) -1-methyl-N- (1,1,3-trimethylindan-4-yl) pyrazol4-carboxamide (A.3.21), 3- (trifluoromethyl) -1-methyl-N- (1, 1,3-trimethylindan-4yl) pyrazol-4-carboxamide (A.3.22), 1,3-dimethyl-N- (1,1,3-trimethylindan-4-yl) pyrazol4-carboxamide (A.3.23), 3 - (trifluoromethyl) -1,5-dimethyl-N- (1,1,3-trimethylindan-43- (difluoromethyl) -1,5-dimethyl-N- (1,1,3-trimethylindan-4 (A.3.24 ), 1,3,5-trimethyl-N- (1,1,3-trimethylindan-4 (A.3.25), N- (7-fluoro-1,1,3-trimethyl-indan-4-yl) - 1,3dimethyl-pyrazol-4-carboxamide (A.3.26), N- [2- (2,4-dichlorophenyl) -2-methoxy-1-methylethyl] -3- (difluoromethyl) -1-methyl-pyrazole-4 -carboxamide (A.3.2 7);
    - other breath inhibitors selected from:
    diflumetorim (A.4.1), (5,8-difluoro-quinazolin-4-yl) - {2- [2-fluoro-4- (4trifluoromethylpyridin-2-yloxy) -phenyl] -ethyl} -amine (A.4.2 ); nitrophenyl derivatives: binapacril (A.4.3), dinobutone (A.4.4), dinocap (A.4.5), fluazinam (A.4.6); ferimzone (A.4.7); organometallic compounds: phentin salts, such as phentin acetate (A.4.8), phentin chloride (A.4.9) or fentin hydroxide (A.4.10); ametoctradin (A.4.11); and siltiofam (A.4.12);
    (B) sterol biosynthesis inhibitors (SBI fungicides)
    - C14 demethylase inhibitors (DMI fungicides) selected from; triazoles: azaconazole (B.1.1), bitertanol (B.1.2), bromuconazole (B.1.3), cyproconazole (B.1.4), diphenoconazole (B.1.5), diniconazole (B.1.6), diniconazole-M (B. 1.7), epoxiconazole (B.1.8), fenbuconazole (B.1.9), fluquinconazole (B.1.10), flusilazole (B.1.11), flutriafol (B.1.12), hexaconazole (B.1.13), imibenconazole (B.1.14) ), ipconazole (B.1.15), metconazole (B.1.17), myclobutanil (B.1.18), oxpoconazole (B.1.19), paclobutrazol (B.1.20),
    7/79 penconazole (B.1.21), propiconazole (B.1.22), protioconazole (B.1.23), simeconazole (B.1.24), tebuconazole (B.1.25), tetraconazole (B.1.26), triadimefon (B.1.27) ), triadimenol (B.1.28), triticonazole (B.1.29), uniconazole (B.1.30), 1- [re / (2S, 3 / ) - 3- (2-chlorophenyl) -2- (2,4 -difluorophenyl) -oxyranylmethyl] -5-thiocyanate-1H [1,2,4] triazole (B. 1.31), 2- [re / - (2S, 3 / ) - 3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiranyl-methyl] -2H- [1,2,4] triazole-3-thiol (B.1.32), 2- [2-chloro-4- (4-chloro-phenoxy) phenyl] -1 - (1,2,4-triazol-1-yl) pentan-2-ol (B. 1.33), 1 - [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1-cyclopropyl- 2- (1,2,4-triazol-1-yl) ethanol (B.1.34), 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl-yl) -phenyl] -1 - (1,2 , 4-triazol-1-yl) butan-2-ol (B.1.35), 2- [2chloro-4- (4-chlorophenoxy) phenyl] -1- (1,2,4-triazol-1-yl) butan-2-ol (B.1.36), 2- (4- (4chloro-phenoxy) -2- (trifluoromethyl) phenyl] -3-methyl-1 - (1,2,4-triazol-1-yl) butan -2-ol (B. 1.37), 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) -phenyl] -1 - (1,2,4-triazol-1 yl) propan-2-ol ( B. 1.38), 2 - [(4-chlorine phenoxy) phenyl-4-chloro-2] -3-methyl-1 - (1,2,4-triazol1 -yl) butan-2-ol (B.1.39), 2- [4- (4-chlorophenoxy) - 2- (trifluoromethyl) -phenyl] -1 - (1,2,4triazol-1-yl) pentan-2-ol (B. 1.40), 2- [4- (4-fluorophenoxy) -2- (trifluoromethyl) -phenyl] -1 (1,2,4-triazol-1-yl) propan-2-ol (B. 1.41)), 2 - [2-chloro-4- (4-chlorophenoxy) phenyl] -1 (1,2,4-triazol-1-yl) pent-3-in-2-ol (B.1.51); imidazoles: imazalil (B.1.42), pefurazoate (B.1.43), prochloraz (B.1.44), triflumizole (B.1.45); pyrimidines, pyridines and piperazines: fenarimol (B.1.46), nuarimol (B.1.47), pirifenox (B.1.48), triforin (B.1.49), [3- (4-chloro-2-fluoro-phenyl) -5- (2,4-difluorophenyl) isoxazol-4-yl] - (3-pyridyl) methanol (B.1.50);
    - Delta14 reductase inhibitors selected from: aldimorf (B.2.1), dodemorf (B.2.2), dodemorfacetate (B.2.3), fenpropimorf (B.2.4), tridemorf (B.2.5), phenpropidine (B. 2.6), piperalin (B.2.7), spiroxamine (B.2.8);
    - 3-keto reductase inhibitors: fenhexamide (B.3.1);
    (C) Nucleic acid synthesis inhibitors
    - phenylamide or acyl amino acid fungicides
    8/79 selected from: benalaxyl (C.1.1), benalaxyl-M (C.1.2), chiralaxyl (C.1.3), metalaxyl (C.1.4), metalaxyl-M (mefenoxam, C.1.5), ofurace (C.1.6), oxadixyl (C.1.7);
    - others selected from: himexazole (C.2.1), octylinone (C.2.2), oxolinic acid (C.2.3), bupyrime (C.2.4), 5-fluorocytosine (C.2.5), 5fluoro-2- ( p-tolylmethoxy) pyrimidin-4-amine (C.2.6), 5-fluoro-2- (4 fluorophenylmethoxy) pyrimidin-4-amine (C.2.7);
    (D) Cell division and cytoskeleton inhibitors
    - Tubulin inhibitors selected from: benomyl (D1.1), carbendazim (D1.2), fuberidazole (D1.3), thiabendazole (D1.4), thiophanate-methyl (D1.5); triazolopyrimidines: 5-chloro-7- (4-methyl-piperidin-1-yl) -6- (2,4,6-trifluorphenyl) [1,2,4] triazole [1,5-a] pyrimidine (D1. 6);
    - Inhibitors of another cell division selected from: dietofencarb (D2.1), etaboxam (D2.2), pencicurone (D2.3), fluopicolid (D2.4), zoxamide (D2.5), metrafenone (D2. 6), pyriophenone (D2.7);
    (E) Inhibitors of the synthesis of amino acids and proteins
    - Inhibitors of methionine synthesis (anilino-pyrimidines) selected from: ciprodinil (E.1.1), mepanipirim (E.1.2), pyrimethanil (E.1.3):
    - Protein synthesis inhibitors selected from: blasticidin-S (E.2.1), casugamycin (E.2.2), casugamycin hydrochloride hydrate (E.2.3), mildiomycin (E.2.4), streptomycin (E.2.5) ), oxytetracycline (E.2.6), polyoxin (E.2.7), validamycin A (E.2.8);
    (F) Signal transduction inhibitors
    - MAP / histidine kinase inhibitors selected from: fluoroimid (F.1.1), iprodione (F.1.2), procymidone (F.1.3), vinclozoline (F.1.4), fenpiclonil (F.1.5), fludioxonil (F .1.6);
    - Protein G inhibitor: quinoxyphen (F.2.1);
    9/79 (G) Lipid and membrane synthesis inhibitors
    - phospholipid biosynthesis inhibitors selected from: edifenfos (G.1.1), iprobenfos (G.1.2), pyrazophos (G.1.3), isoprothiolan (G.1.4);
    - lipid peroxidation compounds selected from: dichloran (G.2.1), quintozene (G.2.2), tecnazene (G.2.3), tolclofos-methyl (G.2.4), biphenyl (G.2.5), chloroneb (G.2.6), etridiazole (G.2.7);
    - phospholipid biosynthesis and cell wall deposition: dimetomorph (G.3.1), flumorf (G.3.2), mandipropamide (G.3.3), pyrimorf (G.3.4), bentiavalicarb (G.3.5), iprovalicarb (G. 3.6), valiphenalate (G.3.7) and N- (1- (1- (4-cyano-phenyl) -ethanesulfonyl) -but-2-yl) -carbamic acid (4-fluorophenyl) ester (G.3.8);
    - the compound that affects the permeability of the cell membrane and fatty acids: propamocarb (G.4.1);
    - the fatty acid amide hydrolase inhibitors selected from: oxatiapiprolin (G.5.1), methanesulfonate 2- {3- [2- (1 - {[3,5-bis (difluoromethyl-1 H-pyrazol-1 -yl] acetyl} piperidin-4-yl) -1,3-thiazol-4-yl] -4,5-dihydro1,2oxazol-5-yl} -phenyl (G.5.2), methanesulfonate 2- {3- [ 2- (1 - {[3,5-bis (difluoromethyl) -1 H-pi razol-1 -yl] acetyl} piperidin-4-yl) -1,3-thiazol-4-yl] -4,5- dihydro-1,2-oxazol-5yl} -3-chlorophenyl (G.5.3);
    (H) Inhibitors with multilocal action
    - the inorganic active substances selected from: Bordeaux mixture (H.1.1), copper acetate (H.1.2), copper hydroxide (H.1.3), copper oxychloride (H.1.4), basic copper sulphate ( H.1.5), sulfur (H.1.6);
    - the thio- and dithiocarbamates selected from: ferbam (H.2.1), mancozeb (H.2.2), maneb (H.2.3), metam (H.2.4), metam (H.2.5), propineb (H. 2.6), draw (H.2.7), zineb (H.2.8), ziram (H.2.9);
    - organochlorine compounds selected from: anilazine
    10/79 (H.3.1), chlorothalonil (Η.3.2), captafol (Η.3.3), captan (Η.3.4), folpet (Η.3.5), diclofluanide (Η.3.6), diclorfen (Η.3.7) , hexachloro-benzene (Η.3.8), pentachlorphenol (Η.3.9) and its salts, phthalide (H.3.10), tolylfluanide (H.3.11), N- (4chloro-2-nitro-phenyl) -N-ethyl- 4-methyl-benzenesulfonamide (H.3.12);
    - guanidines and others selected from: guanidine (H.4.1), dodine (H.4.2), dodine-free base (H.4.3), guazatin (H.4.4), guazatin acetate (H.4.5), iminoctadine (H. 4.6), iminoctadine triacetate (H.4.7), iminoctadine tris (albesylate) (H.4.8), dithianone (H.4.9), 2,6-dimethyl-1H, 5H [1,4 ] dithino [2,3-c: 5,6-c '] dipyrrol-1,3,5,7 (2H, 6H) -tetraone (H.4.10);
    (I) inhibitors of cell wall synthesis
    - glucan synthesis inhibitors selected from: validamycin (1.1.1), polyoxin B (1.1.2);
    - melanin synthesis inhibitors: pyrokylone (1.2.1), tricyclazole (I.2.2), carpropamide (I.2.3), dicyclomethane (I.2.4), phenoxanil (I.2.5);
    (J) Defensive inducers of vegetables selected from: acibenzolar-S-methyl (J.1.1), probenazole (J.1.2), isothianyl (J.1.3), thiadinyl (J.1.4), proexadione-calcium (J .1.5); phosphonates: fosetil (J.1.6), fosetil-aluminum (J.1.7), phosphorous acid and its salts (J.1.8), of potassium or sodium bicarbonate (J.1.9);
    (K) Unknown mode of action selected from: bronopol (K.1.1), quinomethinate (K.1.2), cyflufenamide (K.1.3), cymoxanil (K.1.4), dazomet (K.1.5), debacarb (K .1.6), diclomezine (K.1.7), difenzoquat (K.1.8), difenzoquat methylsulfate (K.1.9), diphenylamine (K.1.10), phenpyrazamine (K.1.11), flumetover (K.1.12), flusulfamide ( K.1.13), flutianil (K.1.14), metasulfocarb (K.1.15), nitrapirin (K.1.16), isopropyl nitrotal (K.1.18), oxatiapiproline (K.1.19), tolprocarb (K.1.20), oxine copper (K.1.21), proquinazid (K.1.22), tebufloquine (K.1.23), keyboardphthalam (K.1.24), triazoxide (K.1.25), 2-butoxy-6-iodo3-propylchromen-4-one ( K. 1.26), 2- [3,5-bis (difluoromethyl) -1 H-pyrazol-1 -i] -1 - [4- (4 {5- [2- (prop-2-in-1-yloxy ) phenyl] -4,5-dihydro-1,2-oxazol-3-yl} -1,3-thiazol-2-yl) piperidin-111/79 yl] ethanone (K.1.27), 2- [3, 5-bis (di-fluoromethyl) -1 H-pyrazol-1-yl] -1- [4- (4- {5- [2-fluoro6- (prop-2-in-1-yl-oxy) phenyl] -4,5-dihydro-1,2-oxazol-3-yl} -1,3-thi-azol-2-yl) piperidin-1yl] ethanone (K. 1.28), 2- [3,5-bis ( difluoromethyl) -1 H-pyrazol-1-yl] -1- [4- (4- {5- [2-chloro-6 (prop-2-in-1-yl-oxy) phenyl] -4,5- dihydro-1,2-oxazol-3-yl} -1,3-thiazol-2-yl) piperidin-1yljetanone (K.1.29), N- (cyclopropylmethoxyimino- (6-difluoro-methoxy2.3-) acetamide di-fluoro-phenyl) -2-phenyl-methyl) (K.1.30), N '- (4- (4-chloro-3trifluoro-methyl-phenoxy) -2,5-dimethyl-phenyl) -N- ethyl-N methyl (K.1.31), N '(4- (4-fluoro-3-trifluoro-methyl-phenoxy) -2,5-dimethyl-phenyl) -N-ethyl-N-methyl (K. 1.32), N '- (2-methyl-5-trifluoromethyl-4- (3-trimethyl-silanyl-propoxy) -phenyl) -Netyl-N-methyl (K.1.33) formamidine, N' - (5- difluoromethyl-2-methyl-4- (3-tri-methylsilanylpropoxy) -phenyl) -N-ethyl-N-methyl (K.1.34), methoxy-acetic acid ester Q-tert-butyl-8-fluoro-2,3- dimethyl-quinolin-4-yl (K.1.35), 3- [5- (4-methylphenyl) -2,3-dimethylisoxazolidin-3-yl] -pyridine (K. 1.36), 3- [5- (4-chloro-phenyl) -2,3-dimethyl-isoxazolidin-3yl] -pyridine (pyrisoxazole) (K.1.37), N- (6methoxy-pyrid in cyclopropan-carboxylic acid amide) -3-i I) (K. 1.38), 5-chloro-1 - (4,6-di-methoxy-pyrimidin-2-yl) -2-methyl-1 Hbenzoimidazole (K.1.39), 2- (4 -chloro-phenyl) -N- [4- (3,4-dimethoxy-phenyl) -isoxazol-5-yl] 2-prop-2-ynyloxy-acetamide, (Z) -3-amino-2-cyano-3 ethyl-phenyl-prop-2-enoate (K.1.40), picarbutrazox (K.1.41), N- [6 - [[(Z) - [(1-methyltetrazol-5-yl) -phenylmethylene] amino] oxy -methyl] -2-pentyl (p.1.42), 2- [2 - [(7,8difluoro-2-methyl-3-quinolyl) oxy] -6-fluoro-phenyl] -propan-2-ol (K.1.43), 2- [2-fluoro-6 - [(8-fluoro-2-methyl-3-quinolyl) oxy] -phenyl] propan-2-ol (K.1.44), 3- (5- fluoro-3,3,4,4tetramethyl-3,4-dihydroiso-quinolin-1-yl) -quinoline (K. 1.45), 3- (4,4-difluoro-3,3dimethyl-3,4-dihydroisoquinolin -1-yl) -quinoline (K.1.46), 3- (4,4,5-trifluoro-3,3-dimethyl3.4-dihydroisoquinolin-1-yl) -quinoline (K.1.47), 9-fluoro- 2,2-dimethyl-5- (3-quinolyl) 3H-1,4-benzoxazepine (K.1.48);
    (L) Biopesticides (L1) Microbial pesticides with fungicidal, bactericidal, viricidal and / or vegetable activating activity: Ampelomyces quisqualis,
    12/79
    Aspergillus flavus, Aureobasidium pullulans, Bacillus amyloliquefaciens, B. mojavensis, B. pumilus, B. simplex, B. solisalsi, B. subtilis, B. subtilis var. amyloliquefaciens, Candida oleophila, C. saitoana, Clavibacter michiganensis (bacteriophages), Coniothyríum minitans, Cryphonectria parasitica, Cryptococcus albidus, Dilophosphora alopecurí, Fusarium oxysporum, Clonostachys rosea f. catenulate / also known as Gliocladium catenulatum), Gliocladium roseum, Lysobacter antibioticus, L. enzymogenes, Metschnikowia fructicola, Microdochium dimerum, Microsphaeropsis ochracea, Muscodor albus, Paenibacillus polymyxa, Pantoea vagans, Phlebiopsis, Pleeapsis, plebiopsis , Pythium oligandrum, Streptomyces gríseovirídis, S. lydicus, S. violaceusniger, Talaromyces flavus, Trichoderma asperellum, T. atroviríde, T. fertile, T. gamsii, T. harmatum, T. harzianum; mixture of T. vinde and T. harzianurrr, mixture of T. polysporum and T. harzianum; T. stromaticum, T. virens / also known as Gliocladium virens), T. viride, Typhula phacorrhiza, Ulocladium oudemansii, Verticillium dahlia, yellow mosaic zucchini virus (non-virulent strain);
    (L2) Biochemical pesticides with fungicidal, bactericidal, viricidal and / or vegetable activating activity: chitosan (hydrolysis), harpine protein, laminarin, Menhaden fish oil, natamycin, Plum pox, potassium or bicarbonate coated protein sodium, Reynoutria sachlinensis extract, salicylic acid, tea tree oil;
    (L3) Microbial pesticides with insecticidal, acaricidal, molluscidal and / or nematicidal activity: Agrobacterium radiobacter, Bacillus cereus, B. firmus, B. thuríngiensis, B. thuríngiensis ssp. aizawai, B. t. ssp. israelensis, B. t. ssp. galleriae, B. t. ssp. kurstaki, B. t. ssp. tenebrionis, Beauvería bassiana, B. brongniartii, Burkholdería sp., Chromobacterium subtsugae, Cydia pomonella granulosis virus, Cryptophlebia leucotreta granulovirus (CrieGV), Isaria fumosorosea, Heterorhabditis bacteriophora, Lecanicillium longisporum
    13/79 muscaríum (formerly Verticillium lecanii), Metarhizium anisopliae, M. anisopliae var. acridum, Nomuraea rileyi, Paecilomyces fumosoroseus, P. lilacinus, Paenibacillus popilliae, Pasteuria spp., P. nishizawae, P. penetrans, P. ramose, P. reneformis, P. thornea, P. usgae, Pseudomonas fluorescens, Steinemema carpocapsae, feltiae, S. kraussei;
    (L4) Biochemical pesticides with insecticidal, acaricidal, molluscidal, pheromone and / or nematicidal activity: L-carvone, citral, acetate (E, Z) -7.9 dodecadien-1-yl, ethyl format, (E decadenoate) , Z) -2,4-ethyl (pear ester), (Z, Z, E) -7,11,13-hexadecatrienal, heptyl butyrate, isopropyl myristate, lavanulil senecioate, cis-jasmine, 2-methyl- 1-butanol, methyl eugenol, methyl jasmonate, (E, Z) -2,13-octadecadien-1-ol, (E, Z) -2,13octadecadien-1-ol, (E t Z) - 3,13-octadecadien-1-ol, R-1-octen-3-ol, pentatermanone, potassium silicate, sorbitol actanoate, (Ε, Ζ, Ζ) acetate 3,8,11-tetradecatrienyl acetate ( Z, E) -9,12-1-tetradecadien-yl, Z-7tetradecen-2-one, Z-9-tetradecen-1-yl acetate, Z-11-tetradecenal, Z-11tetradecen-1-ol, extract black wattle, grapefruit and pulp seed extract, Chenopodium ambrosiodae extract, Catnip oil, Neem oil, Quillay extract, Tagetes oil;
    (L5) Microbial pesticides with the activity of reducing the tension of the plant, regulating growth, promoting plant growth and / or enhancing yield: Azospirillum amazonense, A. brasilense, A. lipoferum, A. irakense, A. halopraeferens, Bradyrhizobium sp, B. elkanii, B. japonicum, B. liaoningense, B. Lupini, Delftia acidovorans, Glomus intraradices, Mesorhizobium sp., Paenibacillus alvei, Penicillium bilaiae, Rhizobium leguminosarum bv. phaseoli, R. I. trifolii, R. I. bv. viciae, R. tropici, Sinorhizobium meliloti;
    (L6) Biochemical pesticides with the activity of reducing the tension of the plant, regulating growth and / or enhancing yield: acid
    14/79 abscisic, aluminum silicate (kaolin), 3-decen-2-one, formononetin, genistein, hesperetin, homobrassinlide, humates, jasmonic acid or its salts or derivatives, lysophosphatidyl ethanolamine, naringenin, polymeric hydroxy acid, extract Ascophyllum nodosum (Norwegian kelp, brown kelp) and Ecklonia maxima extract (seaweed);
    (M) Growth regulators selected from; abscisic acid (M.1.1), amidochlor, ancimidol, 6-benzylaminopurine, brassinolide, butralin, clormequat, clormequat chloride, choline chloride, cyclanilide, daminozide, diquegulac, dimethypine, 2,6-dimethylpuridine, etefone, flumetrinin, flumetrinin flutiacet, forclorfenuron, gibberellic acid, inabenfide, acetic acid indole-3, maleic hydrazide, mefluidide, mepiquat (mepiquat chloride), naphthalene acetic acid, Ν-6-benzyladenine, paclobutrazol, proexadion, proexaditone, trioxide; , 2,3,5triiodo-benzoic, trinexapac-ethyl and uniconazole;
    (N) Herbicides
    - the acetamides selected from: acetochlor (N.1.1), alachlor, butachlor, dimetachlor, dimethenamide (N.1.2), flufenacet (N.1.3), mefenacet (N.1.4), metolachlor (N.1.5), metazachlor (N. 1.6), napropamide, naproanilide, petoxamide, pretilachlor, propachlor, tenilchlor;
    - derivatives of amino acids selected from: bilanafos, glyphosate (N.2.1), glufosinate (N.2.2), sulfosate (N.2.3);
    - aryloxyphenoxypropionates: clodinafop (N.3.1), cihalofop-butyl, fenoxaprop (N.3.2), fluazifop (N.3.3), haloxifop (N.3.4), metamifop, propaquizafop, quizalofop, quizalofop-P-tefuril;
    - bipyridyls: diquat, paraquat (N.4.1);
    - the (uncle) carbamates selected from: asulam, butylate, carbetamide, demedipham, dimepiperate, eptam (EPTC), esprocarb, molinate, orbencarb, fenmedipham (N.5.1), prosulfocarb, pyributicarb, thiobencarb, trialate;
    15/79
    - cyclohexanediones selected from: butroxidim, cletodim (N.6.1), cycloxidim (N.6.2), profoxidim (N.6.3), setoxidim (N.6.4), tepraloxidim (N.6.5), tralcoxidim;
    - dinitroanilines selected from: benfluralin, etalfluralin, oryzaline, pendimethalin (N.7.1), prodiamine (N.7.2), trifluralin (N.7.3);
    - diphenyl ethers selected from: acifluorfen (N.8.1), aclonifen, bifenox, diclofop, ethoxyfen, fomesafen, lactofen, oxyfluorfen;
    - hydroxybenzonitriles selected from: bromoxynil (N.9.1), diclobenyl, ioxynil;
    - the imidazolinones selected from: imazametabenz, imazamox (N.10.1), imazapic (N.10.2), imazapir (N.10.3), imazaquin (N.10.4), imazetapyr (N.10.5);
    - phenoxyacetic acids selected from: clomeprop, acetic acid 2,4-dichlorophenoxy (2,4-D), 2,4-DB, dichlorprop, MCPA, MCPAtioethila, MCPB, mecoprop;
    - pyrazines selected from: chloridazone (N.11.1), flufenpir-ethyl, fluthiacet, norflurazone, pyridate;
    - the pyridines selected from: aminopyralid, clopyralid (N.12.1), diflufenican, dithiopir, fluridone, fluroxypyr (N.12.2), picloram (N.12.3), picolinafen (N.12.4), tiazopir;
    - the sulphonylureas selected from: amidosulfurone, azimsulfurone, bensulfurone (N.13.1), chlorimurone-ethyl (N.13.2), chlorsulfurone, cinosulfurone, cyclosulfamurone (N.13.3), ethoxysulfurone, flazassulfurone, flucetulfosulfurone, flucosulfurone, , imazosulfurone, iodosulfurone (N.13.4), mesosulfurone (N.13.5), mesosulforone, mesosulforon-methyl (N.13.6), nicosulfurone (N.13.7), oxassulfurone, primisulfurone, prosulfurone, pyrazosulfurone, rimsulfurone
    16/79 (N.13.8), sulfometurone, sulfosulfurone, tifensulfuron, triasulfurone, tribenurone, trifloxysulfurone, triflussulfurone (N.13.9), tritosulfurone, 1 - (((2-chloro6-propyl-imidazo [1,2-b] pyridazin 3-yl) sulfonyl) -3- (4,6-dimethoxypyrimidin-2-yl) urea;
    - triazines: ametrine, atrazine (N.14.1), cyanazine, dimetamethrin, ethiozine, hexazinone (N.14.2), metamitron, metribuzin, promethrin, simazine, terbutilazine, terbutrine, triaziflam;
    - urea selected from: chlorotolurone, daimurone, diurone (N.15.1), fluometurone, isoproturone, linurone, metabenzo-thiazurone, tebutiurone;
    - other acetolactate synthase inhibitors selected from: bispiribac sodium, cloransulam-methyl, diclosulam, florasulam (N.16.1), flucarbazone, flumetsulam, metosulam, orthosulfamurone, penoxsulam, propoxycarbazone, pyribambenzimpropyl, pyribambenzim-propyl, piriminobacmethyl, pirimisulfan, piritiobac, pyroxasulfone (N.16.2), pyroxsulam;
    - others selected from: amicarbazone, aminotriazole, anilophos, beflubutamide, benazolin, bencarbazone, benfluresate, benzofenap, bentazone (N.17.1), benzobicyclone, bicyclopyrone, bromacila, bromobutide, butafenacyl, butamidone, ethanol, N.17.2), chlortal, cinmetilina (N.17.3), clomazono (N.17.4), cumilurone, cyprosulfamide, dicamba (N.17.5), difenzoquat, diflufenzopyr (N.17.6), Drechslera monoceras, endotal, etofumesato, etobenzanida, phenoxysulfone, fentrazamide, flumichloracpentyl, flumioxazin, flupoxam, fluorochloridone, flurtamone, indanofan, isoxaben, isoxaflutol, lenacil, propanil, propizamide, quinclorac (N.17.7), quinmerac (N.17.8, mes.9 naptalam, oxadiargil, oxadiazon, oxaziclomefone, pentoxazone, pinoxadene, pyraclonil, piraflufen-ethyl, pirasulfotol, pyrazoxifen, pyrazolinate, quinoclamine, saflufenacil (N.17.10), sulcotrione (N.17.11), terrazine carbazone, topramezone (N.17.12), acid ethyl ester (317/79 [2-chloro-4-fluoro-5- (3-methyl-2 t 6-dioxo-4-trifluoromethyl-3 l 6-diichloro- 2H-pyrimidin-1yl) phenoxy] pyridin-2-yloxy) acetic, 6-amino-5-chloro-2-cyclopropylpyrimidine-4-carboxylic acid methyl ester, 6-chloro-3- (2-cyclopropyl-6- methylphenoxy) -pyridazin-4ol, 4-amino-3-chloro-6- (4-chlorophenyl) -5-fluoro-pyridin-2-carboxylic acid, 4-amino-3-chloro-6- acid methyl ester ( 4-chloro-2-fluoro-3-methoxy-phenyl) -pyridin-2-carboxylic acid and methyl ester of 4-amino-3-chloro-6- (4-chloro-3dimethylamino-2-fluoro-phenyl) -pyridin- 2-carboxylic;
    (O) Insecticides
    - the organo (uncle) phosphates selected from: acephate (0.1.1), azametiphos (0.1.2), azinphos-methyl (0.1.3), chlorpyrifos (0.1.4), chlorpyrifos-methyl (0.1.5) , chlorfenvinfos (0.1.6), diazinon (0.1.7), dichlorvos (0.1.8), dicrotophos (0.1.9), dimetoate (0.1.10), disulfoton (0.1.11), ethione (0.1.12), fenitrothione (0.1.13), fentiona (0.1.14), isoxathione (0.1.15), malationa (0.1.16), metamidophos (0.1.17), metidathione (0.1.18), paration-methyl (0.1.19) , mevinfos (0.1.20), monocrotofós (0.1.21), oxidemeton-methyl (0.1.22), paraoxon (0.1.23), parathione (0.1.24), phentoate (0.1.25), phosalone (0.1.26) ), fosmet (0.1.27), phosphamidone (0.1.28), phorate (0.1.29), foxima (0.1.30), pirimiphos-methyl (0.1.31), profenofos (0.1.32), protiofos (0.1. 33), sulprofós (0.1.34), tetrachlorvinphos (0.1.35), terbufos (0.1.36), triazophos (0.1.37), trichlorfone (0.1.38);
    - carbamates selected from: alanicarb (0.2.1), aldicarb (0.2.2), bendiocarb (0.2.3), benfuracarb (0.2.4), carbaryl (0.2.5), carbofuran (0.2.6), carbosulfan (S.2.7), phenoxycarb (0.2.8), furatiocarb (0.2.9), methocarb (0.2.10), methomyl (0.2.11), oxamil (0.2.12), pyrimicarb (0.2.13), propoxur (O. 2.14), tiodicarb (0.2.15), triazamate (0.2.16);
    - pyrethroids selected from: alethrin (0.3.1), bifenthrin (0.3.2), cyfluthrin (0.3.3), cyhalothrin (0.3.4), cyphenothrin (0.3.5), cypermethrin (0.3.6), alpha-cypermethrin (0.3.7), beta-cypermethrin (0.3.8), zetacipermethrin (0.3.9), deltamethrin (0.3.10), esfenvalerate (0.3.11), etofenprox
    18/79 (0.3.11), fenpropatrin (0.3.12), fenvalerate (0.3.13), imiprotrine (0.3.14), lambda-cyhalothrin (0.3.15), permethrin (0.3.16), pralethrin (0.3. 17), pyrethrin I and II (0.3.18), resmethrin (0.3.19), silafluofen (0.3.20), tau-fluvalinate (0.3.21), teflutrin (0.3.22), tetramethrin (0.3.23), tralometrine (0.3.24), transflutrin (0.3.25), proflutrin (0.3.26), dimeflutrin (0.3.27);
    - the growth regulators of insects selected from: (a) inhibitors of chitin synthesis: benzoylureas, chlorfluazurone (0.4.1), chiramazine (0.4.2), diflubenzurone (0.4.3), flucicloxurone (0.4. 4), fluphenoxurone (0.4.5), hexaflumurone (0.4.6), lufenurone (0.4.7), novalurone (0.4.8), teflubenzurone (0.4.9), triflumurone (0.4.10); buprofezin (0.4.11), diophenolane (0.4.12), hexithiazox (0.4.13), ethoxazole (0.4.14), clofentazine (0.4.15); (b) ecdysone antagonists: halofenozide (0.4.16), methoxyfenozide (0.4.17), tebufenozide (0.4.18), azadiractin (0.4.19); (c) the juvenoids: pyriproxifene (0.4.20), methoprene (0.4.21), phenoxycarb (0.4.22); (d) lipid biosynthesis inhibitors: spirodiclofen (0.4.23), spiromesifene (0.4.24), spirotetramate (0.4.24);
    - nicotinic receptor agonist / antagonist compounds selected from: clothianidin (0.5.1), dinotefuran (0.5.2), flupiradifurone (0.5.3), imidacloprid (0.5.4), thiamethoxam (0.5.5), nitenpiram ( 0.5.6), acetamipride (0.5.7), thiaclopride (0.5.8), 1- (2-chloro-thiazol-5-ylmethyl) -2-nitrimino3,5-dimethyl- [1,3,5] triazinan ( 0.5.9);
    - GABA antagonist compounds selected from: endosulfan (0.6.19, etiprol (0.6.2), fipronil (0.6.3), vaniliprol (0.6.4), pirafluprol (0.6.5), pyriprol (0.6.6 ), 5-amino-1- (2,6-dichloro-4-methyl-phenyl) -4sulfinamoyl-1H-pyrazol-3-carbothioic acid amide (0.6.7);
    - the insecticides of macrocyclic lactones selected from: abamectin (0.7.1), emamectin (0.7.2), milbemectin (0.7.3), lepimectin (0.7.4), spinosad (0.7.5), espinetoram (0.7. 6);
    19/79
    - mitochondrial electron transport inhibitor (METI) I acaricides selected from: phenazaquin (0.8.1), pyridaben (0.8.2), tebufenpirade (0.8.3), tolfenpirad (0.8.4), flufenerin (0.8 .5);
    - METI II and III compounds: acequinocyl (0.9.1), fluaciprim (0.9.2), hydramethylnone (0.9.3);
    - decouplers: chlorfenapyr (0.10.1);
    - the oxidative phosphorylation inhibitors selected from: cyhexatin (0.11.1), diafentiuron (0.11.2), fenbutatin oxide (0.11.3), propargite (0.11.4);
    - feather-disrupting compounds: cyromazine (0.12.1);
    - mixed-function oxidase inhibitors: piperonyl butoxide (0.13.1);
    - sodium channel blockers selected from: indoxacarb (0.14.1), metaflumizone (0.14.2);
    - ryanodine receptor inhibitors selected from:
    chlorantraniliprol (0.15.1), cyantraniliprol (0.15.2), flubendiamide (0.15.3), N- [4,6dichloro-2 - [(diethyl-lambda-4-sulfaniliden) carbamoyl] -phenyl] -2- (3 -chloro-2-pyridyl) -5 (trifluoromethyl) pyrazol-3-carboxamide (0.15.4); N- [4-chloro-2 - [(diethyl-lambda-4sulfaniliden) carbamoyl] -6-methyl-phenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazol-3carboxamide (0.15. 5); N- [4-chloro-2 - [(di-2-propyl-lambda-4-sulfaniliden) carbamoyl] 6-methyl-phenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazole -3-carboxamide (0.15.6); N [4,6-dichloro-2 - [(di-2-propyl-lambda-4-sulfaniliden) carbamoyl] -phenyl] -2- (3-chloro-2pyridyl) -5- (trifluoromethyl) pyrazol-3-carboxamide (0.15.7); N- [4,6-dichloro-2 - [(diethylambda-4-sulfaniliden) carbamoyl] -phenyl] -2- (3-chloro-2-pyridyl) -5- (difluoromethyl) pyrazole-3carboxamide (0.15.8) ; N- [4,6-dibromo-2 - [(di-2-propyl-lambda-4sulfaniliden) carbamoyl] -phenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazole-3carboxamide ( 0.15.9), N- [4-chloro-2 - [(di-2-propyl-lambda-4-sulfaniliden) carbamoyl] 20/79
    6-cyano-phenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazoyl-3-carboxamide (0.15.10); N- [4,6-dibromo-2 - [(diethyl-lambda-4-sulfaniliden) carbamoyl] -phenyl] -2- (3-chloro-2-pyridyl) 5- (trifluoromethyl) pyrazol-3-carboxamide (0.15 .11);
    - others selected from: benclothiaz (0.16.1), biphenazate (0.16.2), cartap (0.16.3), flonicamide (0.16.4), pyridalyl (0.16.5), pymetrozine (0.16.6), sulfur (S.16.7), thiocyclam (0.16.8), cyienopyraphene (0.16.9), flupirazophos (0.16.10), ciflumetofeno (0.16.11), amidoflumet (0.16.12), imicyafos (0.16.13), bistrifluron ( O. 16,14), pyrifluquinazon (0.16.15) and cyclopropanacetic acid ester 1, r - [(3S, 4R, 4aR, 6S, 6aS, 12R, 12aS, 12bS) -4 - [[(2cyclopropylacetyl) oxy] methyl] -1,3,4,4a, 5,6,6a, 12,12a, 12b-decahydro-12-hydroxy4,6a, 12b-trimethyl-11 -oxo-9- (3-pyridinyl) -2H, 11 H-naphtho [2,1-b] pyran [3,4-e] pyran-3,6 diyl] (0.16.16).
    [013] According to one embodiment, the mixtures comprise the B. amyloliquefaciens ssp. plantarum TJ1000 (also referred to herein as TJ1000) and at least one pesticide II in a synergistically effective amount.
    [014] The present invention also relates to a method for the control of harmful phytopathogenic fungi using mixtures of TJ1000 and at least one pesticide II and the use of TJ1000 and pesticides II for the preparation of such mixtures, and the compositions that comprise these mixtures and to the seeds that comprise these mixtures or are coated with this mixture.
    [015] Furthermore, it has been found that the simultaneous application, together or separately, of TJ1000 and a pesticide II or a successive application of TJ1000 and a pesticide II allows an intensified control of harmful fungi than is possible with the individual components in isolation (synergistic mixtures).
    [016] When applying TJ1000 and a pesticide II sequentially, the
    21/79 time between the two applications can vary, for example, between 2 hours to 7 days. A wider range is also possible, ranging from 0.25 hours to 30 days, preferably from 0.5 hours to 14 days, especially from 1 hour to 7 days or 1.5 hours to 5 days, more preferably, from 2 hours and 1 day. Preferably, TJ1000 is applied as a last treatment.
    [017] Component (1) in the mixtures covers not only pure cultures, isolated from TJ1000, as defined herein, but also a cell-free extract with pesticidal activity, preferably a ketone-based extract, its suspensions in a total culture broth or as a supernatant containing the metabolite or a purified metabolite obtained from a total culture broth of the microorganism or strain of microorganism.
    [018] As used herein, the term "total broth culture" refers to a liquid culture of a microorganism that contains cells and / or spores suspended in the vegetative culture medium and metabolites, optionally produced by the respective microorganism.
    [019] As used in the present, the term "strain" refers to isolating or a group of isolates exhibiting phenotypic and / or genotypic aspects belonging to the same lineage, distinct from other isolates or strains of the same species.
    [020] According to another embodiment, component (1) is TJ1000, and its cell-free extract. According to another embodiment, the component (1) is the TJ1000. According to another embodiment, component (1) is TJ1000 in a total broth. According to another embodiment, component (1) is TJ1000 in an inactive form. According to another embodiment, component (1) is TJ1000 in the form of spores.
    22/79 [021] TJ1000 can be grown, for example, using potato dextrose agar (PDA) under aerobic growth conditions at around 28 ° C. In large liquid cultures, aeration may be necessary. Bacterial cells (vegative cells and spores) can be washed and concentrated (for example, by centrifugation at room temperature for about 15 min at 7,000 xg). For the production of a dry formulation, the bacterial cells, preferably the spores, were suspended in a suitable dry vehicle (eg, clay). For the production of a liquid formulation, the cells, preferably the spores, can be resuspended in a liquid vehicle suitable (for example, water-based) for the desired spore density. The number of spore density of spores per ml_ can be determined by identifying the number of colony forming units (CFU) on agar plates, for example, potato dextrose agar after incubation for several days at 28 ° C TJ1000 is generally active at a temperature between 5 ° C and 50 ° C, preferably between 15 ° C and 35 ° C.
    [022] Il chemical pesticides of a chemical nature are described by common names, their preparation and their activity against pests are known (cf: http://www.alanwood.net/pesticides/); these pesticides are usually commercially available.
    [023] According to another embodiment, component (2) is selected from Bradyrhizobium japonicum, B. elkanii, Bradyrhizobium spp., Bradyrhizobium sp. (Arachis), Bradyrhizobium sp. (Vigna), B. liaoningense, B. lipine; Azospiríllum brasilense, A. amazonense, A. lipoferum, A. irakense, A. halopraeferens; Acidovorans Delftia, Glomus intraradices; Mesorhizobium spp, Mesorhizobium cicerí, M. huakii, M. loti; Rhizobium leguminosarum bv. phaseoli, R. leguminosarum bv. trifolii, R. leguminosarum bv. viciae, R. tropici, Sinorhizobium meliloti; Bacillus amyloliquefaciens, B.
    23/79 amyloliquefaciens ssp. plantarum, B. firmus, B. pumilus, B. subtilis, B. simplex, B. megateríum, B. altitudinis, B. mojavensis, B. mycoides, B. solisalsi, Burkholderia spp., Coniothyríum minitans, Muscodor albus, Paecilomyces lilacinus , Paenibacillus alvei, Pasteuria Nishizawa, Pasteuria usgae, Penicillium bilaiae, Pseudomonas fluorescens, Pseudomonas putida; abscisic acid, jasmonic acid, its salts and derivatives, cis-jasmine, methyl jasmonate; harpin protein.
    [024] According to another embodiment, component (2) is selected from Bradyrhizobium japonicum, B. elkanii, Azospiríllum brasilense; Bacillus amyloliquefaciens, B. amyloliquefaciens ssp. plantarum, B. firmus, Bacillus pumilus, Bacillus subtilis, B. simplex, B. megateríum; Burkholderia spp, Coniothyríum minitans, Muscodor albus, Paecilomyces lilacinus, Paenibacillus alvei, Penicillium bilaiae, Pasteuria Nishizawa ', cisjasmona, methyl jasmonate and harpine protein.
    [025] According to another embodiment, component (2) is selected from Bacillus firmus, Bacillus pumilus, Burkholderia spp., Muscodor albus and Paecilomyces lilacinus. These mixtures are especially effective for the control of nematodes.
    [026] According to another embodiment, the mixture comprises, in addition to component (1) and component (2) another active component (3), which is selected from methyl jasmonate, cis-jasmine and harpine , provided that component (2) is different from component (3).
    [027] Biopesticides of group (L) of pesticides II, their preparation and their pesticidal activity, for example, against harmful fungi and insects are known (e-Pesticide Manual V 5.2 (ISBN 978 1 901396 85 0) (2008-2011); http://www.epa.gov/opp00001/biopesticides/, see product lists at present; http: //www.omri.org/omri-lists, see lists at present; bank BPDB data sheet for biopesticides http://sitem.herts.ac.uk/aeru/bpdb/, see
    24/79 connection from A to Z).
    [028] Biopesticides in the group (L1) and / or (L2) may also have insecticidal, acaricidal, molluscidal, pheromone, nematicidal activity, reduced plant tension, growth regulator, promotion of plant growth and / or yield intensified. Biopesticides in the group (L3) and / or group (L4) may also have fungicidal, bactericidal, viricidal activity, activator of plant defense, reduction of plant tension, growth regulator, promotion of plant growth and / or yield intensified. The biopesticides of the group (L5) and / or (L6) may also have fungicidal, bactericidal, viricidal, plant defense activator, insecticide, acaricide, molluscidal, pheromone and / or nematicide.
    [029] Many of these biopesticides are registered and / or commercially available: aluminum silicate (Screen ™ Duo from Certis LLC, USA), Agrobacterium radiobacter K1026 (eg NoGall® from BASF Agricultural Specialties Pty Ltd., Australia), A. radiobacter K84 (Nature 280, 697-699, 1979; for example, from GalITroll® AG Biochem, Inc., C, USA), Ampelomyces quisqualis, H-10 (for example, from AQ 10® from Intrachem Bio GmbH & Co. KG, Germany), Ascophyllum nodosum (Norwegian kelp, Brown kelp) extract or filtrate (for example, ORKA Gold from BASF Agricultural Specialties (Pty) Ltd., South Africa, or Goemar® from Laboratoires Goemar, France) , Aspergillus flavus NRRL 21882 isolated from a peanut in Georgia in 1991 by the USDA, National Peanut Research Laboratory (for example, in Syngenta's Afla-Guard®, CH), mixtures of Aureobasidium pullulans DSM14940 and DSM 14941 (for example, Blastospors in BlossomProtect® by bio-ferm GmbH, Germany), Bacillus altitudinis 41 KF2b (DSM 21631; J. Syst Evol Microbiol 56 (7), 1,465-1,473, 2006), Bacillus amyloliquefaciens strains AP-136 (NRRL B-50614 and B-50330), AP-188 (NRRL B-50615 and B-50331), AP-218 (NRRL B-50618), AP-219 (NRRL
    25/79
    B-50619 and Β-50332), and AP-295 (NRRL B-50620 and B-50333) all known from US patent 8,445,255; B. amyloliquefaciens TI-45 (CNCM I 3800) (for example, from C Rhizocell ITHEC, France), B. amyloliquefaciens IN937a (J. Microbiol Biotechnol 17 (2), 280-286, 2007; BioYield®, for example, from Gustafson LLC, TX, USA), B. amyloliquefaciens spp. plantarum D747 (US patent 2013 / 0.236,522 A1; FERM BP 8234; for example, 55 WDG or Double Nickel ™ LC from Certis LLC, USA Double Nickel ™), B. amyloliquefaciens spp. plantarum FZB24 isolated from soil infested with vegetable pathogen from a sugar beet field in Brandenburg, Germany (also called SB3615; DSM ID 96-2; J. Planta Dis Prot 105, 181-197, 1998; for example, Taegro® of Novozyme Biologicals, Inc., USA),), B. amyloliquefaciens spp. plantarum SB3615vPPI being a phage-resistant variant of FZB24 (MRRL B-50349, US 2011/023045 A1, from Novozyme Biologicals, Inc., USA), B. amyloliquefaciens ssp. plantarum FZB42 isolated from the plant pathogen-infested soil of a sugar beet field in Brandenburg, Germany (J. Planta Dis Prot 105, 181-197, 1998; DSM 23117; for example, RhizoVital® 42 by AbiTEP GmbH, Berlin, Germany), B. amyloliquefaciens ssp. plantarum GB03 (also called GBO3; ATCC SD-1397; Phytopathol 86 (11), S36, 1996; for example, Kodiak® or BioYield® by Gustafson, Inc., USA; or Companion® by Produts Growing, Ltd., White Plains , NY 10603, USA), B. amyloliquefaciens ssp. plantarum MBI600 also referred to as 1430 (NRRL B-50595; Int. J. Microbiol Res 3 (2) (2011), 120-130; US 2012/0149571 A1, for example, Integral®, Subtilex® NG at BASF Corp., USA), B. amyloliquefaciens spp. plantarum TJ1000 (also called 1 BE; CA 2,471,555 A1; ATCC BAA390, for example, from TJ QuickRoots ™ Technologies, Watertown, SD, USA), B. cereus CNCM 1-1562 (US 6,406,690), B. chitinosporus AQ746 isolated from roots in Saskatchewan, Canada (NRRL B-21618; US 5,733,544;
    26/79
    AgraQuest now Bayer CropScience LP, USA), B. firmus CNCM 1-1582 (WO 2009/126473, WO 2009/124707, US 6,406,690, for example, Votivo® from Bayer Crop Sciencie LP, USA), strains of B. megaterium H491 (NRRL B50769), M018 (NRRL B-50770) and J142 (NRRL B-50771) all known from US patent 2014/0051571 A1 to Marrone Bio Innovations, Inc., USA; B. mojavensis AP-209 (NRRL B-50616, US 8,445,255), B. mycoides AQ726 (NRRL B-21664, US 5,906,818, from Bayer Crop Science, Germany), B. mycoides J strain (for example, BMJ GT from Certis, USA against potato Y virus), B. pumilus GB34 (ATCC 700814; for example, YieldShield® by Gustafson LLC, TX, USA), B. pumilus GHA 180 isolated from apple rhizosphere in Mexico (IDAC 260707 -01; for example, in PRO-Mix® BX by Premier Horticulture, 1, avenue Premier, Rivie're-du-Loup, Quebec, Canada G5R6C1), B. pumilus KFP9F (NRRL B-50754; WO 2014/029697, for example, BAC-UP or FUSION-P from BASF Agricultural Specialties (Pty) Ltd., South Africa), B. pumilus INR-7 otherwise referred to as BU F22 and BU-F33 (NRRL B50185, NRRL B-50153 , US 8,445,255), B. pumilus QST 2808 (NRRL B 30087; for example, Sonata® or Ballad® Plus from AgraQuest Inc., USA), B. solisalsi AP-217 (NRRL B-50617; US 8,445,255 ), B. subtilis CX-9060 (Federal Register 77 (7), 1,633-1,637, by Certis EUA, LLC), B. subtilis FB17 also called U D 1022 or UD10-22 isolated from North American red beets (ATCC PTA-11857; System Appl. Microbiol 27 (2004) 372-379, 2004; US 2010/0260735; WO 2011/109395); B. subtilis GB07 (Phytopathol 86 (11), S36, 1996; Epic® by Gustafson, Inc., USA), B. subtilis QST-713 isolated from a California peach orchard in 1995 (NRRL B-21661; Rhapsody ®, for example, Serenade® MAX or Serenade® ASO from AgraQuest Inc., USA), by B. thuríngiensis ssp. aizawai ABTS-1857 (also called ABG-6346; ATCC SD-1372; for example, XenTari® from BioFa AG, Münsingen, Germany), B. t. ssp. aizawai SAN 401 I, ABG-6305
    27/79 (WO 2013/087709); Bacillus t. ssp. israelensis AM65-52 from Serotype H-14 (ATCC SD-1276; for example, VectoBac® by Valent BioSciences, IL, USA), Bacillus thuringiensis ssp. kurstaki SB4 (NRRL B-50753; for example, Beta Pro® from BASF Agricultural Specialties (Pty) Ltd., South Africa), B. t. ssp. kurstaki ABTS-351 identical to HD-1 (ATCC SD-1275; for example, Dipel® DF from Valent BioSciences, IL, USA), B. t. ssp. kurstaki EG 2348 (NRRL B-18208; for example, Lepinox® or Rapax® from CBC (Europe) Srl, Italy), B. t. ssp. tenebríonis DSM 2803 from Serotype H 8a, 8b (identical to NRRL B-15939; EP 0.585.215 B1; Mycogen Corp.), B. t. ssp. tenebríonis NB-125 (also referred to as SAN 418 I or ABG-6479; EP.585.215 B1; DSM 5526; previous production strain of Novo-Nordisk), B. t. ssp. tenebríonis NB-176 (or NB-176-1; an irrigated high-throughput gamma mutant, induced from strain NB-125; EP 585.215 B1; DSM 5480, for example, Novodor® by Valent BioSciences, Switzerland), Beauveria bassiana JW- 1 (ATCC 74040; for example, Naturalis® from CBC (Europe) Srl, Italy), B. bassiana DSM 12256 (US 200,020,031,495, for example, BioExpert® SC from Live Sytems Technology SA, Colombia), B. bassiana GHA (ATCC 74250; for example, BotaniGard® 22WGP from Laverlam Int. Corp., USA), B. bassiana PPRI 5339. (ARSEF 5339; NRRL 50757, for example, BroadBand® from BASF Agricultural Specialties (Pty) Ltd., South Africa Sul), B. brongniartii for the control of beetle (J. Appl. Microbiol 100 (5), 1063-1072, 2006; for example, Melocont® from Agrifutur, Agrianello, Italy), Bradyrhizobium sp. (for example, Vault® by BASF Corp., USA), B. sp. (Arachis) CB1015 presumably originally collected in India (IITA 1006, USDA 3446, Autralian Inoculant Research Group; http://www.qaseeds.com.au/inoculant_applic.php). B. sp. (Vigna) PNL01 (Bisson and Mason, April 29, 2010, Project Report, Worcester Polytechnic Institute, Worcester, MA, USA: http://www.wpi.edu/Pubs/Eproject/Available/E-project-042810 -163614 /; for example, Vault® Peanut
    28/79
    Liquid from BASF Corp., USA), B. elkanii USDA 76, B. elkanii USDA 94B. elkanii USDA 3254, B. elkanii L-1301 and L-1302 (for example, Nitragin® Optimize from Novozymes Bio As SA, Brazil, or Nitrasec for soy from LAGE y Cia, Brazil), B. japonicum (for example, Vault ® from BASF Corp., USA), B. japonicum G49 (MSDJ G49; CR Acad. Agric. Fr. 73, 163-171, 1987); B. japonicum TA-11 (TA11 NOD + ) (NRRL B-18466; US 5,021,076; Appl. Environ. Microbiol. 56, 2399-2403, 1990; for example, Vault® NP from BASF Corp., USA), the B. japonicum strain deposited in USDA known from US 7,262,151 and Appl. Environ. Microbiol. 60, 940-94, 1994: USDA 3 isolated from Glycine max in Virginia (USA) in 1914, USDA 31 (= Nitragin 61A164) od Serogrup 31 isolated from Glycine max in Wisconsin (USA) in 1941, USDA 76 isolated plant passage of the strain USDA 74 (Serogrup 76), which was isolated from G. max, in California (USA), in 1956, USDA 121 isolated from G. max in Ohio (USA), in 1965 (Crop Science 26 (5 ), 911-916, 1986); B. japonicum WB74 (for example, Eco-Rhiz Soya from Plant Health Products (Pty) Ltd, South Africa, or Soybean inoculant from Stimuplant CC, South Africa), B. Lupini LL13 isolated from Lupinus iuteus nodules from French soils (deposited at INRA, France; http://agriculture.gouv.fr/IMG/pdf/ch20060216.pdf), B. Lupini strains from Australia and known from Palta JA, Berger JB (eds), Proceed. 12 International Lupine Conference, 14 to 18 September 2008, Fremantle, Western Australia, Lupine Association International, Canterbury, New Zealand, 47-50, http:
    //www.lupins.org/pdf/conference/2008/Agronomy%20and%20Production/John% 20Howieson% 20and% 20G% 200Hara.pdf; Appl. Environ. Microbiol. 71, 7041-7052, 2005; Australian J. Exp. Agricult. 36 (1), 63-70, 1996: isolated WU425 strains in Esperance, Western Australia from a non-Australian vegetable Omithopus compressus, WSM471 isolated from Omithopus pinnatus in Oyster Harbor, Western Australia, and WSM4024 isolated from lupines in
    29/79
    Australia, by CRS during a 2005 survey; Burkholderia sp. A396 (NRRL B-50319; WO 2013/032693; Marrone Bio Innovations, Inc., USA), Candida oleophila 1-182 (NRRL Y-18846; Phytoparasitica 23 (3), 231-234, 1995; for example, Aspire® from Ecogen Inc., USA;), strain C. oleophila O (NRRL Y 2317; Biological Control 51, 403-408, 2009), Candida saitoana (eg, Biocure® [in mixture with lysozyme] and MicroCoat® Micro Yarn Company, USA (BASF SE) and Arysta), chitosan (for example, Armor-Zen® by BotriZen Ltd., NZ), Clonostachys rosea f. catenulate (also called Gliocladium catenulatum) J1446 isolated from Finnish field soil (NJF Seminar No. 389: Pest, disease and weed management in strawberry; Finland from 8 to 9 November 2006 in NJF Report 2 (10), 15-15, 2006 ; DSM 9212, for example, Primastop® or Prestop® from Verdera Oy, Finland), Chromobacteríum subtsugae PRAA4-1 isolated from the soil under an eastern hemlock (Tsuga canadensis) from Catoctin Mountain, in central Maryland (NRRL B-30655; for example, Grandevo® from Marrone Bio Innovations, USA), Coniothyrium minitans CON / M / 91-08 (WO 1996/021358; DSM 9660, for example, Contans® WG, Intercept® WG from Prophyta Biologischer Pflanzenschutz GmbH, Germany), Cryphonectría parasitica (hypovirulent strains; Microbiol. Reviews 56 (4), 561-576, 1992; for example, product Endothia parasitica by CNICM, France), Cryptococcus albidus (for example, YIELD PLUS® by Anchor Bio-Technologies, South Africa ), Cryptophlebia leucotreta granulovirus (CrleGV) (e.g. CRYPTEX de And ermatt Biocontrol, Switzerland), Cydia pomonella granulovirus (CpGV) V03 (DSM GV-0006; for example Madex® Max from Andermatt Biocontrol, Switzerland), CpGV V22 (DSM GV-0014, for example Madex® Twin from Andermatt Biocontrol, Switzerland), Delftia acidovorans RAY209 (ATCC PTA-4249; WO 2003/57861, for example , BioBoost® by Brett Young, Winnipeg, Canada), Dilophosphora alopecuri (FarmNote 396, February 2010, Department of
    30/79
    Agriculture and Food, Government of Western Australia, for example, Twist Fungus of BASF Agricultural Specialties Pty Ltd, Australia), extract of Ecklonia maxima (seaweed) (J. Ecological Engineering 14 (1), 48-52, 2013; for example, KELPAK SL from Kelp Products Ltd, South Africa), Flavobacterium sp. H492 (ATCC B-505,584; WO 2013/138398, for example, MBI-302 from Marrone Bio Innovations, USA for the control of soy cyst nematode), formononetine (US 5,002,603, for example, Myconate® from Plant Health Care pic, United Kingdom), Fusaríum oxysporum Fo47 (isolated non-pathogenic strain of a suppressive soil located in Châteaurenard, France; Appl. Environ. Microbiol 68 (8), 4.044-4.060, 2002; Fusaclean® by Natural Plant Protection, NPP ( société anonyme) Route d'Artix F-64,150 Nogueres, France), F. oxysporum 251 / 2RB (Preventio Today Vol 2, n 1-2, 47-62, 2006; for example, Biofox® C from SIAPA, Italy); Glomus intraradices (for example, Myc® 4000 from ITHEC, France), Glomus intraradices RTI-801 (for example, MYKOS from Xtreme Gardening, USA or RTI Reforestation Technologies International; USA), pomelo seed and pulp extract (for example, BC-1000 from Chemie SA, Chile), harpin protein (alpha-beta) (Science 257, 85-88, 1992; for example, Messenger ™ or HARP-N-Tek from Plant Health Care pic, UK), nucleopolihedrovirus Helicoverpa armigera (HearNPV) (J. Invertebrate Pathol. 107, 112-126, 2011; for example, Helicovex® by Andermatt Biocontrol, Switzerland), Heterorhabditis bacteriophora (for example, Nemasys® G of BASF Agricultural Specialties Limited, United Kingdom), Isaria fumosorosea Apopka-97 (ATCC 20874; Biocontrol Science Technol. 22 (7), 747-761, 2012; for example, PFR-97 ™ or PreFeRal® from Certis LLC, USA), /. fumosorosea FE 9901 (ARSEF 4490; Biocontrol Science Technol. 22 (7), 747761, 2012; for example, blastospores in NoFIy ™ WP from Natural Industries, Inc., Houston, TX, USA or Novozymes, USA), c / s -jasmona (US 6,890,525, US 8,221,736; Plant Bioscience Limited, Norwich, United Kingdom), laminarin
    31/79 (for example, in Vacciplant® by Laboratoires Goemar, St. May, France or Stáhler SA, Switzerland), Lecanicillium longisporum KV42 and KV71 (for example, Vertalec® by Koppert BV, Netherlands), L. muscarium Ve6 (also called KV01; IMI 19-79, CABI 268.317, CBS 102071, ARSEF 5128, for example, Mycotal® by Koppert BV, Netherlands), Lysobacter antibioticus 13-1 (Biological Control 45, 288-296, 2008), L. antibioticus HS124 (Curr. Microbiol. 59 (6), 608-615, 2009), L. enzymogenes 3.1T8 (Microbiol. Res. 158, 107-115, 2003; Biological Control 31 (2), 145-154, 2004); Mesorhizobium spp. known from Soil Biol. Biochem. 36 (8), 1309-1317, 2004; Plant and Soil 348 (1-2), 231-243, 2011: M. sp. WSM1271 collected in Sardinia, Italy, from the host plant Biserrula pelecinus, M. sp. WSM 1497 collected in Mykonos, Greece, from Biserrula pelecinus, Mesorhizobium ciceri CC1192 collected in Israel from Cicer arietinum nodules (UPM 848, CECT 5549; Can. J. Microbiol. 48, 279-284, 2002; from Horticultural Research Station, Gosford, Australia), M. huakuii HN3015 isolated from Astralagus sinicus in a rice field in South China (World J. Microbiol. Biotechn. 23 (6), 845-851, 2007, ISSN 0.959-3.993) , M. loti CC829 isolated from L. ulginosus nodules in the USA (NZP 2012; commercial inoculant for Lotus pedunculatus and L. ulginosus in Australia), and M. loti SU343 isolated from host nodules in the USA (commercial inoculant for Lotus comiculatus in Australia); Metarhizium anisopliae FI-1045 (AGAL V10 / 0.104.285; WO 2012/018266, for example, Biocane® from BASF Agricultural Specialties Pty Ltd, Australia), M. anisopliae var. anisopliae F52 also called 275 or V275 (DSM 3884, ATCC 90448; for example, Met52® Novozymes Biologicals BioAg Group, Canada), M. anisopliae ICIPE 69 isolated from a soil sample obtained from the Democratic Republic of Congo (DRC) and using the Galleria bait method in 1990 (for example, ICIPE Metathripol, Nairobe, Kenya), M. anisopliae var. acridum IMI 330189 isolated from
    32/79
    Ornithacris cavroisi in Niger (NRRL 50758, for example, Green Muscle® from BASF Agricultural Specialties (Pty) Ltd., South Africa), M. a. var. acridum Fl985 isolated from a spur-throat locust, Austracris guttulosa (Walker), near Rockhampton, Queensland, Australia, in 1979 (ARSEF 324; Memoirs of the Entomological Society of Canada 171, 287-300, 1997; for example, Green Guard® SC from BASF Agricultural Specialties Pty Ltd, Australia), Metschnikowia fructicola 277 isolated from the surface of grape berries (Superior cv) grown in central Israel (US 6,994,849; NRRL Y30752; for example, from Shemer ® Agrogreen, Israel, currently distributed by Bayer CropSciences, Germany), Microdochium dimerum L13 (CNCM 1-3141, for example, Antibot® from Agrauxine, France), Microsphaeropsis ochracea P130A isolated from apple leaves an abandoned orchard, St- Joseph-du-Lac, Quebec, Canada in 1993 (ATCC 74.412; Mycologia 94 (2), 297-301, 2002), Muscodor albus QST 20799 also named 620 originally isolated from the bark of a cinnamon tree in Honduras (NRRL 30547, for example, Muscudor ™ or QRD300 from Agra-Qu est, USA), Muscodor albus SA-13 (NRRL B-50774; US 2014/0086879 A1; for example, MBI-601-EP by Marrone Biolnovations, Inc., USA), Neem oil (eg, Trilogy®, Triact® 70 CE, Certis LLC, USA), Nomuraea rileyi SA86101, GU87401, SR86151, CG128 and VA9101 (Braz. Arch. Biol Technol. 46 (1), 13-19, 2003; WO 2013/110594), Paecilomyces lilacinus 251 isolated from infected nematode eggs in the Philippines (AGAL 89/030550; W01991 / 02051; Crop. Protection. 27, 352-361, 2008; for example, BioAct® / MeloCon® of Prophyta, Germany), P. lilacinus DSM 15169 (for example, Nemata® SC of Live Systems Technology SA, Colombia), P. lilacinus BCP2 (NRRL 50756 ; Acta agriculturee Slovenica, 101-2, 263 -275, 2013; for example, PL Gold from BASF Agricultural Specialties (Pty) Ltd., South Africa), Paenibacillus alvei NAS6G6 (WO 2014/029697; NRRL B-50755; by
    33/79 example, BAC-UP from BASF Agricultural Specialties (Pty) Ltd., South Africa mixed with Bacillus pumilus KFP9F), P. polymyxa PKB1 (ATCC 202127; Can. J. Microbiol 48 (2), 159-169 , 2002), Pantoea agglomerans E325 (NRRL B-21856; Phytopathol 101 (10), 1234-1241, 2011; Trees 26, 227-238, 2012; Bloomtime Biological ™ by Northwest Agricultural Products, Inc., USA), Pantoea vagans (formerly agglomerans) C9-1 originally isolated in 1994 from apple stem tissue to control bacterial fire in the apple (J. Bacteriol. 192 (24), 6486-6487, 2010; for example, BlightBan C9-1 ® by NuFrams America Inc., USA), Pasteuría sp. ATCC PTA-9643 (WO 2010/085795), Pasteuría sp. Ph3 isolated from soil samples collected on the DeBary Golf Course lawn in central Florida (ATCC SD5832; WO 2012/064527; for the control of Hoplolaimus galeatus nematode from Pasteuría Bioscience, Inc. at the moment Syngenta Crop Protection, LLC, USA) , Pasteuría sp. Pr3 isolated from soil samples collected in the southeastern United States (ATCC SD-5834; for the donematoid control Rotylenchulus reniformis potentially of species P. ramosa Naviva® ST from Syngenta Crop Protection, LLC, USA), P. nishizawae ( WO 2010/80619), P. nishizawae PN1 (Federal Register 76 (22), 5808, February 2, 2011; ATCC SD 5833; for example, Clariva ™ PN from Syngenta Crop Protection, LLC, USA), P. penetrans ( US 5,248,500; Del Monte Corp), P. ramosa (WO 2010/080619), P. thomea (WO 2010/080619), P. usgae BL1 (ATCC SD-5835; J. Nematol 42 (2.): 87 -90, 2010; ibid. 43 (2), 101-109, 2011; for example, Econem ™ for the control of Belonolaimus longicaudatus from Pasteuría BioScience at the time Syngenta marketed by HarelPs LLC, Florida, USA, for use on the lawn for the management of Belonolaimus longicaudatus), Penicillium bilaiae (also called P. bilaii) strains ATCC 18309 (ATCC = 74,319), ATCC 20851 and / or ATCC 22348 (ATCC = 74,318) originally isolated from the soil in southern Alberta (Res 39 fertilizers,
    34/79
    97-103, 1994; Can. J. Plant I know. 78 (1), 91-102, 1998; US 5,026,417, WO 1995/017806 ;, for example, Ir Start®, Provide® of Novozymes Biologicals BioAg Group, Canada), P. bilaiae NRRL 50162 and NRRL 50169 (WO 2010/037228), Phlebiopsis gigantea (e.g. RotStop® from Verdera Oy, Finland), Pichia anomalous WRL-076 (NRRL Y-30842; US 8,206,972), potassium bicarbonate (eg Amicarb® from Stáhler SA, Switzerland), potassium silicate (eg Sil -MATRIZ ™ from Certis LLC, USA), Pseudozyma flocculosa PF-A22 UL (e.g., Sporodex® L from Plant Products Co. Ltd., Canada), Pseudomonas sp. Proradix (DSM 13134; WO 2001/40441, for example, PRORADIX by Sourcon Padena GmbH & Co. KG, Hechinger Str 262, 72072 Tübingen, Germany), P. chloraphis MA 342 (Microbiology Monographs 18, 21-43, 2011; by example, Cerall® or Cedemon® from Bioagri AB, Uppsala, Sweden or Intrachem Bio Deutschland GmbH & Co. KG, Bad Camberg, Germany), P. fluorescens (for example, in Bio Cure-B by T. Stanes & Company Limited, India; or in the Blight-End of Agri Naturals, Mumbai, India), P. fluorescens A506 (Phytopathol 97 (2), 244-249, 2007; ATCC 31948; for example, BlightBan® by Nufarm Americas, Inc., Morrisville, NC, USA), P. fluorescens ATCC 13525 of biovar I = biotype A; originally isolated from pre-filter tanks in England (DSM 50090; registered for use in Canada), P. fluorescens CHA0 (Mol. Planta Microbe Interact. 5 (1), 4-13, 1992.), P. fluorescens CL 145A (J. Invertebr. Pathol. 113 (1), 104-14, 2013; for example, Zequanox® by Marrone Biolnovations, Davis, CA, USA), P. fluorescens NCIB 12089 (EP 0.210.734 Al; Victus® by Mauri Laboratories, 9 Moorebank Ave., Moorebank, NSW 2170, Australia), P. fluorescens Pf-5 isolated from the cotton root surface (ATCC BAA-477), P. putida ATCC 202153 (EMBRAPA 63/88 4 B ; WO 2004/0245865), Pythium oligandrum DV 74 (US 2013/0035230; ATCC 38472; for example, Poyversum® by Remeslo SSRO,
    35/79
    Biopreparaty, Czech and Gowan Rep., USA), Reynoutria sachalinensis extract (EP 0.307.510 B1; for example, Regalia® SC by Marrone Biolnnovations, Davis, CA, USA or Milsana® by Biofa AG, Germany), Rhizobium leguminosarum bv . phaseoli (for example, RHIZO-STICK from BASF Corp., USA), R. leguminosarum bv. phaseoli RG-B10 (USDA 9041; from Int. J. Syst. Bacteriol. 46 (1), 240-244, 1996; Int. J. Syst. Evol. Microbiol. 50, 159170, 2000; for example, Nodulator® Dry Bean in Africa, HiStick NT Dry Bean in the USA, and Nodulator® Dry Bean in Canada by BASF Corp., USA, or BASF Agriculture Specialties Ltd., Canada), RI bv. trifolii CB782 (Nodulaid® peat for the Kenya white clover from BASF Agricultural Specialties Pty Ltd, Australia), R. I. bv. trifolii CC275e (peat Nodulaid® for NZ white clover from BASF Agricultural Specialties Pty Ltd, Australia), R. I. bv. trifolii CC283b (ICMP 4073b; Proc. New Zealand Grassland Assoe. 56, 101-105, 1994; Microbiol. 153, 3,184-3,195 2007; Nodulaid® peat for the European clover of BASF Agricultural Specialties Pty Ltd, Australia), RI bv . trifolii CC1099 (Inoculating Vegetables: A Pratctical Guide, ed Grain Reasearch and Development Corporation, 2012, ISBN 978-1-921779-45-9; for example, the Nodulaid® peat for the accordion of BASF Agricultural Specialties Pty Ltd, Australia), IR bv. trifolii RP113-7 (Appl. Environ. Microbiol. 44 (5), 10961101, 1982; for example, Dormal® from BASF Corp., USA), R. L. bv. trifolüTM (Appl Environ. Microbiol. 49 (1), 127-131, 1985; for example, the Nodulaid® peat for white clover from BASF Agricultural Specialties Pty Ltd, Australia), strain R. I. bv. trifolii WSM1325 isolated in 1993 from the Greek island of Serifos (Stand Genomic Sei. 2 (3), 347-356, 2010; Inoculating Legumes: A Practical Legumes, ed. Grain Research and Development Corporation, 2012, ISBN 978-1 -921779- 45-9; Nodulaid® peat for the sub-clover and Nodulator® granules for the sub-clover, both from BASF Agricultural Specialties Pty Ltd, Australia, for a wide range of annual clovers of Mediterranean origin),
    36/79 strain R. I. bv. trifolii WSM2304 isolated from Trifolium polymorphum in Uruguay in 1998 (Stand. Genomic Sei. 2 (1), 66-76, 2010), R. I. bv. viciae P1NP3Cst a mutant resistant to P1NP3C streptomycin isolated from pea root nodules in Bretenière, France (also referred to as 1435; Nova Fitol 176, 680-690, 2007; ibid. 179 (1), 224-235, 2008; por example, Nodulator® PL Peat Granule by BASF Corp., USA; or Nodulator® PL PL by BASF Agriculture Specialties Ltd., Canada), RL bv. viciae RG-P2 also called P2 isolated from pea root nodules in Sakatchewan, Canada (for example, RhizUP peat for peas and lentils in Canada from BASF Agriculture Specialties Ltd., Canada), R. I. bv. viciae SU303 (for example, Nodulaid® Group E of BASF Agriculture Specialties Pty Ltd, Australia), R. I. bv. viciae WSM1455 (for example, Nodulaid® Group F from BASF Agriculture Specialties Pty Ltd, Australia), R. tropici CC511 (Agronomy, NZ 36, 4-35, 2006; for example, the Nodulaid® peat for BASF Agricultural common beans Specialties Pty Ltd, Australia), Sinorhizobium meliloti RCR2011 also named 2011 or SU47 (MSDJ0848; Mol. Gen. Genomics 272, 1-17, 2004; for example, Dormal® Alfalfa & Luzerne from BASF Corp., USA; Nitragin® Gold from Novozymes Biologicals BioAg Group, Canada), Sphaerodes mycoparasitica SMCD2220 also known as SMCD2220-01 (IDAC 301008-01; WO 2011/022809), nucleopolihedrovirus Spodoptera littoralis (SpliNPV) (for example, in LITTOVIR by Andermatt Biocontrol, Switzerland, Switzerland) for example, Millenium® from BASF Agricultural Specialties Limited, United Kingdom), S. feltiae (Nemashield® from BioWorks, Inc., USA; Nemasys® from BASF Agricultural Specialties Limited, United Kingdom), S. kraussei L137 (Nemasys® L from BASF Agricultural Specialties Limited, United Kingdom), S treptomyces galbus AQ6047 (NRRL 30232; WO 2012/135763; AgraQuest at the moment Bayer CropScience LP, USA); S. galbus M1064 (NRRL 50334; WO 2012/135763; AgraQuest at the moment Bayer CropScience
    37/79
    LP, USA); S. griseoviridis K61 (Crop Protection 25, 468-475, 2006; for example, Mycostop® by Verdera Oy, Espoo, Finland), S. lydicus WYEC 108 (US 5403584; for example, Actinovate® by Natural Industries, Inc., USA), S. violaceusniger YCED-9 (USA 5,968,503; for example, DT-9® from Natural Industries, Inc., USA), Talaromyces flavus V117b isolated from the ground (for example, Prophyta's Protus® WG, Germany), and Ulocladium oudemansii HRU3 (Agronomy 3, 632-647, 2013; for example, Botry-Zen® by Botry-Zen Ltd, NZ).
    [030] Strains can be obtained from culture collections and deposition centers (listed by their acronym prefix = strain, at present: http://www.wfcc.info/ccinfo/collection/by_acronym/), such as strains with AGAL or NMI prefixes from: National Measurement Institute, 1/153 Bertie Street, Port Melbourne, Victoria, Australia 3207; ATCC: American Type Culture Collection, 10801 University Blvd., Manassas, VA 20110-2209, USA; BR: Embrapa Agrobiology Diazothrophic Microbial Culture Collection, POBox 74,505, Seropédica, Rio de Janeiro, 23,851-970, Brazil; CABI or IMI: CABI Europa - International Institute of Mycology, Bakeham Lane, Egham, Surrey, TW20 9TYNRRL, United Kingdom; CB: The Rhizobium Collection CB, School of Environment and Agriculture, University of Western Sydney, Hawkesbury, Locked Bag 1797, South Penrith Distribution Center, NSW 1797, Australia; CBS: Centraalbureau voor Schimmel-cultures, Fungai Biodiversity Center, Uppsalaan 8, PO Box 85167, 3508 AD Utrecht, Nether-lands; CC: Flora Industry Division, CSIRO, Canberra, Australia; CNCM: Collection Nationale de Cultures de Microorganismes, Pasteur Institute, 25 rue du Docteur Roux, F75724 Paris Cedex 15; CPAC: Embrapa-Cerrados, CX.Postal 08223, Planaltina, DF, 73301-970, Brazil; DSM: Leibniz-lnstitut DSMZ-Deutsche Sammlung von und Mikroorganismen Zellkulturen GmbH, InhoffenstraBe 7 B, 38124 Braun-Schweig, Germany; IDAC: International Depositary of Canada
    38/79
    Collection, Canada; ICMP: International Collection of Microorgnisms from Plants, Landcare Research, Private Bag 92170, Auckland Mail Center, Auckland 1142, New Zealand; IITA: IITA, PMB 5320, Ibadan, Nigeria; INTA: Agriculture Collection Laboratory of the Institute of Agricultural Microbiology and Zoology (IMYZA), National Institute of Agricultural Technology (INTA), Castelar, Argentina; MSDJ: Laboratoire de Microbiologia des Sois, INRA, Dijon, France; MUCL: Mycothèque de TUniversité Catholique de Louvain, Croix du Sud 2, box L7.05.06, 1348 Louvain-la-Neuve, Belgium; NCIMB or NICB: the National Collection of Industrial and Marine Bacteria Ltd., Torry Research Station, PO Box 31, 135 Abbey Road, Aberdeen, AB9 8DG, Scotland; Nitragin: Nitragin strain Collection, The Nitragin Company, Milwaukee, Wisconsin, USA, NRRL or ARSEF (collection of entomopathogenic fungi): ARS Culture Collection of National Center for Agricultural Utilization Research, Agricultural Research Service, United States Department of Agriculture, 1815 North University Street, Peoria, Illinois 61604, USA; NZP: Department of Scientific and Industrial Research Culture Collection, Applied Biochemistry Division, Palmerston North, New Zealand; PPRI: ARC-Plant Protection Research Institute, Private Bag x134, Queenswood Pretoria, Gauteng, 0121, South Africa; SEMIA: FEPAGRO-State Foundation for Agricultural Research, Rua Gonçalves Dias, 570, Bairro Menino Deus, Porto Alegre / RS, Brazil; SRDI: SARDI, Adelaide, South Australia; USDA: US Department of Agriculture, Agricultural Research Service, Soybean and Alfalfa Research Laboratory, BARC-West, 10300 Baltimore Boulevard, Building 011, Room 19-9, Beltsville, MD 20705, USA (Beltsville Rhizobium Culture Collection Catalog, March 1987 USDA-ARS ARS-30: http://pdf.usaid.gov/pdf_docs/PNAAW891.pdf); and Murdoch University, Perth, Western Australia. Other strains can be found at: http://www.landcareresearch.co.nz/resources/collections/icmp.
    39/79 [031] Jasmine acid, its salts (jasmonates) or derivatives include, without limitation, potassium, sodium, lithium, ammonium, dimethylammonium, isopropylammonium, diolammonium and dietriethanolammonium; and also the methyl ester of jasmonic acid, amide of jasmonic acid, methylamide of jasmonic acid, jasmonic acid of L-amino acid (with amide bond) conjugated (for example, conjugated to L-isoleucine, L-valine, L-leucine or L-phenylalanine), 12-oxo-phytodienic acid, coronatine, coronafacoyl-L-serine, coronafacoyl-L-threonine, 1-oxo-indanoyl-isoleucine methyl esters, 1-oxo-indanoyl-leucine methyl esters , cis-jasmine, linoleic acid or its derivatives, and combinations of any of the above.
    [032] Humates are humic and fulvic acids extracted from a form of lignite coal and clay, known as leonardite. Humic acids are organic acids that occur in humus and other materials of organic origin such as peat and certain soft charcoal. They have been shown to increase phosphate's fertilizing efficacy and in micro-absorption of nutrients by vegetables, as well as assist in the development of the plant's root system.
    [033] According to an embodiment of the mixtures of the present invention, at least one pesticide II is selected from groups (L1) to (L6):
    (L1) Microbial pesticides with fungicidal, bactericidal, viricidal and / or plant defense activating activities selected from: Ampelomyces quisqualis M-10 (L.1.1), Aspergillus flavus NRRL 21882 (L1.2), Aureobasidium pullulans DSM 14940 (L1.3), A. pullulans DSM 14941 (L.1.4), Bacillus altitudinis 41KF2b (L.1.5), Bacillus amyloliquefaciens AP-136 (L.1.6), B. amyloliquefaciens AP-188 (L.1.7), B amyloliquefaciens AP-218 (L.1.8), B. amyloliquefaciens AP-219 (L.1.9), B. amyloliquefaciens AP-295 (L.1.10), B. amyloliquefaciens IN937a (L.1.11), B. amyloliquefaciens TI- 45 (G.1.12), B.
    40/79 amyloliquefaciens ssp. plantarum D747 (L.1.13), B. amyloliquefaciens ssp. plantarum FZB24 (L.1.14), B. amyloliquefaciens ssp. plantarum FZB42 (L.1.15), B. amyloliquefaciens ssp. plantarum GB03 (L.1.16), B. amyloliquefaciens ssp. plantarum MBI600 (NRRL B-50595) (L.1.17), B. amyloliquefaciens ssp. plantarum QST-713 (L.1.18), B. mojavensis AP 209 (L.1.20), B. mycoides AQ726 (L.1.21), B. mycoides J (L.1.22), B. pumilus INR-7 (L .1.23), B. pumilus KFP9F (L.1.24), B. pumilus QST 2808 (L.1.25), B. pumilus GHA 180 (L.1.26), B. simplex ABU 288 (L.1.27), B. solisalsi AP 217 (L.1.28), B. subtilis CX-9060 (L.1.29), B. subtilis FB17 (L.1.30), B. subtilis GB07 (L.1.31), Candida oleophila I-82 (L.1.32) , C. oleophila O (L.1.33), C. saitoana (L.1.34), Clavibacter michiganensis (bacterium) (L.1.35), Coniothyrium minitans CON / M / 91-08 (L.1.36), Cryphonectria parasitica (L .1.37), Cryptococcus albidus (L.1.38), Dilophosphora alopecurí (L.1.39), Fusarium oxysporum (L.1.40), Clonostachys rosea f. catenulata J1446 (L.1.41), Gliocladium roseum 321U (L.1.42), Metschnikowia fructicola NRRL Y-30752 (L.1.43), Microdochium dimerum (L.1.44), Microsphaeropsis ochracea P130A (L.1.45), Muscodor albus QST 20799 (L.1.46), Muscodor albus SA-13 (L.1.47), Paenibacillus alvei NAS6G6 (L.1.48), Paenibacillus polimyxa PKB1 (L.1.49), Pantoea agglomerans E325 (L.1.90), Pantoea vagans C9-1 ( L.1.50), Penicillium bilaiae ATCC 22348 (L.1.51), P. bilaiae ATCC 20851 (L.1.52), Penicillium bilaiae ATCC 18309 (L. 1.53), Phlebiopsis gigantea (L.1.54), Anomalous Pichia WRL-76 ( L.1.55), Pseudomonas sp. Proradix (L.1.56), Pseudomonas chloraphis MA 342 (L.1.57), P. fluorescens A506 (L.1.58), P. fluorescens CL 145A (L.1.91), P. fluorescens NCIB 12089 (L.1.92), P fluorescens Pf-5 (L.1.93), P. fluorescens WCS 374 (L.1.94), P. fluorescens ATCC 13525 (L.1.95), P. fluorescens CHAO (L.1.96), P. putida ATCC 202153 (L .1.97), Pseudozyma flocculosa PF-A22 UL (L.1.59), Pythium oligandrum DV 74 (L.1.60), Sphaerodes mycoparasitica SMCD2220 (L. 1.61), Streptomyces gríseovirídis K61 (L.1.62), S. lydicus WYEC 108
    41/79 (L.1.63), S. violaceusniger XL-2 (L.1.64), S. violaceusniger YCED-9 (L.1.65), Talaromyces flavus V117b (L.1.66), Typhula phacorrhiza 94671 (L.1.86) , Ulocladium oudemansii HRU3 (L.1.87), Verticillium dalia (L.1.88), yellow mosaic zucchini virus (non-virulent strain) (L.1.89);
    (L2) Biochemical pesticides with fungicidal, bactericidal, viricidal and / or plant defense activating activities selected from chitosan (hydrolysis) (L.2.1), harpin protein (L.2.2), laminarin (L.2.3), Menhaden fish oil (L.2.4), natamycin (L.2.5), Plum pox virus coated protein (L.2.6), potassium bicarbonate (L.2.7), Reynoutria sachalinensis extract (L.2.8), salicylic acid ( L.2.9), potassium or sodium bicarbonate (L.2.10), tea tree oil (L.2.11);
    (L3) Microbial pesticides with insecticidal, acaricidal, molluscidal and / or nematicidal activity selected from: Agrobacteríum radiobacter K1026 (L.3.1), K84 A. radiobacter (L.3.2), Bacillus firmus I 1582 (L.3.3); B. thuringiensis ssp. aizawai strains ABTS-: 1857 (L.3.4), SAN 401 I (L.3.5), ABG6305 (L.3.6) and ABG-6346 (L.3.7); B. t. ssp. israelensis AM65-52 (L.3.8), B. t. ssp. israelensis SUM-6218 (L.3.9), B. t. ssp. galleríae SDS-502 (L.3.10), B. t. ssp. kurstaki EG 2348 (L.3.11), B. t. ssp. kurstaki SB4 (L.3.12), B. t. ssp. kurstaki ABTS-351 (HD-1) (L.3.13), Beauvería bassiana ATCC 74040 (L.3.14), B. bassiana GHA (L.3.15), B. bassiana h123 (L.3.16), B. bassiana DSM 12256 (L.3.17), B. bassiana PPRI 5339 (L.3.18), B. brongniartii (L.3.19), Burkholderia sp. A396 (L.3.20), Chromobacterium subtsugae PRAA4-1 (L.3.21), Cydia pomonella granulose virus V22 (L.3.22), Cydia pomonella granulose virus V1 (L.3.23), Cryptophlebia leucotreta granulovirus (CrleGV) (L.3.57 ), Flavobacteríum sp. H492 (L.3.60), Helicoverpa armigera nucleopolyhedrovirus (HearNPV) (L.3.58), Isaría fumosorosea Apopka-97 (L.3.24), Lecanicillium longisporum KV42 (L.3.25), L. longisporum KV71 (L.3.26), L muscarium KV01 (L.3.27), Metarhizium anisopliae FI-985 (L.3.28), M. anisopliae FI-1045 (L.3.29), M. anisopliae F52
    42Γ $ (L.3.30), Μ. anisopliae ICIPE 69 (L.3.31), M. anisopliae var. acridum IMI 330189 (L.3.32); Nomuraea rileyi strains: SA86101 (L.3.33), GU87401 (L.3.34), SR86151 (L.3.35), CG128 (L.3.36) and VA9101 (L.3.37); Paecilomyces fumosroseus FE 9901 (L.3.38), P. lilacinus 251 (L.3.39), P. lilacinus DSM 15169 (L.3.40), P. lilacinus BCP2 (L.3.41), Paenibacillus popilliae Dutky-1940 (NRRL B- 2309 = ATCC 14706) (L.3.42), P. popilliae Dutky 1 (L.3.43), P. popilliae KLN 3 (L.3.56), Pasteuria sp. Ph3 (L.3.44), Pasteuria sp. ATCC PTA-9643 (L.3.45), Pasteuría sp. ATCC SD-5832 (L.3.46), P. nishizawae PN1 (L.3.46), P. penetrans (L.3.47), P. ramosa (L.3.48), P. sp. Pr-3 (L.3.49), P. thomea (L.3.50), P. usgae (L.3.51), Pseudomonas fluorescens CL 145A (L.3.52), Spodoptera littoralis nucleopolyhedrovirus (SpliNPV) (L.3.59), Steinemema carpocapsae (L.3.53), S. feltiae (L.3.54), S. krausse / 'L137 (L.3.55);
    (L4) Biochemical pesticides with insecticidal, acaricidal, molluscidal, pheromone and / or nematicidal activity selected from: L-carvone (L.4.1), citral (L.4.2), acetate (E, Z) -7.9 dodecadien -1-yl (L.4.3), ethyl format (L.4.4), acetate (E, Z) -2,4-decadienoate (pear ester) (L.4.5), (Z, Z, E) -7 , 11,13 hexadecatrienal (L.4.6), heptyl butyrate (L.4.7), isopropyl myristate (L.4.8), cis-jasmine (L.4.9), lavanulil senecioate (L.4.10), 2-methyl- 1-butanol (L.4.11), methyl eugenol (L.4.12), methyl jasmonate (L.4.13), ((E, Z) -2.13octadecadien-1-ol (L.4.14), acetate ( E, Z) -2,13-octadecadien-1-ol (L.4.15), (E, Z) -3,13-octadecadien-1-ol (L.4.16), R-1-octen-3-ol , pentatermanone (L.4.17), pentatermanone (L.4.18), potassium silicate (L.4.19), sorbitol actanoate (L.4.20), (E, Z, Z) -3,8,11-tetradecatrienyl acetate (L.4.21), (Z, E) 9,12-tetradecadien-1-yl acetate (L.4.22), Z-7-tetradecen-2-one (L.4.23), Ζ-9-tetradecen1-yl (L.4.24), Ζ-11-tetra-decennial (L.4.25), Z-11-tetradecen-1-ol ( L.4.26), black wattle extract (L.4.27), grapefruit and pulp seed extract (L.4.28), Chenopodium ambrosiodes extract (L.4.29), Catnip oil (L.4.30), Neem oil ( L.4.31), Quillay extract (L.4.32), Tagetes oil (L.4.33);
    43/79 (L5) Microbial pesticides with the activity of reducing the tension of the plant, regulating growth, promoting growth of plants and / or enhancing yield selected from: Bradyrhizobium sp. PNL01 (L.5.9), B. sp. (Arachis) CB1015 (L.5.10), B. sp. (Arachis) USDA 3446 (L.5.11), B. sp. (Vigna) (L.5.15), B. elkanii U-1302 (L.5.19), B. elkanii USDA 74 (L.5.20), B. elkanii USDA 76 (L.5.21), B. elkanii USDA 94 (L .5.22), B. elkanii USDA 3254 (L.5.23), B. japonicum CPAC 15 (L.5.25), B. japonicum G49 (L.5.27), B. japonicum TA-11 (L.5.28), B. japonicum USDA 3 (L.5.29), B. japonicum USDA 31 (L.5.30), B. japonicum USDA 76 (L.5.31), B. japonicum USDA 110 (L.5.32), B. japonicum USDA 121 (L. 5.33), B. japonicum USDA 123 (L.5.34), B. japonicum WB74 (L.5.39), B. liaoningense (L.5.40), B. Lupini LL13 (L.5.41), B. Lupini WU425 (L. 5.42), B. Lupini WSM471 (L.5.43), B. Lupini WSM4024 (L.5.44), Glomus intraradices RTI-801 (L.5.45), Mesorhizobium sp. WSM1271 (L.5.46), M. sp. WSM1497 (L.5.47), M. ciceri CC1192 (L.5.48), M. huakii (L.5.49), M. loti CC829 (L.5.50), M. loti SU343 (L.5.51), Rhizobium leguminosarum bv. phaseoli RG-B10 (L.5.52), R. I. bv. trifolii RP 113-7 (L.5.53), R. I. bv. trifolii 095 (L.5.57), R. I. bv. trifolii ΊΜ (L.5.58),
    R. I. bv. trifolii CC283b (L.5.59), R. I. bv. trifolii CC275e (L.5.60), R. I. bv. trifolii CB782 (L.5.61), R. I. bv. trifolii CC1099 (L.5.62), R. I. bv. trifolii WSM1325 (L.5.63), R. I. bv. viciae SU303 (L.5.64 / R. /. bv. viciae WSM1455 (L.5.65), RI bv. viciae P1NP3Cst (L.5.66), RI bv. viciae RG-P2 (L.5.67), R. tropici CC511 ( L.5.70), Sinorhizobium meliloti RCR2011 (L.5.71), S. meliloti NRG185 (L.5.72),
    S. meliloti RRI128 (L.5.73);
    (L6) Biochemical pesticides with the activity of reducing the tension of the plant, regulating growth and / or enhancing the yield selected from: abscisic acid (L.6.1), aluminum silicate (kaolin) (L.6.2), 3 -decen-2-one (L.6.3), formononectin (L.6.4), genistein (L.6.5), hesperetin (L.6.6), homobrassinolide (L.6.7), humates (L.6.8), jasmonate
    44/79 methyl (L.6.9), cis-jasmine (L.6.10), lysophosphatidyl ethanlamine (L.6.11), naringenin (L.6.12), polymeric polyhydroxy acid (L.6.13), salicylic acid (L.6.14 ), Ascophyllum nodosum extract (Norwegian kelp, Brown kelp) (L.6.15) and Ecklonia maxima (algae) extract (L.6.16).
    [034] The present invention also relates to agrochemical compositions comprising a mixture of TJ1000 (component 1) and at least one biopesticide selected from the group (L) (component 2), in particular at least one fungicide additional selected from the biopesticides of groups (L1) and (L2), as described above and, if desired, at least one suitable auxiliary.
    [035] Preference is also given to mixtures containing, as pesticide II (component 2) a biopesticide from the group (L1), preferably selected from Bacillus amyloliquefaciens, most preferably at present from the AP strains -136, AP-188, AP-218, AP-219, AP-295, IN937a, IT-45; B. amyloliquefaciens ssp. plantarum (formerly called B. subtilis or B. subtilis amyloliquefaciens spp.), most preferably, at present from strains MBI600, D747, FZB254, FZB42, GB03, and QST-713; B. mojavensis AP-209; B. pumilus, most preferably, at present from the strains GHA 180, INR-7, KFP9F and QST 2808; B. simpiex, most preferably, at present the ABU 288 strain; B. solisalsi, most preferably, at present the strain AP-217; B. subtilis, most preferably, at present selected from strains CX-9060, FB17 and GB07; Albus Muscodor, most preferably, at present the strains QST 20799 and SA-13; Paenibacillus alvei, most preferably, at present the strain NAS6G6, Paenibacillus polymyxa, most preferably, at present the strain PKB1, Penicillium bilaiae at present, more preferably still, strains ATCC 22348, ATCC 20581 and ATCC 18309; Pseudomonas fluorescens, most preferably, at present the strain A506; Sphaerodes mycoparasitica, of greater
    45/79 preference, at present the strain SMCD2220.
    [036] Preference is also given to mixtures containing, as pesticide II (component 2), a biopesticide from the group (L1), most preferably selected preferably from B. amyloliquefaciens AP188, B. amyloliquefaciens ssp . plantarum MBI600, B. amyloliquefaciens ssp. plantarum QST-713, B. pumilus INR-7, B. pumilus QST 2808, B. simplex ABU 288, B. subtilis FB17, and Paenibacillus alvei NAS6G6.
    [037] According to an embodiment of the mixtures of the present invention, at least one pesticide II is Bacillus amyloliquefaciens ssp. plantarum MBI600. These mixtures are especially suitable for soy.
    [038] According to another embodiment of the mixtures of the present invention, at least one pesticide II is B. pumilus INR-7. These mixtures are especially suitable for soy and corn.
    [039] According to another embodiment, at least one Bacillus simplex II pesticide is preferably B. simplex ABU 288. These mixtures are especially suitable in soy and corn.
    [040] According to another embodiment, at least one pesticide II is Bacillus subtilis, preferably the strain Bacillus subtilis FB17.
    [041] According to an embodiment of the mixtures of the present invention, at least one pesticide II is selected from Bacillus amyloliquefaciens AP-136, B. amyloliquefaciens AP-188, B. amyloliquefaciens AP-218, B. amyloliquefaciens AP- 219, B. amyloliquefaciens AP-295, B. amyloliquefaciens spp. plantarum FZB24, B. amyloliquefaciens ssp. plantarum FZB42, B. amyloliquefaciens ssp. plantarum D747, B. amyloliquefaciens ssp. plantarum MBI600, B. amyloliquefaciens spp. plantarum GB03, B. amyloliquefaciens spp. plantarum QST-713, B. mojavensis AP-209, B. pumilus GB34, B. pumilus INR-7, B. pumilus KFP9F, B. pumilus QST 2808, B. pumilus GHA 180, B. simplex ABU 288, B. solisalsi AP-217, B. subtilis CX-9060, B.
    46/79 subtilis FB17e B. subtilis GB07. These mixtures are especially suitable for soybeans and corn, especially for seed treatment.
    [042] According to an embodiment of the mixtures of the present invention, at least one pesticide II is Coniothyrium minitans CON / M / 9108. These mixtures are especially suitable for seed and / or soil treatment.
    [043] According to another embodiment, at least one pesticide II is selected from Pseudomonas spp., Preferably selected from P. chloraphis, most preferably, at present the strain MA 342 and Pseudomonas sp. DSM 13134; P. fluorescens at present, most preferably still, selected from strains A506, WCS 374 and PF-5; and P. putida in the present, most preferably the strain ATCC 202153.
    [044] The present invention also relates to mixtures in which at least one pesticide II is selected from the fungus species Muscodor albus, preferably from the strains SA-13 and QST 20799, which are especially suitable for the treatment of soil and seeds against soil pathogens and / or nematodes.
    [045] Preference is also given to mixtures containing, as pesticide II (component 2) a biopesticide from the group (L2), preferably selected from chitosan (hydrolysis), methyl jasmonate, cis-jasmine, laminarin , extract of Reynoutria sachalinensis and tea tree oil; most preferably, methyl jasmonate and cis-jasmine.
    [046] Preference is also given to mixtures containing, as pesticide II (component 2), a biopesticide from the group (L3), preferably selected from Agrobacterium radiobacter, preferably at present the K1026 strain, Bacillus firmus , preferably, at present the strain I 1582, Bacillus thuríngiensis ssp. kurstaki, preferably in the present strain SB4, Beauvería bassiana, preferably in the present selected from the
    47/79 strains GHA, h123, DSM 12256 and PPRI 5339; Burkholderia sp. and, preferably, at present the strain A396, Metarhizium anisopliae var. acridum, preferably in the present strain IMI 330189, M. anisopliae, preferably in the present selected from strains FI-985, FI-1045, F52 and ICIPE 69; Paecilomyces lilacinus, preferably in the present selected from strains 251, DSM 15169 and BCP2, Paenibacillus popilliae, preferably in the present selected from strains Dutky 1940, KLN 3 and Dutky 1; Pasteuria nishazawa and, preferably, the PN1 strain at present.
    [047] Preference is also given to mixtures containing, as pesticide II (component 2) a biopesticide from the group (L3), most preferably from Bacillus thuringiensis ssp. kurstaki SB4, B. bassiana DSM 12256, B. bassiana PPRI 5339, Paecilomyces lilacinus DSM 15169, P. lilacinus BCP2, P. lilacinus 251, Paenibacillus popilliae Dutky-1940, P. popilliae KLN 3 and P. popilliae Dutky 1.
    [048] According to another embodiment, at least one pesticide II is Beauveria bassiana PPRI 5339.
    [049] According to another embodiment, at least one pesticide II is Bacillus firmus, preferably spores of the CNCM 1-1582 strain, preferably useful for treating soybean and corn seeds against nematodes and insects .
    [050] According to another embodiment, at least one pesticide II is Bacillus cereus, preferably the spores of CNCM 1-1562, preferably useful for the treatment of soybean and corn seeds against nematodes and insects .
    [051] According to another embodiment, at least one pesticide II is a mixture of spores of B. firmus and B. cereus, preferably the mixtures of strains spores mentioned above CNCM 1-1582 and CNCM I1562, of preferably useful for the treatment of soybean and corn seeds
    48/79 against nematodes and insects.
    [052] According to another embodiment, at least one pesticide II is selected from Bacillus t. ssp. kurstaki, preferably from strains EG 2348, SB4 and ABTS-351 (HD-1), in particular B. t. ssp. kurstaki SB4. These strains are used to control lepidopteran larvae, but without noctuidae.
    [053] According to an embodiment of the mixtures of the present invention, at least one pesticide II is selected from Bacillus firmus CNCM 1-1582, Paecilomyces lilcinus 251, Pasteuria Nishizawa PN1 and Burkholderia sp. A396 which has nematicidal, acaricidal and / or insecticidal activity. These mixtures are especially suitable for soybeans and corn, especially for seed treatment.
    [054] Preference is also given to mixtures containing, as pesticides II (component 2) a biopesticide from the group (L4), preferably selected from methyl jasmonate, black wattle extract, grapefruit seed extract and cellulose , catnip oil, Neem oil, Quillay extract and Tagetes oil, especially methyl jasmonate or water-based Quillay extract.
    [055] Preference is also given to mixtures containing, as pesticide II (component 2) a biopesticide from the group (L5), preferably selected from Azospirillum amazonense, A. brasilense, A. lipoferum, A. irakense , A. halopraeferens, Bradyrhizobium sp. (Vigna), B. elkanii, B. japonicum Paenibacillus alvei, Penicillium bilaiae, Rhizobium leguminosarum bv. phaseoli, P. I. bv. trifolii, R. I. bv. viciae and Sinorhizobium meliloti.
    [056] Preference is also given to mixtures containing, as pesticide II (component 2) a biopesticide from the group (L5) selected from Bradyrhizobium sp. (Vigna) PNL1, B. japonicum TA-11, Paenibacillus
    49/79 I targeted NAS6G6, Peniciillium bilaiae strains ATCC 18309, ATCC 20851 and ATCC 22348; Rhizobium leguminosarum bv. phaseoli P1NP3Cst, R. I. bv. phaseoli RG-B10, R. I. bv. trifolii RP113-7, R. I. bv. viciae SU303, R. I. bv. viciae WSM1455 and Sinorhizobium meliloti; most preferred, selected from Bradyrhizobium sp. (Vigna) PNL1 and B. japonicum TA-11.
    [057] The present invention also relates to mixtures, in which at least one pesticide II is selected from B. japonicum and B. elkanii and further comprises a pesticide III, in which pesticide III is selected from jasmonic acid, its salts and derivatives, preferably methyl jasmonate or cis-jasmine.
    [058] The present invention also relates to mixtures in which at least one pesticide II is selected from Bacillus amyloliquefaciens ssp. plantarum MBI600, B. amyloliquefaciens ssp. plantarum FZB24, B. amyloliquefaciens ssp. plantarum FZB42, B. amyloliquefaciens ssp. plantarum D747, B. amyloliquefaciens ssp. plantarum QST-713, B. firmus CNCM 1-1582, B. pumilus GHA 180, B. pumilus INR-7, B. pumilus QST 2808, B. simplex ABU 288, B. subtilis FB17, Burkholdería sp. A396, Coniothyríum minitans CON / M / 91-08, Paecilomyces lilacinus 251, Paenibacillus alvei NAS6G6, Pasteuría nishizawae PN1, P. bilaiae ATCC 18309, P. bilaiae ATCC 20851, P. bilaiae ATCC 22348; cis-jasmine, methyl jasmonate and harpin protein.
    [059] Preference is also given to mixtures containing, as component (2) at least one pesticide II from the groups (A) to (H), (N) and (O) selected from:
    (A) complex III inhibitors at site Q o selected from: pyraclostrobin, azoxystrobin, picoxystrobin, trifloxystrobin, dimoxystrobin, enestroburin, phenaminstrobin, fluoxastrobin, cresoxim-methyl, mandestrobin, metominostrobin, pyrethostrobin, pyrametostrostrin;
    50/79
    - complex II inhibitors selected from: fluxapiroxad, boscalid, benzovindiflupir, penflufen, pentiopirad, silkxane, fluopyram, bixafen, flutolanil, isofetamid, isopirasame; carboxine, benodanil, fenfuram, flutolanil, furametpir, mepronil, oxycarboxine, tifluzamide;
    - another inhibitor of respiration: siltiofam;
    (B) DMI fungicides selected from: ipconazole, diphenoconazole, protioconazole, prochloraz, triticonazole, flutriafol, cyproconazole, diniconazole, diniconazole-M, fluquinconazole, flusilazole, hexaconazole, imazalil, imibenconazole, tincolazole, methanol, methanol uniconazole;
    (C) nucleic acid synthesis inhibitors selected from: metalaxyl, mefenoxam;
    (D) Cell division and cytoskeleton inhibitors selected from: thiabendazole, thiophanate-methyl, carbendazim; etaboxam;
    (F) MAP / histidine kinase inhibitors: fludioxonil;
    (G) inhibitors of lipid membrane synthesis selected from: dimetomorf, zoxamide, flumorf, mandipropamide, pyrimorf, bentiavalicarb, iprovalicarb, oxatiapiproline, valifenalate;
    (H) Inhibitors with multilocated action selected from:
    tirame, ziram;
    (N) Herbicides selected from: glyphosate and dicamba;
    (O) insecticides selected from:
    - organo (uncle) phosphates selected from: acephate, chlorpyrifos,
    - carbamates selected from: metiocarb, tiodicarb;
    - pyrethroids selected from: teflutrin, bifenthrin, cypermethrin, alpha-cypermethrin, cyfluthrin, beta-cyfluthrin, lambda-cyhalothrin, deltamethrin, sphenolvalerate, etofenprox, fenvalerate, flucitrinate, permethrin;
    - macrocyclic lactone insecticides selected from:
    51/79 abamectin, spinosad;
    - nicotinic receptor agonist / antagonist compounds selected from: clothianidin, imidacloprid, thiametoxam, dinotefuran, acetamipride, flupiradifurone, thiacloprid, triflumezopyrim, nitenpiram, sulfoxaflor;
    - GABA antagonist compounds selected from: fipronil, etiprol, vaniliprol, pirafluprol, pyriprol, 5-amino-1- (2,6dichloro-4-methyl-phenyl) -4-sulfinamoyl-1H-pyrazole- amide 3-carbothioic;
    - ryanodine receptor inhibitors selected from: clorantraniliprol, cyantraniliprol, and flubendiamide.
    [060] Preference is also given to mixtures that contain, as component (2) at least one pesticide II from pyraclostrobin, azoxystrobin, trifloxistobine; fluxpyroxad, penflufen, silkxane, fluopyram; ipconazole; oxatiapiproline, valifenalate; fipronil; imidacloprid; chlorantraniliprol; and cyantraniliprol.
    [061] Mixtures of the present invention comprising TJ1000 and / or as a pesticide II a microbial pesticide from groups (L1), (L3) and (L5) can be formulated as an inoculant for a plant. The term "inoculant" means a preparation that includes a culture isolated from a microbial pesticide and, optionally, a vehicle, which may include a biologically acceptable medium.
    [062] At present, microbial pesticides can be supplied in any physiological state as active or inactive. Inactive microbial pesticides can be supplied, for example, frozen, dried, or lyophilized or partially dried (procedures for the production of partially dried organisms are provided in publication WO 2008/002371) or in the form of spores.
    [063] Microbial pesticides II selected from groups (L1), (L3) and (L5) and from a TJ1000 strain used as an organism in a
    52/79 active state can be released in a growth medium without any additional additives or materials or in combination with the appropriate nutrient mixtures.
    [064] TJ1OOO is preferably delivered and formulated in an inactive stage, preferably in the form of spores, most preferably in the form of chlamydospores.
    [065] Mixtures and compositions according to the present invention are suitable as fungicides. They are distinguished by an excellent efficacy against a wide spectrum of phytopathogenic fungi, including soil fungi, especially in the classes of the Plasmodiophoromycetes, Peronosporomycetes (syn. Oomicetes), Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes and Deuteromyietes (syn. ). Some are systemically effective and can be used to protect crops, such as foliar fungicides, seed coating fungicides and soil fungicides. In addition, they are suitable for combating harmful fungi, which occur, inter alia, in wood or in plant roots.
    [066] Mixtures and compositions, according to the present invention, are especially important for the control of a variety of pathogenic fungi in various cultivated vegetables; and on the propagation material of the plant, such as the seeds, and the culture material of these plants.
    [067] Preferably, the mixtures and compositions of the present invention are used to control a multiplicity of fungi in crops, such as potatoes, sugar beets, tobacco, wheat, rye, barley, oats, rice, corn, cotton, soy, rapeseed, vegetables, sunflower, coffee or sugar cane; fruits; vineyards; ornamental vegetables; or vegetables, such as cucumbers, tomatoes, beans or pumpkins.
    53/79 [068] The term “plant propagating material should be understood as designating all the generative parts of the plant, such as seeds and vegetative plant material such as grafts and tubers (for example, potatoes), which can be used for plant multiplication. This includes seeds, roots, fruits, tubers, bulbs, rhizomes, stems, shoots and other parts of the plants, including seedlings and young plants, which will be transplanted after germination, or after emergence from the soil.
    [069] Preferably, the treatment of vegetable propagating materials with the mixtures of the present invention and the compositions of the present invention, respectively, are used to control a multiplicity of fungi in cereals, such as wheat, rye, barley and oats; rice, corn, cotton and soy.
    [070] The term cultivated vegetables ”should be understood as including plants that have been modified through reproduction, mutagenesis or genetic engineering, including, but not limited to, biotechnological agricultural products on the market or in development (cf. http: // ceragmc. org /, see database of GM crops). Genetically modified vegetables are vegetables in which the genetic material has been modified in this way, through the use of recombinant DNA techniques that in natural circumstances cannot be easily obtained through cross-breeding, mutations or natural recombination. Typically, one or more genes have been integrated into the genetic material of a genetically modified plant, to enhance certain properties of the plant.
    [071] The mixtures and compositions of the present invention are especially suitable for the control of the following plant diseases:
    - Albugo spp. (white rust) in ornamental plants,
    54/79 vegetables (for example, A. Candida) and sunflowers (for example, A. tragopogonis); Alternaria spec. (Alternaria leaf spot) in vegetables, rapeseed (A. brassicola or brassicae), sugar beets (A. tenuis), fruits, rice, soy, potatoes (for example, A. solani or A. altemata), tomatoes (for example , A. solani or A. altemata) and wheat; Aphanomyces spp. sugar beets and vegetables; Ascochyta spp. in cereals and vegetables, for example, A. tritici (anthracnose) in wheat and A. hordei in barley; Bipolaris and Drechslera spp. (teleomorph: Cochliobolus spp.) in corn (for example, D. maydis), cereals (for example, B. sorokiniana: brown spot), rice (for example, B. oryzae) and lawns; Blumeria (formerly Erysiphe) graminis (powdery mildew) in cereals (for example, wheat or barley); Botrytis cinerea (teleomorph: Botryotinia fuckeliana: gray mold) in fruits and berries (for example, strawberries), vegetables (for example, lettuce, carrots, celery and cabbage), rapeseed, flowers, vines, forest vegetables and wheat; Bremia lactucae (downy mildew) on lettuce; Ceratocystis (syn. Ophiostoma) spp. (rotting or wilt) in broad-leaved and evergreen trees, for example, C. ulmi (Dutch elm disease) in elm trees; Cercospora spp. (Cercospora leaf spots) on maize, rice, sugar beet (for example, C. beticola), sugar cane, vegetables, coffee, soy (for example, C. sojina or C. kikuchii) and rice; Cladosporium spp. in tomatoes (for example, C. fulvum: leaf mold) and cereals, for example, C. herbarum (black grain) in wheat; Claviceps purpurea (rust) in cereals; Cochliobolus (anamorph: Helminthosporium de Bipolaris) spp. (leaf spots) in corn (C. carbonum), cereals (for example, C. sativus, anamorph: B. sorokiniana) and rice (for example, C. miyabeanus, anamorph: H. oryzae); Colletotrichum (teleomorph: Glomerella) spp. (Anthracnose) on cotton (for example, C. gossypii), corn (for example, C. graminicola), red fruits, potatoes (for example, C. coccodes: black dot), beans (for example, C. lindemuthianum) and soy (for example, C. truncatum or C gloeosporioides.); Corticium spp., For
    55/79 example, C. sasakii (sheath rust) in rice; Corynespora cassiicola (leaf spots) in soy and ornamental vegetables; Cycloconium spp., For example, C. oleaginum in olive trees; Cylindrocarpon spp. (for example, the decline in cancer of the fruit tree or young vine, teleomorph: Nectría or Neonectria spp.) in fruit trees, vines (for example, C. liriodendri, teleomorph: Neonectria liriodendri: Black foot disease) and ornamental plants ; Dematophora (teleomorph: Rosellinia) necatrix (stem and root) in soybean; Diaporthe spp., For example, D. phaseolorum (tipping) in soybean; Drechslera (syn Helminthosporium, teleomorph: Pyrenophora) spp. in corn, cereals, such as barley (for example, D. teres, reticular spot) and wheat (for example, D. tritici-repentis: local spot), rice and peat; Esca (death, stroke) in vines, caused by Formitiporia (syn Phellinus.) Punctata, F. mediterrânea, Phaeomoniella chlamydospora (formerly Phaeoacremonium chlamydosporum), Phaeoacremonium aleophilum and / or Botryosphaeria obtusa: Elsinoe spp. in pigeons (E. pyri), soft fruits (E. veneta: anthracnose) and vines (E. ampelina: anthracnose); Entyloma oryzae (leaf coal) in rice; Epicoccum spp. (black mold) in wheat; Erysiphe spp. (powdery mildew) on beet (E. betae), vegetables (for example, E. pisi), such as cucurbits (for example, E. cichoracearum), cabbages, rapeseed (for example, E. cruciferarum): Eutypa lata (cancer or death Eutypa, anamorph: Cytosporina lata, syn Libertella blepharis) in fruit trees, vineyards and ornamental forests; Exserohilum (syn. Helminthosporium) spp. in corn (for example, E. turcicum.): Fusarium (teleomorph: Gibberella) spp. (wilt or root rot) in various vegetables, such as F. graminaarum or F. culmorum (root rot, scab or gibberellas) on the inside of cereals (eg wheat or barley), F. oxysporum in tomatoes, F. solani in soybean and F. verticillioides in corn; Gaeumannomyces graminis (all) of cereals (for example, wheat or barley) and corn; Gibberella spp. in cereals (for example,
    56/79
    G. zeaé} and rice (for example, G. fujikuror. Bakanae disease); Glomerella cingulata on vines, pome and other vegetables and G. gossypii on cotton; rice grain stain complex; Guignardia bidwellii (black rot) on vines; Gymnosporangium spp. in vegetables and pink junipers, for example, G. sabinae (rust) in pears; Helminthosporíum spp. (syn Drechslera, teleomorph: Cochliobolus) in corn, cereals and rice; Hemileia spp., For example, H. vastatrix (coffee rust) in coffee; Isariopsis clavispora on vines (syn Cladosporium vitis) ·, Phaseolina Macrophomina (syn phaseoli) (stem and root rot) in soybeans and cotton; Microdochium (syn Fusarium) nivale (snow-pink mold) in cereals (for example, wheat or barley); Microsphaera diffusa (powdery mildew) in soybean; Monilinia spp., For example, M. laxa, M. fructicola and M. fructigena (flower and branch rust, brown rot) in stone fruits and other rosaceous vegetables; Mycosphaerella spp. in cereals, bananas, red fruits and mold nuts, such as, for example, M. graminicola (anamorph: Septoria tritici, Septoria spot) in wheat; Peronospora spp. (Downy mildew) on cabbage (for example, P. brassicaé), rapeseed (for example, P. parasitica), onion (for example, P. destructor), tobacco (P. tabacina) and soy (for example, P. manshuríca) ; Phakopsora pachyrhizi and P. meibomiae (soybean rust) in soybean; Phialophora spp., For example, on vines (for example, P. tracheiphila and P. tetraspora) and soy (for example, P. gregata: rot); Phoma lingam (root and rot) in rapeseed and cabbage and P. betae (root rot, leaf spot and tipping) in beet; Phomopsis spp. in sunflowers, vines (for example, P. viticola: leaf spot) and soy (for example, rot: P. phaseoli, teleomorph: Diaporthe phaseolorum); Physoderma maydis (brown spots) of corn; Phytophthora spp. (wilt, root, leaves, fruits and stem) in various vegetables, such as paprika and cucurbits (for example, P. capsici), soy (for example, P. megasperma, syn. P. soye), potatoes and tomatoes ( for example, P. infestans: late blight) and broad-leaved trees (for
    57/79 example, P. ramorum: sudden death of the oak); Plasmodiophora brassicae (root club) on cabbage, rapeseed, radish and other vegetables; Plasmopara spp., For example, P. viticola (grape downy mildew) on vines and P. halstedii on sunflowers; Podosphaera spp. (Powdery mildew) in rosaceous vegetables, hops, pome and red fruits, for example, P. leucotricha in apples; Polymyxa spp., For example, in cereals, such as barley and wheat (P. graminis) and beet (P. betae) and their communicable viral diseases; Herpotrichosides Pseudocercosporella (spot, teleomorph: Tapesia yallundae) in cereals, for example, wheat or barley; Pseudoperonospora (downy mildew) on various vegetables, for example, P. cubensis on cucurbits or P. humili on hops; Tracheiphila Pseudopezicula (red fire disease or brenner rot, anamorph: Phialophora) on the vines; Puccinia spp. (oxidizes) in various vegetables, for example, P. triticina (brown rust or leaf), P. stríiformis (yellow or striped rust), P. hordei (dwarf rust), P. graminis (black stem or rust) or P. recondite (brown rust or leaves) in cereals, such as, for example, wheat, barley or rye, and asparagus (for example, P. asparagi); Pyrenophora (anamorph: Drechslera) trichotrepentis (brown spot) in wheat or P. teres (reticular spot) in barley; Pyrícularia spp., For example, P. oryzae (teleomorph: Magnaporthe grisea, blast) in rice and P. grisea in lawns and cereals; Pythium spp. (tipping) on grass, rice, corn, wheat, cotton, rapeseed, sunflower, soy, beans, beets, vegetables and other vegetables (for example, P. ultimum or P. aphanidermatum); Ramularia spp., For example, R. collo-cygni (Ramularia leaf spots, physiological leaf spots in barley) and R. beticola in sugar beet; Rhizoctonia spp. on cotton, rice, potatoes, grass, corn, rapeseed, potatoes, beets, vegetables and various other vegetables, for example, R. solani (root and rot) on soybeans, R. solani (sheath rust) rice or R. cerealis ( spring rust Rhizoctonia) wheat or barley; Rhizopus stolonifer (black mold, soft rot) in strawberries,
    58/79 carrots, cabbage, vines and tomatoes; Rhynchosporíum secalis (scald) in barley, rye and triticale; Sarocladium oryzae and S. attenuatum (rot sheath) in rice; Sclerotinia spp. (white rot or mold) in vegetables and field crops, such as rapeseed, sunflowers (for example, S. sclerotiorum) and soy (for example, S. rolfsii or S. sclerotiorum) ', Septoría spp. in various vegetables, for example, S. glycines (brown spot) in soy, S. tritici (Septoría spot) in wheat and S. (syn Stagonospora.) Nodorum (Stagonospora spot) in the inner part of the cereals; Uncinula (syn Erysiphe) Necator (powdery mildew, anamorph: Oidium tuckerí) on the vines; Setospaería spp. (leaf spot) in corn (for example, S. turcicum, syn Helminthosporium turcicum) and peat; Sphacelotheca spp. (Soot) in corn, (for example, S. reiliana: charcoal head), sorghum and sugar cane; Sphaerotheca fuliginea (powdery mildew) in cucurbits; Underground spongospora (scabies powder) in potatoes and viral, communicable diseases; Stagonospora spp. in cereals, for example, S. nodorum (Stagonospora spot, teleomorph: [syn Phaeosphaeria] Leptosphaeria nodorum) in wheat; Synchytríum endobioticum in potatoes (potato wart disease); Taphrina spp., For example, T. deformante (leaf wave disease) in peaches and T. pruni (plum pocket) in plums; Thielaviopsis spp. (black root rot) in tobacco, pome, vegetables, soy and cotton, for example, T. basicola (syn Chalara elegans); Tilletia spp. (common or stinking coal weevil) in cereals, such as, for example, T. tritici (syn T. carie, wheat bowl) and controversial T. (dwarf bowl) in wheat; Typhula Incamata (snow gray mold) in barley or wheat; Urocystis spp., For example, U. occult (stem rust) in rye; Uromyces spp. (rust) in vegetables, such as beans (for example, U. appendiculatus, syn U. phaseoli) and beets (for example, U. betae); Ustilago spp. (loose rust) in cereals (for example, U. nuda and U. avaenae), corn (for example, U. maydis: corn rust) and sugar cane; Venturia spp. (scabies) in apples and pears (for example, V. inaequalis); and
    59/79
    Verticillium spp. (Wilt) in various vegetables, such as ornamental fruits and vegetables, vines, red fruits, vegetables and crops, for example, V. dahliae in strawberries, rapeseed, potatoes and tomatoes.
    [072] Mixtures and compositions according to the present invention are also suitable as bactericides. They are distinguished by excellent efficacy against a wide spectrum of phytopathogenic fungi, including soil fungi, especially in the classes of the Agrobacterium, Clavibacter, Corynebacterium, Erwinia, Leifsonia, Pectobacterium, Pseudomonas, Ralstonia, Xanthomonas (eg Xanthomonas oryzae causing bacterial stain on rice) and Xylella; preferably, Erwinia; most preferably, Erwinia amylovora causing bacterial fire on apples, pears and other members of the Rosaceae family.
    [073] The mixtures according to the present invention and their compositions, respectively, are also suitable for the control of harmful fungi in the protection of stored or harvest products.
    [074] Mixtures and compositions according to the present invention are especially important for the control of a wide variety of insects and other phytopathogenic pests (for example, lepidoptera, beetles, dipterans, tripods, bedbugs, hemiptera, homoptera, termites, orthopterans, arachnids and nematodes) in various cultivated vegetables.
    [075j Preferably, the mixtures and compositions of the present invention are used to control a multiplicity of fungi in crops, such as potatoes, sugar beets, tobacco, wheat, rye, barley, oats, rice, corn, cotton, soybeans , rapeseed, vegetables, sunflower, coffee or sugar cane; fruits; vineyards; ornamental vegetables; or vegetables, such as cucumbers, tomatoes, beans or pumpkins.
    [076] The mixtures of the present invention and their compositions, respectively, are especially suitable for the control of the following
    60/79 insects of the order
    - of lepidopterans (Lepidoptera), for example, Agrotis ypsilon, Agrotis segetum, Alabama argillacea, Anticarsia gemmatalis, Argyresthia conjugella, Autographa gamma, Bupalus piniarius, Cacoecia murinana, Capua reticulana, Cheimatobia brumata, Chorea pomonella, Dendrolimus pini, Diaphania nitidalis, Diatraea grandiosella, Earias insulana, Elasmopalpus lignosellus, Eupoecilia ambiguella, Evetria bouliana, Underground feltia, Galiena mellonella, Grapholitha funebrana, Grapholitha molesta, Heliothisis hibiscus, Heliothisis, Hyphantria cunea, Hyponomeuta malinellus, Keifería lycopersicella, Lambdina fiscellaria, Laphygma exigua, Leucoptera coffeella, Leucoptera scitella, Lithocolletis blancardella, Lobesia botrana, Loxostege sticticalis, Lymantria dispar, Lymantria pomeranica, Lymantria monacha, Lyacostria monacha, Lymantria monacha a nubilalis, Panolis flammea, Pectinophora gossypiella, Peridroma saucia, Phalera bucephala, Phthorimaea operculella, Phyllocnistis citrella, Pieris brassicae, Plathypena scabra, Plutella xylostella, Pseudoplusia incluens, Rhyacionaisotropidae, Scrobogaa, Scobora, Scral , Spodoptera litura, Thaumatopoea pityocampa, Tortrix viridana, Trichoplusia ni and Zeiraphera canadensis,
    - beetles (coleopterans), for example, Agrilus sinuatus, Agríotes lineatus, Agriotes obscurus, Amphimallus solstitialis, Anisandrus dispar, Anthonomus grandis, Anthonomus pomorum, Aphthona euphoridae, Athous haemorrhoidalis, Atomaria linearis, Blomtopha Bruchus pisorum, Bruchus lentis, Byctiscus betulae, Cassida nebulosa, Cerotoma trifurcata, Cetonia aurata, Ceuthorrhynchus por Consequilis, Ceuthorrhynchus napi, Chaetocnema
    61/79 tibialis, Conoderus vespertinus, Cróoceris asparagi, Ctenicera ssp., Diabrotica longicomis, Diabrotica semipunctata, Diabrotica 12-punctata Diabrotica speciosa, Diabrotica virgifera, Epilachna varivestis, Epitrix hietisis, hutipis, eutis, typographus, Lema bilineata, Lema melanopus, Leptinotarsa decemlineata, Limonius califomicus, Lissorhoptrus oryzophilus, Melanotus communis, aeneus Meligethes, Melolontha hippocastani, Melolontha melolontha, Oulema oryzae, Ortiorrhynchus sulcatus, Otiorrhynchus ovatus, Phaedon cochleariae, Phyllobius pyri, Phyllotre ta chrysocephala, Phyllophaga sp., Phyllopertha horticola, Phyllotreta nemorum, Phyllotreta striolata, Popillia japonica, Sitona lineatus and Sitophilus granaria,
    - Diptera (Diptera), for example, Aedes aegypti, Aedes vexans, Anastrepha ludens, Anopheles maculipennis, Ceratitis capitata, Chrysomya bezziana, Chrysomya hominivorax, Chrysomya macellaria, Contarinia sorghicola, Cordylobia anthropopacea, Dili, Culex brassicae, Fannia canicularis, intestinal Gasterophilus, Glossina morsitans, Haematobia irritans, Haplodiplosis equestris, Hylemyia platura, Hypoderma lineata, Liriomyza sativae, Liriomyza trifolii, Lucilia caprina, Lucilia cuprina, Lucilia sericata, storica, destructive, Oestrus ovis, Oscinella frita, Pegomya hysocyami, Phorbia antiqua, Phorbia brassicae, Phorbia coarctata, Rhagoletis cerasi, Rhagoletis pomonella, Tabanus bovinus, Tipula oleracea and Tipula paludosa,
    - tripods (Thysanoptera), for example, Frankliniella fusca, Frankliniella occidentalis, Frankliniella tritici, Scirtothrips citri, Thrips oryzae, Thrips palmi and Thrips tabaci,
    - the hymenopterans (Hymenoptera), for example, Acromyrmex ambuguus, Acromyrmex crassispinus, Acromyrmex heiery, Acromyrmex
    62/79 landolti, Acromyrmex subterraneus, Athalia rosae, Atta capiguara, Atta cephalotes, Atta laevigata, Atta robusta, Atta sexdens, Atta texana, Hoplocampa minuta, Hoplocampa testudinea, Monomorium pharaonis, Solenopsis geminata, Solenopsis inveminta and Solenopsis inveminta
    - heteropterans (Heteroptera), for example, Acrostemum hilare, Blissus leucopterus, Cyrtopeltis notatus, Dichelops furcatus, Dysdercus cingulatus, Dysdercus intermedius, Euchistos heros, Eurygaster integríceps, Euschistus impictiventris, Lyptoglossis, Lympho- Quadrata, Piezodorus guildini, Solubea insularis and Thyanta perditor,
    - Hemiptera and Homoptera, for example, Acrostemum hilare, Blissus leucopterus, Cyrtopeltis notatus, Diaphorína citri, Dysdercus cingulatus, Dysdercus intermedius, Eurygaster integríceps, Euschistus impictiventrís, Leptoglossus insylisis, Lygisis, Lygisis, Lygisis , Thyanta perditor, Acyrthosiphon onobrychis, Adelges larchis, Aphidula nasturtii, Aphis fabae, Aphis forbesi, Aphis pomi, Aphis gossypii, Aphis grossularíae, Aphis schneiderí, Aphis spiraecola, Aphis Sambuci, Acyrthosipachyachis, Brachycai persicae, Brachycaudus prunicola, Brevicoryne brassicae, Capitophorus homi, Cerosipha gossypii, Chaetosiphon fragaefolii, Cryptomyzus ribis, Dreyfusia nordmannianae, Dreyfusia piceae, Dysaphis radicola, Dysaulacorthy Dysaysachne pysudosis Macrosiphon rosae, Megoura viciae, Melanaphis pyraríus, Metopolophium dirhodum, Myzodes persicae, Myzus ascalonicus, Myzus cerasi, Myzus varíans, Nasonovia ribisnigrí, Nilaparvata lugens, Pemphigus bursarius, Perkinsiella saccharícida, Rumania, Pyrodal, Pyrodal, Pyrodal
    63/79
    Rhopalosiphum padi, insertum Rhopalosiphum, Sappaphis suitcase Sappaphis mali, graminum Schizaphis, Schizoneura lanuginosa, Sitobion avenae, Trialeurodes vaporariorum, Toxoptera aurantiiand, Viteus vitifolii, Cimex lectularius, Cimex hemipterus, senilis Reduvius, Triatoma spp., And Arilus crítatus,
    - termites (Isoptera), for example, Calotermes flavicollis, Comitermes cumulans, Heterotermes tenuis, Leucotermes flavipes, Neocaprítemes opacus, Procomitermes triacifer; Reticulitermes Myotis, Syntermes molestus, and Termes natalensis,
    - orthopterans (Orthoptera), for example, Acheta domestica, Blatta orientalis, Blattella germanica, Forficula, Gryllotalpa Gryllotalpa, Migratory locusta, Melanoplus bivittatus, Melanoplus femur-rubrum, Melanoplus mexicanus, Melanoplus sanguinipes, Melanoplus sprettaem, Nomadacrisasta, , Schistocerca americana, Schistocerca peregrina, Stauronotus maroccanus and Tachycines asynamorus,
    - arachnids, such as arachnids, for example, from the Argasidae, Ixodidae and Sarcoptidae families, such as Amblyomma americanum, Amblyomma variegatum, Argas persicus, Boophilus annulatus, Boophilus decoloratus, Boophilus microplus, Dermacentor silvarum, Hyalomomorum, Hyalomomorum, Hyalomom , Omithodorus moubata, Otobius megnini, Dermanyssus gallinae, Psoroptes ovis, Rhipicephalus appendiculatus, Rhipicephalus evertsi, Sarcoptes scabiei, and Eriophyidae spp. such as Aculus schlechtendali, Phyllocoptrata oleivora and Eriophyes sheldoni; Tarsonemidae spp. such as Phytonemus pallidus and Polyphagotarsonemus latus; Tenuipalpidae spp. such as Brevipalpus phoenicis; Tetranychidae spp. such as Tetranychus cinnabarinus, Tetranychus kanzawai, Tetranychus pacificus, Tetranychus telarius and Tetranychus urticae, Panonychus ulmi, Panonychus citri, and Oligonychus pratensis.
    [077] In particular, the mixtures of the present invention are
    64/79 suitable for combating parasites of the orders Coleoptera, Lepidoptera, Thysanoptera, Homoptera, Isoptera, and Orthoptera.
    [078] They are also suitable for the control of the following parasitic plant nematodes, such as root nodule nematodes, Meloidogyne arenaria, Meloidogyne chitwoodi, Meloidogyne exigua, Meloidogyne hapla, Meloidogyne incognita, Meloidogyne javanica and another Meloidogyne species; cyst nematodes, Globodera rostochiensis, Globodera pallida, Globodera tabacum and other species of Globodera, Heterodera avenae, Heterodera glicines, Heterodera schachtii, Heterodera trifolii, and other species of Heterodera: seedlings and other species of anguine Anguina; stem and leaf nematodes, Aphelenchoides besseyi, Aphelenchoides fragariae, Aphelenchoides ritzemabosi and other species of Aphelenchoides; sting nematodes, Belonolaimus longicaudatus and other species of Belonolaimus; pine nematodes, Bursaphelenchus xilophilus and other species of Bursaphelenchus; ring nematodes, Criconema species, Criconemella species, Criconemoides species, Mesocriconema species; stem and bulb nematodes Ditilenchus destructor, Ditilenchus dipsaci and other Ditilenchus species, borer nematodes, Dolichodorus species; spiral nematodes, Heliocotilenchus multicinctus and other species of Helicotilenchus, Rotylenchus robustus and other species of Rotylenchus; sheath and sheathoid nematodes, Hemicycliophora species and Hemicriconemoides species; Hirshmanniella species; sandeel nematodes, Hoplolaimus Columbus, Hoplolaimus galeatus and other species of Hoplolaimus; false root nodule nematodes, Nacobbus aberrans and other species of Nacobbus; needle nematodes, Longidorus elongates and other species of Longidorus; pine nematodes, Paratylenchus species; lesions nematodes Pratylenchus brachyurus, Pratylenchus coffeae, Pratylenchus curvitatus, Pratylenchus goodeyi,
    65/79
    Pratylencus neglectus, Pratylenchus penetrans, Pratylenchus scríbneri, Pratylenchus vulnus, Pratylenchus zeae and other species of Pratylenchus; Radinaphelenchus cocophilus and other species of Radinaphelenchus; excavating nematodes, Radopholus similis and other species of Radopholus; reniform nematodes, Rotilenchus robustus and other species of Rotilenchus; Scutellonema species; short root nematodes, Trichodorus primitivus and other species of Trichodorus, species of Paratrichodorus; inhibited nematodes, Tilenchorhynchus claytoni, Tilenchorhynchus dubius and other species of Tylenchorhynchus and species Meriinius; citrus nematodes, Tylenchulus semipenetrans and other species of Tylenchulus; stylus nematodes, Xiphinema americanum, Xiphinema index, Xiphinema diversicaudatum and other species of Xiphinema; and other species of plant parasitic nematodes.
    [079] Plant propagation materials can be treated with the mixtures and compositions of the present invention, prophylactically or before planting or transplanting.
    [080] In particular, the present invention relates to a method for protecting plant propagating material against pests, wherein the plant propagating material is treated with an effective amount of a mixture of the present invention.
    [081] In a preferred embodiment, the present invention relates to a method for the protection of plant propagating material against animal pests (insects, mites or nematodes), in which the plant propagating material is treated with an amount effectiveness of a mixture of the present invention.
    [082] In an equally preferred embodiment, the present invention relates to a method for protecting plant propagating material against harmful fungi, wherein the plant propagating material is treated with an effective amount of a mixture of the present invention.
    66/79 [083] For example, for seed and soil treatment applications, it is evident that a plant suffering from fungal attack or insecticide shows reduced germination and emergence causing a weaker plant or establishment of culture and vigor, and, consequently, to a reduced yield, compared to a vegetable propagating material that has been subjected to curative or preventive treatment against the pest in question and that can grow without the damage caused by the biotic stress factor. However, the methods according to the present invention lead to an enhanced plant health, even in the absence of any biotic stress. This means that the positive effects of the mixtures of the present invention cannot be explained only by the pesticidal fungicidal activities of TJ1000 and pesticides II, but are still based on the activity profiles. Consequently, the application of the mixtures of the present invention can also be carried out in the absence of pest pressure.
    [084] The term “plant health” should be understood to indicate a condition of the plant and / or its products, which is determined by several indicators alone or in combination with each other, such as yield (eg increase in biomass) and / or increase in the content of valuable ingredients), vigor of the vegetable (for example, the improved growth of the vegetable and / or greener leaves (“green effect”)), quality (for example, the improved content or composition of certain ingredients ) and tolerance to abiotic and / or biotic stress. The indicators identified above for the health condition of a vegetable may be interdependent or may work together.
    [085] In an equally preferred embodiment, the present invention relates to a method for improving the health of vegetables grown from said plant propagation material, in which the material
    Q7 / 79 plant propagation is treated with an effective amount of a mixture of the present invention.
    [086] In an equally preferred embodiment, the present invention relates to a method for improving the health of vegetables, wherein the vegetable is treated with an effective amount of a mixture of the present invention.
    [087] Each indicator of vegetable health, such as yield, vegetable vigor, quality and vegetable tolerance to abiotic and / or biotic stress, should be understood as a preferred embodiment of the present invention, each in itself.
    [088] The present invention also relates to agrochemical compositions comprising an auxiliary and TJ1000, or a cell-free extract thereof, or at least one of its metabolites, which has pesticidal activity, and / or a TJ1000 mutant which has the pesticidal activity and produces at least one pesticidal metabolite as defined herein, or a pesticidal metabolite or extract of the mutant and at least one pesticide II according to the present invention.
    [089] The agrochemical composition comprises an effective fungicidal or insecticidal amount of TJ1000 and at least one pesticide II. This amount can vary over a wide range and depends on several factors, such as the species of the fungus to be controlled, the plant or treated material grown and the climatic conditions.
    [090] In the case of mixtures comprising microbial pesticides selected from groups II (L1), (L3) and (L5), the microorganisms, as used in accordance with the present invention, can be grown continuously or batchwise in the batch process or in the repeated batch or batch feed process. A review of known cultivation methods will be
    68/79 found in the book by Chmiel (Bio-Prozesstechnik 1. Einführung in die Bioverfahrenstechnik (Gustav Fischer Verlag, Stuttgart, 1991)) or in the textbook by Storhas (Bioreaktoren und períphere Einrichtungen (Vieweg Verlag, Braunschweig / Wiesbaden, 1994)) . The culture medium used must meet the requirements of the particular strains in an appropriate manner. Descriptions of the culture media for various microorganisms are provided in the “Manual of General Bacteriology Methods” manual of the American Society of Bacteriology (Washington DC, USA, 1981). Information on medium optimization can be found in the book “Applied Microbiol. Physiology. The Practice Approach (Publ. P.M. Rhodes, P.F. Stanbury, IRL Press (1997) p. 53-73, ISBN 0 19 963577 3).
    [091] According to one embodiment, the individual components of the composition according to the present invention, such as parts of a set or parts of a binary or ternary mixture can be mixed by the user himself, in a spray tank or any other type of container used for applications (eg seed treatment battery, seed granulating machines, backpack sprayer) and other auxiliaries can be added, if appropriate. When living microorganisms, such as pesticides and TJ1000 II from groups (L1), (L3) and (L5), are part of that set, care must be taken that the selection and quantities of components (for example, chemical agents pesticides) and other auxiliaries do not influence the viability of microbial pesticides in the composition mixed by the user. Especially for bactericides and solvents, compatibility with the respective microbial pesticide needs to be taken into account.
    [092jConsequently, an embodiment of the present invention is a kit for the preparation of a useful pesticidal composition, the kit comprises (a) a composition comprising a component (1),
    69/79 as defined herein and at least one auxiliary; and (b) a composition comprising component (2) as defined herein and at least one auxiliary.
    [093] At least one pesticide II can be converted to the usual types of agrochemical compositions, for example, solutions, emulsions, suspensions, dust, powders, pastes, granules, presses, capsules, and mixtures thereof. Examples of types of composition are suspensions (for example, SC, OD, FS), emulsifiable concentrates (for example, EC), emulsions (for example, EW, EO, ES, ME), capsules (for example, CS, ZC), pastes, lozenges, dusts or wettable powders (for example, WP, SP, WS, DP, DS), pressed (for example, BR, TB, DT), granules (for example, WG, SG, GR, FG , GG, MG), insecticidal articles (for example, LN), as well as gel formulations for the treatment of plant propagation materials, such as seeds (GF). These and other types of compositions are defined in the “Catalog of pesticide formulation types and International coding system”, Technical Monograph n ° 2, 6th to ed. May 2008, CropLife International.
    [094] The compositions are prepared in a known manner, as described by Mollet and Grubemann, Formulation technology, Wiley VCH, Weinheim, 2001; or Knowles, New developments in crop protection product formulation, Agrow Reports DS243, T&F Informa, London, 2005.
    [095] When living microorganisms, such as pesticides and TJ1000 II from groups (L1), (L3) and (L5), are part of the compositions, such compositions can be prepared as compositions that comprise, in addition to the active ingredients at least one auxiliary (inert ingredient) by usual means (see, for example, HD Burges: Formulation of Microbial Biopesticides, Springer, 1998). The usual suitable types of such compositions are suspensions, dust, powders, pastes,
    70/79 granules, capsules, pressed, and mixtures thereof. Examples of types of composition are suspensions (for example, SC, OD, FS), capsules (for example, CS, ZC), pastes, lozenges, dusts or wettable powders (for example, WP, SP, WS, DP, DS), pressed (for example, BR, TB, DT), granules (for example, WG, SG, GR, FG, GG, MG), insecticidal articles (for example, LN), as well as gel formulations for the treatment of plant propagation materials, such as seeds (FG). At present, it must be taken into account that each type of formulation or the selection of the auxiliary must not influence the viability of the microorganism during the storage of the composition and, finally, when applied to the propagation material of the plant. Suitable formulations, for example, are mentioned in WO 2008/002371, US patents 6,955,912, US 5,422,107.
    [096] Examples of suitable auxiliaries are those mentioned earlier in the present, in which care must be taken that the selection and quantities of these auxiliaries should not influence the viability of microbial pesticides in the composition. Especially for bactericides and solvents, the compatibility with the respective microorganism of the respective microbial pesticide needs to be taken into account. In addition, compositions with microbial pesticides may still contain stabilizers or nutrients and UV protectors. Suitable stabilizers or nutrients, for example, are alpha-tocopherol, trehalose, glutamate, potassium sorbate, various sugars such as glucose, sucrose, lactose, maltodextrin (H.D. Burges Formulaztion by Micobial Biopestcides, Springer, 1998). Suitable UV protectors, for example, are inorganic compounds such as titanium dioxide, zinc oxide and iron oxide pigments or organic compounds such as benzophenones, benzotriazols, phenyltriazines. The compositions, in addition to the auxiliaries mentioned for the compositions comprising the compounds of Formula I of the present
    71/79 invention, optionally may contain from 0.1 to 80% of stabilizers or nutrients and from 0.1 to 10% of UV protectors.
    [097] Agrochemical compositions, in general, are characterized by the fact that they contain an effective amount of the active components, as defined above. In general, they contain between 0.01 and 95%, preferably between 0.1 and 90%, and in particular between 0.5 and 75%, by weight of the active components, in particular, the active substances.
    [098] According to one embodiment, the compositions contain microbial pesticides such as pesticides II and TJ1000 from groups (L1, (L3) and (L5) in an amount of 1 χ 10 5 to 1 χ 10 12 CFU preferably from 1 χ 10 7 CFU to 1 χ 10 12 CFU, most preferably between 1 χ 10 9 CFU to 1 χ 10 12 CFU per gram of the total weight of the composition.
    [099] Solutions for seed treatment (LS), suspoemulsions (SE), fluid concentrates (FS), treatment of dusty powders (DS), water dispersible powders for sludge treatment (WS), water-soluble powders (SS), emulsions (ES), emulsifiable concentrates (EC) and gels (GF), in general, are used for the purposes of treating vegetable propagating materials, especially seeds.
    [0100] The preferred examples of the types of seed treatment formulation or soil application for premix compositions are type WS, LS, ES, FS, WG or CS.
    [0101] The compositions in question, after dilution by a factor of two to ten, provide the concentrations of the active components from 0.01 to 60% by weight, preferably from 0.1 to 40%, in preparations ready for use. the utilization. The application can be carried out before or during sowing. Methods for applying or treating compound I and compound II and their compositions, respectively, in plant propagation materials, especially seeds include methods of application by
    72/79 covering, coating, pelletizing, dusting, dipping and furrowing the propagation material. Preferably, compound I and compound II or their compositions, respectively, are applied to the plant propagation material through a method in such a way that germination is not induced, for example, by covering, pelletizing, coating and sprinkling of the seeds.
    [0102] Preferably, the plant's propagating material is a seed, part of the seed (ie the stem) or a seed bulb.
    [0103] Although it is believed that the present method can be applied to a seed in any physiological state, preferably the seed is in a sufficiently durable state that it does not incur damage during the treatment process. Normally, the seed would be a seed that was harvested from the field; removed from the vegetable; and separated from any ear, stem, outer bark, and surrounding pulp or other non-seed plant material. The seed, preferably, would also be biologically stable insofar as the treatment would not cause biological damage to the seed. It is believed that the treatment can be applied to the seed at any time between the harvest of the seed and the sowing of the seed or during the sowing process (applications directed to the seeds). The seed can also be prepared, either before or after treatment.
    [0104] The uniform distribution of the ingredients in the mixtures of the present invention and their adhesion to the seeds is desired during the treatment of the propagation material. The treatment can vary from a thin film (coating) of the formulation containing the combination, for example, a mixture of active ingredient (s), on a vegetable propagating material, such as a seed, in which the original size and / or shape is recognizable to an intermediate state (such as a coating) and then to a thicker film (such as
    73/79 granulation with many layers of different materials (such as vehicles, for example, clays; different formulations, such as other active ingredients, polymers, and dyes) in which the original shape and / or size of the seeds is not more recognizable.
    [0105] The seed can be treated by applying the component (1) and the component (2) present in the mixtures of the present invention in any desired sequence or simultaneously.
    [0106] The seed treatment occurs to an unsown seed, and the term "unsown seed" is intended to include the seed in any period between the harvest of the seed and the sowing of the seed in the soil for the purpose of germination and plant growth .
    [0107JO Treatment of an unsown seed is not intended to include those practices in which the active ingredient is applied to the soil, but which includes any practical application that the seed would target during the planting process.
    [0108] Preferably, the treatment takes place before the sowing of the seed so that the seed sown has been pre-treated with the combination. In particular, seed coating or seed pelleting is preferred in the treatment of the combinations according to the present invention. As a result of the treatment, the ingredients in each combination are glued to the seed and are therefore available for pest control.
    [0109] Treated seeds can be stored, handled, sown and grown in the same way as any other seed treated with the active ingredient.
    [0110] In particular, the present invention relates to a method for protecting plant propagating material against pests and / or improving the health of vegetables grown from said plant material.
    Plant propagation, wherein the soil, in which the plant propagation material is sown, is treated with an effective amount of a mixture of the present invention.
    [0111] In particular, the present invention relates to a method for protecting plant propagating material from pests, in which the soil, in which the plant propagating material is sown, is treated with an effective amount of a mixture of the present invention.
    [0112] In particular, the present invention relates to a method for the protection of plant propagating material against harmful fungi, in which the soil, in which the plant propagating material is sown, is treated with an effective amount of a mixture of the present invention.
    [0113] In particular, the present invention relates to a method for the protection of plant propagating material against animal pests (insects, mites or nematodes), in which the soil, in which the plant propagating material is sown , is treated with an effective amount of a mixture of the present invention.
    [0114] When used in vegetable protection, the total amounts of the active components are applied, depending on the type of effect desired, from 0.001 to 10 kg per ha, preferably from 0.005 to 2 kg per hectare, from more preferably, from 0.05 and 0.9 kg per hectare, in particular, from 0.1 to 0.75 kg per ha. In the case of TJ1000 and microbial pesticides II, the rates of leaf or soil application (for example, in the furrow) of the application methods preferably range from about 1 X 10 6 to 5 x 10 15 (or higher) CFU / ha and, most preferably, the spore concentration is about 1 x 10 7 to about 1 x 10 12 CFU / ha. In the case of nematodes (entomopathogenic) such as microbial pesticides (for example, Steinemema feltiae), application rates preferably range from around
    75/79 χ 10 5 to 1 χ 10 12 (or higher), most preferably from 1 x 10® to 1 x 10 11 and, even more preferably, from 5 x 10® to 1 x 10 '° individuals (eg in the form of eggs, juvenile or any other live stage, preferably in an infective juvenile stage) per ha.
    [0115] When used to protect plants through seed treatment, the amount of mixtures of the present invention (based on the total weight of the active components) is in the range from 0.01 to 10 kg, preferably from from 0.1 to 1,000 g, most preferably from 1 to 100 g per 100 kilograms of plant propagation material (preferably seeds). In the case of TJ1000 and microbial pesticides II, application rates for plant propagating material preferably range from about 1 X 10® to 1 χ 10 12 (or higher) CFU / seed. Preferably, the concentration is from about 1 x 10® to about 1 x 10 11 CFU / seed. In the case of TJ1000 and microbial pesticides II, application rates in relation to plant propagating material, also preferably, vary from about 1 χ 10 7 to 1 χ 10 14 (or higher) CFU per 100 kg seed, preferably between 1 χ 10 9 to about 1 χ 10 12 CFU per 100 kg of seeds.
    [0116] When used to protect stored materials or products, the amount of active components applied depends on the type of application area and the desired effect. The amounts usually applied in the protection of materials are from 0.001 g to 2 kg, preferably from 0.005 g to 1 kg, of the active component per cubic meter of the treated material.
    [0117] The user applies the composition, according to the process of the present invention, from a pre-dosing device, a backpack sprayer, a spray tank or an irrigation system. Usually, the agrochemical composition is made with water, buffer, and / or other auxiliary agents for the desired application concentration and the
    7ΒΓ79 ready-to-use spray solution or agrochemical composition according to the present invention is. therefore obtained. Typically, 20 to 2,000 liters, preferably 50 to 400 liters, of the ready-to-use spray solution are applied per hectare of the useful agricultural area.
    [0118] In mixtures and compositions, the proportions of the compounds are advantageously selected to produce a synergistic effect.
    [0119] The term “synergistic effect”, in particular, must refer to the Formula defined by Colby (Colby, S.R., Calculating synergistic and antagonistic responses of herbicide combinations ”, Weeds, 15, pages 20-22, 1967).
    [0120] The term “synergistic effect must also refer to that defined by the application of the Tammes method, (Tammes, PML, Isoboles, the graphic representation of synergism in pesf / c / ctes”, Netherlands. J. Plant Pathol. 70, 1964).
    [0121] According to the present invention, the solid material (dry matter) of biopesticides (with the exception of oils such as Neem oil, Tagetes oil, and the like) is considered to be an active component (for example, to be obtained after drying or evaporating the extraction medium or the suspension medium, in the case of liquid microbial pesticide formulations).
    [0122] According to the present invention, the weight ratios and percentages used in the present, for a biological extract, such as Quillay extract, are based on the total weight of the dry matter (solid material) content of ( s) respective extract (s).
    [0123] The total weight proportions of the compositions comprising at least one microbial pesticide, in the form of viable microbial cells, including inactive forms, can be determined using the amount of CFU of the respective micro-organism for calculating the
    77/79 total weight of the respective active component, with the following equation where 1 x 10 10 CFU is equivalent to one gram of total weight of the respective active component. The colony-forming unit is measured by viable microbial cells, in particular, fungi and bacterial cells. Furthermore, at present the term CFU can also be understood as the number of individual (juvenile) nematodes in the case of nematode (entomopathogenic) biopesticides, such as Steinemema feltiae.
    [0124] In binary mixtures and compositions, according to the present invention, the weight ratio of the component (1) to the component (2), in general, depends on the properties of the active components used, it is usually in the range from 1: 10,000 to 10,000: 1, regularly in the range from 1: 100 to 10,000: 1, preferably in the range from 1: 100 to 5,000: 1, most preferably, in the range from 1: 1 to 1000: 1, even more preferably, in the range from 1: 1 to 500: 1 and especially in the range from 10: 1 to 300: 1.
    [0125] According to other realizations of binary mixtures and compositions, the weight ratio of component (1) to component (2) is usually in the range from 20,000: 1 to 1:10, often in the range from 10,000: 1 to 1: 1, regularly in the range from 5,000: 1 to 5: 1, preferably in the range from 5,000: 1 to 10: 1, most preferably, in the range from 2,000: 1 to 30: 1, even more preferably, in the range from 2000: 1 to 100: 1 and especially in the range from 1,000: 1 to 100: 1.
    [0126] According to other realizations of binary mixtures and compositions, the weight ratio of component (1) to component (2) is usually in the range from 20,000: 1 to 1: 1,000, often in the range from from 10,000: 1 to 1: 100, regularly in the range from 5,000: 1 to 1: 1, preferably in the range from 5,000: 1 to 10: 1, greater
    78/79 preferably in the range from 2,000: 1 to 30: 1, most preferably in the range from 2,000: 1 to 100: 1 and especially in the range from 1,000: 1 to 100: 1 .
    [0127] According to other embodiments of mixtures and compositions, the weight ratio of component (1) to component (2) is usually in the range from 1: 1 to 1: 1,000, often in the range from 1: 1 to 1: 100, regularly in the range from 1: 1 to 1:50, preferably in the range from 1: 1 to 1:20, most preferably, in the range from 1: 1 at 1:10, even more preferably, in the range from 1: 1 to 1: 4 and, in particular, in the range from 1: 1 to 1: 2.
    [0128] In the achievements mentioned above; the total weight of the component (1) is calculated based on the amount of CFU of the component 1), where 1 x 10 1 ° UFC is equivalent to one gram of the total weight of the component (1); and the total weight of the component (2), in the case of microorganisms, is calculated based on the amount of CFU of the component (2), where 1 x 10 1 ° CFU equivalent to one gram of the total weight of the component (2).
    [0129] These proportions are also suitable for the mixtures of the present invention applied through seed treatment.
    [0130] The fungicidal action of the mixtures, according to the present invention, can be demonstrated by the tests described below.
    (A) Microtiter Plate Tests [0131] Chemical pesticides II were formulated separately as a stock solution with a concentration of 10,000 ppm in dimethyl sulfoxide.
    [0132] The stock solutions of chemical pesticides II were mixed according to the diluted ratio to the indicated concentrations and pipetted into a microtiter filter (MTP) plate. A spore suspension of the pathogen (for example, Botrytis cinerea,
    79/79
    Septoria tritici, and the like), for example, in the aqueous biomalt solution, different concentrations of spores or TJ1000 cells and, if desired, biopesticide II were added.
    [0133] The measured parameters were compared with the growth of the active compound free control variant (100%) and the free blank of active compound and fungus free to determine the relative growth in percentage (%) of the pathogens in the respective active compounds.
    [0134] The expected efficacies of combinations of active compounds were determined using Colby's Formula [R.S. Colby, Calculating synergistic and antagonistic responses of herbicide combinations, Weeds 15, 20-22 (1967)] and compared with the observed efficacy.
    - Colby formula: E = x + y - x · y / 100
    - E means the expected efficacy, expressed as a percentage (%) of the untreated control, when using the mixture of active compounds A and B, at concentrations a and b
    - x means the effectiveness, expressed as a percentage (%) of the untreated control, when an active component A is used in the concentration a
    - y means the effectiveness, expressed as a percentage (%) of the untreated control, when an active component B in concentration b is used.
    1/19
    权利要求:
    Claims (15)
    [1]
    Claims
    1. MIXTURE characterized by the fact that it comprises, as active components (1) the strain B. amyloliquefaciens ssp. plantarum TJ1000 (ATCC
    BAA-390);
    dimoxystrobin, fluphenoxystrobin, coumoxystrobin, phenoxystrobin / metominostrobin, (2) at least one pesticide II from groups (A) to (O) selected from:
    (A) Breathing inhibitors
    - Complex III inhibitors at site Q o (for example, strobilurins): azoxystrobin, coumethoxystrobin, enestroburin, phenaminstrobin, fluoxastrobin, cresoxim-methyl, orisastrobin, picoxystrobin, pyraclostrobin, pirametostrobin, piraoxystrobin (2- pyroxystrobin (2- 3- (2,6-di-chlorophenyl) -1-methyl-alliliden-aminooxy-methyl) -phenyl) -2methoxyimino-N-methyl-acetamide, pyribencarb, triclopiricarb / chlorodincarb, famoxadone, phenamidone, methyl-N- [2 - [((1,4-dimethyl-5-phenyl-pyrazol-3yl) oxylmethyl] phenyl] -N-methoxy-carbamate, 1 - [3-chloro-2 - [[[1 - (4-chlorophenyl) -1 H -pyrazol3-yl] oxy] methyl] phenyl] -1,4-dihydro-4-methyl-5H-tetrazol-5-one, (2E, 3Z) -5 - [[1- (2,4dichlorophenyl) -1H- pyrazol-3-yl] oxy] -2- (methoxyimino) -N, 3-dimethyl-pent-3-enamide, (2E, 3Z) -5 - [[1- (4-chloro-phenyl) -1H-pyrazole -3-yl] oxy] -2- (methoxyimino) -N, 3-dimethyl-pent3-enamide;
    - Ili complex inhibitors at the Qj site: cyazofamide, amisulfon; 2-methylpropanoate [(3S, 6S, 7R, 8R) -8-benzyl-3 - [(3-acetoxy-4methoxy-pyridin-2-carbonyl) amino] -6-methyl-4,9-dioxo-1,5 -dioxonan-7-yl], 2-methylpropanoate [(3S, 6S, 7R, 8R) -8-benzyl-3 - [[3- (acetoxymethoxy) -4-methoxy-pyridin2-carbonyl] amino] -6-methyl-4 , 9-dioxo-1,5-dioxonan-7-yl], 2-methylpropanoate [(3S, 6S, 7R, 8R) -8-benzyl-3 - [(3-isobutoxycarbonyloxy-4-methoxy-pyridin-22 / 19 carbonyl) amino] -6-methyl-4,9-dioxo-1,5-dioxonan-7-yl], 2-methylpropanoate [(3S, 6S, 7R, 8R) -8-benzyl-3 - [[3 - (1,3-benzodioxol-5-ylmethoxy) -4-methoxy-pyridin-2carbonyl] amino] -6-methyl-4,9-dioxo-1,5-dioxonan-7-yl], 2-methylpropanoate (3S , 6S, 7R, 8R) -3 - [[((3-hydroxy-4-methoxy-2-pyridinyl) carbonyl] amino] -6-methyl-4,9dioxo-8- (phenylmethyl) -1,5-dioxonan- 7-yl;
    - Complex II inhibitors selected from: benodanil, benzovindiflupir, bixafen, boscalid, carboxin, fenfuram, fluopiram, flutolanil, fluxapiroxad, furametpir, isofetamid, isopirazam, mepronil, oxycarboxine, penflufen, pentiopyramide, (4'trifluoromethylthiobiphenyl-2-yl) -3-d ifl uoromethyl I-1-methyl-1 H-pyrazol-4-carboxamide, N (2- (1,3,3-trimethyl-butyl) -phenyl) - 1,3-dimethyl-5-fluoro-1 H-pyrazol-4-carboxamide, 3 (difluoromethyl) -1-methyl-N- (1,1,3-trimethyl-indan-4-yl) pyrazole-4-carboxamide, 3 (trifluoromethyl) -1-methyl-N- (1,1,3-trimethylindan-4-yl) pyrazol-4-carboxamide, 1,3dimethyl-N- (1,1,3-trimethylindan-4-yl) pyrazole- 4-carboxamide, 3- (trifluoromethyl) -1,5dimethyl-N- (1,1,3-trimethylindan-4-yl) pyrazol-4-carboxamide, 1,3,5-trimethyl-N- (1,1, 3trimethylindan-4-yl) pyrazol-4-carboxamide, N- (7-fluoro-1,1,3-trimethylindan-4-yl) -1,3dimethyl-pyrazol-4-carboxamide, N- [2- (2, 4-dichlorophenyl) -2-methoxy-1-methyl-ethyl] -3 (difluoromethyl) -1-methyl-pyrazol-4-carboxamide;
    - other respiration inhibitors (eg complex I, uncouplers): diflumetorim, (5,8-difluoro-quinazolin-4-yl) - {2- [2-fluoro-4- (4trifluoromethylpyridin-2-yloxy) -phenyl ] -ethyl} -amine; nitrophenyl derivatives: binapacril, dinobuton, dinocap, fluazinam; ferimzone; organometallic compounds: phentin salts, such as phentin acetate, fentin chloride or fentin hydroxide; ametoctradine; and siltiofam;
    (B) sterol biosynthesis inhibitors (SBI fungicides)
    - C14 demethylase inhibitors (DMI fungicides) triazoles: azaconazole, bitertanol, bromuconazole, cyproconazole, diphenoconazole, diniconazole, diniconazole-M, epoxiconazole, fenbuconazole, fluquinconazole, flusilazole, flutrolazole
    3/19 hexaconazole, imibenconazole, ipconazole, metconazole, myclobutanil, oxpoconazole, paclobutrazol, penconazole, propiconazole, protioconazole, simeconazole, tebuconazole, tetraconazole, triadimefon, triadimenol, 3-tritazole; 3- (2-chlorophenyl) -2- (2,4-difluorophenyl) -oxyranylmethyl] -5-thiocyanate-1H [1,2,4] triazole, 2- [re / - (2S, 3 / ) - 3 - (2-chlorophenyl) -2- (2,4-difluorophenyl) -oxyranyl-methyl] 2H- [1,2,4] triazole-3-thiol, 2- [2-chloro-4- (4-chlorophenoxy) phenyl] -1- (1,2,4-triazol-1 yl) pentan-2-ol, 1- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1-cyclopropyl-2- (1 , 2,4triazol-1-yl) ethanol, 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1,2,4-triazol-1yl) butan-2-ol, 2 - [2-chloro-4- (4-chlorophenoxy) phenyl] -1- (1,2,4-triazol-1-yl) butan-2-ol, 2 [4- (4-chlorophenoxy) -2- ( trifluoromethyl) phenyl] -3-methyl-1- (1 l 2,4-triazol-1-yl) butan-2-ol, 2 [4- (4-chlorophenoxy) -2- (trifluoromethyl) -phenyl] -1 - (1,2,4-triazol-1-yl) propan-2-ol, 2- [2 chloro-4- (4-chlorophenoxy) phenyl] -3-methyl-1- (1,2,4-triazole- 1-yl) butan-2-ol, 2- [4- (4chlorophene xi) -2- (trifluoromethyl) -phenyl] -1 - (1,2,4-triazol-1-yl) pentan-2-ol, 2- [4- (4fluorophenoxy) -2- (trifluoromethyl) -phenyl] -1- (1,2,4-triazol-1-yl) propan-2-ol; imidazoles: imazalil, pefurazoate, prochloraz, triflumizole; pyrimidines, pyridines and piperazines: fenarimol, nuarimol, pyrifenox, triforin; 3- (4-chloro-2-fluoro-phenyl) 5- (2,4-difluorophenyl) isoxazol-4-yl] - (3-pyridyl) methanol;
    - Deitai4 reductase inhibitors: aldimorf, dodemorf, dodemorf acetate, fenpropimorf, tridemorf, fenpropidina, piperalina, spiroxamina;
    - 3-keto reductase inhibitors: fenexamide;
    (C) Nucleic acid synthesis inhibitors
    - the fungicides of the phenylamides or acyl amino acid: benalaxyl, benalaxyl-M, chiralaxyl, metalaxyl, metalaxyl-M (mefenoxam, C.1.5), ofurace, oxadixil;
    - Others selected from: himexazole, octylinone, oxolinic acid, bupyrime, 5-fluorocytosine, 5-fluoro-2- (p-tolylmethoxy) pyrimidin-4amine, 5-fluoro-2- (4-fluorophenylmethoxy) pyrimidin-4- the mine;
    4/19 (D) Cell division and cytoskeleton inhibitors
    - benomyl (D1.1), carbendazim (D1.2), fuberidazole (D1.3), thiabendazole (D1.4), thiophanate-methyl (D1.5); triazolopyrimidines: 5-chloro-7- (4methyl-piperidin-1-yl) -6- (2,4,6-trifluorophenyl) - [1,2,4] triazole [1,5-ajpirimidine (D1.6);
    - Inhibitors of another cell division selected from: dietofencarb (D2.1), etaboxam (D2.2), pencicurone (D2.3), fluopicolid (D2.4), zoxamide (D2.5), metrafenone (D2. 6), pyriophenone (D2.7);
    (E) Inhibitors of the synthesis of amino acids and proteins
    - Methionine synthesis inhibitors (anilino-pyrimidines) selected from: cyprodinil, mepanipyrim, pyrimethanil;
    - Protein synthesis inhibitors selected from: blasticidin-S, casugamycline, casugamycin clorldrate hydrate, mildiomycin, streptomycin, oxytetracycline, polyoxin, validamycin A;
    (F) Signal transduction inhibitors
    - MAP / histidine kinase inhibitors selected from: fluoroimid, iprodione, procymidone, vinclozoline, fenpiclonil, fludioxonil;
    - (L) Lipid and membrane synthesis inhibitors
    - Phospholipid biosynthesis inhibitors: edifenfós, iprobenfós, pyrazofó, isoprotiolana;
    - Peroxidation of lipids: dichloran, quintinto, tecnazene, tolclofos-methyl, biphenyl, cloroneb, etridiazole;
    - Phospholipid biosynthesis and cell wall deposition: dimetomorf, flumorf, mandiproamide, pyrimorf, bentiavalicarb, iprovalicarb, valifenalate and N- (1- (1- (4-cyano-phenyl) ethanesulfonyl) acid (4-fluorophenyl) ester ) -but-2-yl) -carbamic;
    - Compounds that affect the permeability of the cell membrane and fatty acids: propamocarb, propamocarb hydrochloride
    - fatty acid amide hydrolase inhibitors selected from
    5/19 from: oxatiapiproline, 1- [4- [4- [5 (2,6-difluorophenyl) -4,5-dihydro-3 isoxazolyl] -2thiazoliI] -1 -piperidinyl] -2- [5 -methyl-3- (trifluoromethyl) -1 H-pyrazol-1-yljetanone; 2- {3- [2 (1 - {[3,5-bis (d ifluoromethyl-1 H-pyrazol-1-yljaceti IJpiperid in-4-yl) -1,3-thiazol-4-yl] -4, 5dihydro-1,2 oxazol-5-yl} -phenyl, 2- {3- [2- (1 - {[3,5-bis (difluoro-methyl) -1 H-pyrazol-1 yl] acetyl} piperidin- 4-yl) 1,3-thiazol-4-yl] -4,5-dihydro-1,2-oxazol-5-yl} -3chlorophenylmethanesulfonate;
    (H) Inhibitors with multilocal action
    - Inorganic active substances selected from: Bordeaux mixture, copper acetate, copper hydroxide, copper oxychloride, basic copper sulfate, sulfur;
    - Uncle- and dithiocarbamates: ferbam, mancozeb, maneb, metam, metiram, propineb, tiram, zineb, ziram;
    - Organochlorine compounds selected from: anilazine, chlorotalonil, captafol, captan, folpet, dichlofluanide, dichlorophene, flusulfamide, hexachlorobenzene, pentachlorphenol and its salts, phthalide, tolylfluanide, N- (4-chloro-2nitro-phenyl-phenyl) -N -4-methyl-benzenesulfonamide;
    - Guanidines and others selected from: guanidine, dodine, dodine-free base, guazatin, guazatin acetate, iminoctadine, iminoctadine triacetate, iminoctadine tris (albesylate), dithianone, 2,6-dimethyl-1H, 5H [1 , 4] dithino [2,3-c: 5,6-c '] dipyrrol-1,3,5,7 (2H, 6H) -tetraone;
    (I) inhibitors of cell wall synthesis
    - Glucan synthesis inhibitors selected from: validamycin, polyoxin B;
    - Melanin synthesis inhibitors: pyroquinone, tricyclazole, carpropamide, dicyclomethane, phenoxanil;
    (J) Vegetable defense inducers selected from: acibenzolar-S-methyl, probenazole, isothianyl, ti-adinyl, calcium prohexadione; phosphonates: fosetil, fosetil-aluminum, phosphoric acid and its salts, of potassium or
    6/19 sodium bicarbonate;
    (K) Unknown mode of action selected from: bronopol, quinomethinate, cyflufenamide, cymoxanil, dazomet, debacarb, diclomezine, difenzoquat, difenzoquat methylsulfate, diphenylamine, phenepyrazamine, flumetover, flusulfamide, flutianyl, metassulfocarb, nitra; oxatiapiproline, tolprocarb, oxin-copper, proquinazide, tebufloquine, keyboardophthalam, triazoxide, 2-butoxy-6-iodo-3 propylchromen-4-one, 2 [3,5-bis (difluoromethyl) -1 H-pyrazol-1-yl ] -1 - [4- (4- {5- [2- (prop-2-in-1-yloxy) phenyl] -4,5dihydro-1,2-oxazol-3-yl} -1,3-thiazole -2-yl) p iperid in-1-yljetanone, 2- [3,5bis (difluoromethyl) -1 H-pyrazol-1-yl] -1- [4- (4- {5- [2-fluoro-6 - (prop-2-in-1-yloxy) phenyl] 4,5-dihydro-1,2-oxazol-3-yl} -1,3-thiazol-2-yl) piperidin-1-yl] ethanone, 2 - [3,5bis (difluoromethyl) -1 H-pyrazol-1-yl] -1 - [4- (4- {5- [2-chloro-6- (prop-2-in-1-yloxy) pheni l] -4,5-dihydro-1,2-oxazol-3-yl} -1,3-thiazol-2yl) piperidin-1-yljetanone, N- (cyclopropylmethoxyimino- (6-difluoro-methoxy-2,3-difluoro- phenyl) -methyl) -2-phenyl-acetamid a, N '- (4- (4-chloro-3-trifluoromethyl-phenoxy) -2,5-dimethyl-phenyl) -N-ethyl-N-methylformamidine, N' - (4- (4-fluoro-3- trifluoromethyl-phenoxy) -2,5-dimethyl-phenyl) -N-ethyl-Nmethyl-formamidine, N '- (2-methyl-5-trifluoromethyl-4- (3-trimethyl-silanyl-propoxy) -phenyl) N- ethyl-N-methyl formamidine, N '- (5-difluoromethyl-2-methyl-4- (3-trimethylsilanylpropoxy) -phenyl) -N-ethyl-N-methyl formamidine, methoxy-acetic acid ester 6-tertbutyl-8 -fluoro-2,3-dimethyl-quinolin-4-yl, 3- [5- (4-methylphenyl) -2,3-dimethyl-isoxazolidin3-yl] -pyridine, 3- [5- (4-chloro-phenyl ) -2,3-dimethyl-isoxazolidin-3-yl] -pyridine (pyrisoxazole), N- (6-methoxy-pyridin-3yl) cyclopropanecarboxylic acid amide, 5-chloro-1 - (4,6-dimethoxy- pyrimidin-2-yl) -2-methyl-1 H-benzoimidazole, 2- (4-chlorophenyl) -N- [4- (3,4-dimethoxy-phenyl) -isoxazol-5-yl] -2-prop- 2-inyloxy-acetamide; (Z) -3amino-2-co. Pentyl 3-phenyl-prop-2-enoate, N- [6 - [[(Z) - [(1-methylthetrazol-5-yl) -phenylmethylene] oxymethyl] -2-pyridyl] carbamate, 2- [2- [(7,8-difluoro-2-methyl-3quinolyl) oxy] -6-fluoro-phenyl] propan-2-ol, 2- [2-fluoro-6 - [(8-fluoro-2-methyl-3quinolyl) oxy] phenyl] propan-2-ol, 3- (5-fluoro-3,3,4,4-tetramethyl-3,4-dihydroisoquinolin7 / 19
    1 -yl) -quinoline, 3- (4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl) quinoline, 3 (4,4,5-trifluoro-3,3-dimethyl- 3 > 4-dihydroisoquinolin-1-yl) quinolone;
    (L) Biopesticides (L1) Microbial pesticides with fungicidal, bactericidal, viricidal and / or vegetable activating activity: Ampelomyces quisqualis, Aspergillus flavus, Aureobasidium pullulans, Bacillus amyloliquefaciens, B. mojavensis, B. pumilus, B. simplex, B simplex solisalsi, B. subtilis, B. subtilis var. amyloliquefaciens, Candida oleophila, C. saitoana, Clavibacter michiganensis (bacteriophages), Coniothyrium minitans, Cryphonectría parasitica, Cryptococcus albidus, Dilophosphora alopecuri, Fusarium oxysporum, Clonostachys rosea f. catenuiate / also known as Gliocladium catenulatum), Gliocladium roseum, Lysobacter antibioticus, L. enzymogenes, Metschnikowia fructicola, Microdochium dimerum, Microsphaeropsis ochracea, Muscodor albus, Paenibacillus polymyxa, Pantoea vagans, Pantoea vagans, Phlebiopsis, Phlebiopsis , Pythium oligandrum, Streptomyces griseovirídis, S. lydicus, S. violaceusniger, Talaromyces flavus, Trichoderma asperellum, T. atroviride, T. fertile, T. gamsii, T. harmatum, T. harzianum; mixture of T. vinde and T. harzianum-, mixture of T. polysporum and T. harzianum; T. stromaticum, T. virens / also known as Gliocladium virens), T. vinde, Typhula phacorrhiza, Ulocladium oudemansii, Verticillium dahlia, yellow mosaic zucchini virus (non-virulent strain);
    (L2) Biochemical pesticides with fungicidal, bactericidal, viricidal and / or vegetable activating activity: chitosan (hydrolysis), harpine protein, laminarin, Menhaden fish oil, natamycin, Plum pox virus coated protein, potassium bicarbonate or sodium, Reynoutria sachlinensis extract, salicylic acid, tea tree oil;
    (L3) Microbial pesticides with insecticidal, acaricidal, molluscidal and / or nematicidal activity: Agrobacterium radiobacter, Bacillus cereus, B.
    8/19 firmus, B. thuringiensis, B. thuringiensis ssp. aizawai, B. t. ssp. israelensis, B. t. ssp. galleríae, B. t. ssp. kurstaki, B. t. ssp. tenebrionis, Beauveria bassiana, B. brongniartii, Burkholdería sp., Chromobacteríum subtsugae, Cydia pomonella granulosis virus, Cryptophlebia leucotreta granulovirus (CrieGV), Isaria fumosorosea, Heterorhabditis bacteriophora, Lecanicillium longisporium anisopliae var. acridum, Nomuraea rileyi, Paecilomyces fumosoroseus, P. lilacinus, Paenibacillus popilliae, Pasteuría spp., P. nishizawae, P. penetrans, P. ramose, P. reneformis, P. thornea, P. usgae, Pseudomonas fluorescens, Steinemema carpocapsae, feltiae, S. kraussei;
    (L4) Biochemical pesticides with insecticidal, acaricidal, molluscidal, pheromone and / or nematicidal activity: L-carvone, citral, acetate (E, Z) -7.9 dodecadien-1-yl, ethyl format, acetate (E, Z ) -2,4-decadienoate (pear ester), (Z, Z, E) -7,11,13-hexadecatrienal, heptyl butyrate, isopropyl myristate, lavanulil senecioate, cis-jasmine, 2-methyl-1- butanol, methyl eugenol, methyl jasmonate, (E, Z) -2,13-octadecadien-1-ol, acetate (E, Z) -2,13octadecadien-1 -ol, (E, Z) -3,13 -octadecadien-1 -ol, R-1-octen-3-ol, pentatermanone, potassium silicate, sorbitol actanoate, acetate (Ε, Ζ, Ζ) 3,8,11-tetradecatrienyl, acetate (Z, E) - 9,12-1-tetradecadien-yl, Z-7-tetradecen-2ona, Z-9-tetradecen-1-yl acetate, Ζ-11-tetradecenal, Z-11-tetradecen-1-ol, black wattle extract, grapefruit and pulp seed extract, Chenopodium ambrosiodae extract, Catnip oil, Neem oil, Quillay extract, Tagetes oil;
    (L5) Microbial pesticides with the activity of reducing the tension of the plant, regulating growth, promoting plant growth and / or enhancing yield: Azospirillum amazonense, A. brasilense, A. lipoferum, A. irakense, A. halopraeferens, Bradyrhizobium sp, B. elkanii, B. japonicum, B. liaoningense, B. Lupini, Delftia acidovorans, Glomus
    9/19 intraradices, Mesorhizobium sp., Paenibacillus alvei, Penicillium bilaiae, Rhizobium leguminosarum bv. phaseoli, R. I. trifolii, R. I. bv. viciae, R. tropici, Sinorhizobium meliloti;
    (L6) Biochemical pesticides with the activity of reducing the tension of the plant, regulating growth and / or enhancing yield: abscisic acid, aluminum silicate (kaolin), 3-decen-2-one, formononetine, genistein, hesperetin, homobrassinolide , humates, jasmonic acid or its salts or derivatives, lysophosphatidyl ethanolamine, naringenin, polymeric polyhydroxy acid, Ascophyllum nodosum extract (Norwegian kelp, brown kelp) and Ecklonia maxima extract (alga);
    (M) Growth regulators selected from: abscisic acid, amidochlor, ancimidol, 6-benzylaminopurine, brassinolide, butralin, clormequat (chlormequat chloride), choline chloride, cyclanilide, daminozide, diquegulac, dimethypine, 2,6-dimethylpuridine , etefone, flumetralin, flurprimidol, flutiacet, forclorfenuron, gibberellic acid, inabenfide, indole-3 acetic acid, maleic hydrazide, mefluidide, mepiquat (mepiquat chloride), naphthalene acetic acid, Ν-6-benzyladazine, proxylamine calcium), prohydrojasmon, tidiazuron, triapentenol, tributylphosphorotrithioate, 2,3,5triodo-benzoic, trinexapac-ethyl and uniconazole;
    (N) Herbicides
    - acetamides selected from: acetochlor, alachlor, butachlor, dimetachlor, dimethanamide, flufenacet, mefenacet, metolachlor, metazachlor, napropamide, naproanilide, petoxamide, pretylachlor, propachlor, tenilchlor;
    - derivatives of amino acids selected from: bilanafos, glyphosate, glufosinate, sulfosate;
    - aryloxyphenoxypropionates: clodinafop, cihalofop-butyl, fenoxaprop, fluazifop, haloxifop, metamifop, propaquizafop, quizalofop,
    10/19 quizalofop-P-tefuril;
    - bipyridyls: diquat, paraquat;
    - (uncle) carbamates selected from: asulam, butylate, carbetamide, demedipham, dimepiperate, eptam (EPTC), esprocarb, molinate, orbencarb, fenemedifam, prosulfocarb, pyributicarb, thiobencarb, trialate;
    - cyclohexanediones selected from: butroxidim, cletodim, cycloxidim, profoxidim, setoxidim, tepraloxidim, tralcoxidim;
    - dinitroanilines selected from: benfluralin, etalfluralin, oryzaline, pendimethalin, prodiamine, trifluralin;
    - diphenyl ethers selected from: acifluorfen, aclonifen, bifenox, diclofop, ethoxyfen, fomesafen, lactofen, oxyfluorfen;
    - hydroxybenzonitriles selected from: bomoxynil, diclobenil, ioxynil;
    - the imidazolinones selected from: imazametabenz, imazamox (N.10.1), imazapic (N.10.2), imazapir (N.10.3), imazaquin (N.10.4), imazetapyr (N.10.5);
    - phenoxyacetic acids selected from: clomeprop, acetic acid 2,4-dichlorophenoxy (2,4-D), 2,4-DB, dichlorprop, MCPA, MCPAtioethila, MCPB, mecoprop;
    - pyrazines selected from: chloridazone (N.11.1), flufenpir-ethyl, fluthiacet, norflurazone, pyridate;
    - the pyridines selected from: aminopyralid, clopyralid (N.12.1), diflufenican, dithiopir, fluridone, fluroxypyr (N.12.2), picloram (N.12.3), picolinafen (N.12.4), tiazopir;
    - the sulphonylureas selected from: amidosulfurone, azimsulfurone, bensulfurone (N.13.1), chlorimurone-ethyl (N.13.2), chlorsulfurone, cinosulfurone, cyclosulfamurone (N.13.3), ethoxysulfurone, flazassulfurone, flucetulfosulfurone, flucosulfurone, ,
    11/19 imazosulfurone, iodosulfurone (N.13.4), mesosulfurone (N.13.5), mesosulforone, mesosulforon-methyl (N.13.6), nicosulfurone (N.13.7), oxassulfurone, primisulfurone, prosulfurone, pyrazosulfurone (rimssulfurone (rimssulfurone) ), sulfometurone, sulfosulfurone, thifensulfuron, triasulfurone, tribenurone, trifloxysulfurone, triflussulfurone (N.13.9), tritosulfurone, 1 - (((2-chloro-6-propyl-imidazo [1,2-b] pyridazin-3-yl) sulfonyl) 3- (4,6-dimethoxypyrimidin-2yl) urea;
    - triazines: ametrine, atrazine (N.14.1), cyanazine, dimetamethrin, ethiozine, hexazinone (N.14.2), metamitron, metribuzin, promethrin, simazine, terbutilazine, terbutrine, triaziflam;
    - urea selected from: chlorotolurone, daimurone, diurone (N.15.1), fluometurone, isoproturone, linurone, metabenzo-thiazurone, tebutiurone;
    - other acetolactate synthase inhibitors selected from: bispiribac sodium, cloransulam-methyl, diclosulam, florasulam (N.16.1), flucarbazone, flumetsulam, metosulam, orthosulfamurone, penoxsulam, propoxycarbazone, pyribambenzimpropyl, pyribambenzim-propyl, piriminobacmethyl, pirimisulfan, piritiobac, pyroxasulfone (N.16.2), pyroxsulam;
    - others selected from: amicarbazone, aminotriazole, anilophos, beflubutamide, benazolin, bencarbazone, benfluresate, benzofenap, bentazone (N.17.1), benzobicyclone, bicyclopyrone, bromacila, bromobutide, butafenacyl, butamidone, ethanol, N.17.2), chlortal, cinmetilina (N.17.3), clomazono (N.17.4), cumilurone, cyprosulfamide, dicamba (N.17.5), difenzoquat, diflufenzopyr (N.17.6), Drechslera monoceras, endotal, etofumesato, etobenzanida, phenoxysulfone, fentrazamide, flumichloracpentyl, flumioxazin, flupoxam, fluorochloridone, flurtamone, indanofan, isoxaben, isoxaflutol, lenacil, propanil, propizamide, quinclorac (N.17.7), quinmerac (N.17.8, mes.9 naptalam,
    12/19 oxadiargyl, oxadiazon, oxaziclomefone, pentoxazone, pinoxadene, pyraclonil, piraflufen-ethyl, pirasulfotol, pyrazoxifen, pyrazolinate, quinoclamine, saflufenacil (N.17.10), sulcotrione (N.17.11), sulfacethazone , topramezone (N.17.12), acid ethyl ester (3 [2-chloro-4-fluoro-5- (3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-2H-pyrimidin -1yl) phenoxy] pyridin-2-yloxy) acetic acid, 6-amino-5-chloro-2-cyclopropylpyrimidine-4-carboxylic acid methyl ester, 6-chloro-3- (2-cyclopropyl-6-methylphenoxy) - pyridazin-4ol, 4-amino-3-chloro-6- (4-chlorophenyl) -5-fluoro-pyridin-2-carboxylic acid, 4-amino-3-chloro-6- (4-chlorine) methyl ester -2-fluoro-3-methoxy-phenyl) -pyridin-2-carboxylic acid and 4-amino-3-chloro-6- (4-chloro-3dimethylamino-2-fluoro-phenyl) -pyridin-2-carboxylic acid methyl ester ;
    (O) Insecticides
    - the organo (uncle) phosphates: the asphate, azametiphos, azinfos-methyl, chlorpyrifos, chlorpyrifos-methyl, chlorfenvinfos, diazinon, dichlorvos, dicrotofos, dimetoate, disulfoton, etione, fenitrotiona, fentiona, isoxathione, methazione, methalation, methalation, methalation -methyl, mevinfós, monocrotofós, oxidemeton-methyl, paraoxon, parathione, fentoate, fosalone, fosmet, phosphamidone, forato, foxima, pirimipós-methyl, profenofós, protiofós, sulprofós, tetrachlorvinfós, terbufós, triazofós and trorfona;
    - carbamates selected from: alanicarb, aldicarb, bendiocarb, benfuracarb, carbaryl, carbofuran, carbosulfan, phenoxycarb, furatiocarb, metiocarb, metomyl, oxamyl, pyrimicarb, propoxur, tiodicarb and triazamate;
    - the pyrethroids selected from: alethrin, bifentrin, cyflothrin, cyhalothrin, cyphenothrin, cypermethrin, alpha-cypermethrin, betacipermethrin, zeta-cypermethrin, deltamethrin, sphenol valdate, etofenprox, fenpropatrin, prenetrethine, prenetrethine, prenetrethine, prenetrethine, prenetrethine, prenetrethine, prenetrethine, prenetrethine, prenetrethine, prenetrethine, prothetrethine, prothetrethine, prothetrethine, prenetrethine, prothetrethine, prothetrethine, prothetrethine, prothetrethine, prothetrethine, prothetrethine, prothetrethine, prothetrine. pyrethrin I and II, resmethrin, silafluofem, tau-fluvalinate, teflutrin, tetramethrin,
    13/19 tralometrina, transflutrina, proflutrina, dimeflutrina;
    - the growth regulators of insects selected from: (a) inhibitors of chitin synthesis: benzoylureas, chlorfluazurone, chiramazine, diflubenzurone, flucicloxurone, flufenoxurone, hexaflumurone, lufenurone, novalurone, teflubenzurone, triflum; buprofezin, diophenolane, hexitiazox, ethoxazole and clofentazine; (b) ecdysone antagonists: halofenozide, methoxyfenozide, tebufenozide and azadiractin; (c) the juvenoids: pyriproxyphene, methoprene, phenoxycarb and (d) lipid biosynthesis inhibitors: spirodiclofen, spiromesifene, spirotetramate;
    - nicotinic receptor agonist / antagonist compounds selected from: clothianidin, dinotefuran, imidacloprid, thiamethoxam, nitenpiram, acetamipride, thiaclopride, 1- (2-chloro-thiazol-5-ylmethyl) -2-nitrimino-3,5-dimethyl- [ 1.3.5] triazinan;
    - GABA antagonist compounds selected from:
    endosulfan (0.6.19), etiprol, fipronil, vaniliprol, pirafiuproi, pyriprol, 5-amino-1 - (2,6-dichloro-4-methyl-phenyl) -4-sulfinamoyl-1 H-pyrazol-3-carbothioic acid amide ;
    - the insecticides of macrocyclic lactones selected from: abamectin, emamectin, milbemectin, lepimectin, spirosad, espinetoram;
    - mitochondrial electron transport inhibitor (METI) I acaricides selected from: phenazaquin, pyridaben, tebufenpirate, tolfenpirad, flufenerim;
    - METI II and III compounds: acequinocyl, fluaciprim, hydramethylnone;
    - decouplers: chlorfenapyr (0.10.1);
    - Oxidative phosphorylation inhibitors selected from: oxidative phosphorylation inhibitors selected from: cyhexatin
    14/19 (0.11.1), diafentiuron (0.11.2), fenbutatin oxide (0.11.3), propargite (0.11.4);
    - feather-disrupting compounds: cyromazine (0.12.1);
    - mixed-function oxidase inhibitors: piperonyl butoxide (0.13.1);
    - sodium channel blockers selected from: indoxacarb (0.14.1), metaflumizone (0.14.2);
    - ryanodine receptor inhibitors selected from:
    chlorantraniliprol (0.15.1), cyantraniliprol (0.15.2), flubendiamide (0.15.3), N [4,6-dichloro-2 - [(diethyl-lambda-4-sulfaniliden) carbamoyl] -phenyl] -2- ( 3-chloro-2-pyridyl) 5- (trifluoromethyl) pyrazol-3-carboxamide (0.15.4); N- [4-chloro-2 - [(diethyl-lambda-4sulfaniliden) carbamoyl] -6-methyl-phenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazol3-carboxamide (0.15. 5); N- [4-chloro-2 - [(di-2-propyl-lambda-4sulfaniliden) carbamoyl] -6-methyl-phenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazole3- carboxamide (0.15.6); N- [4,6-dichloro-2 - [(di-2-propyl-lambda-4sulfaniliden) carbamoyl] -phenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazole-3carboxamide ( 0.15.7); N- [4,6-dichloro-2 - [(diethyl-lambda-4-sulfaniliden) carbamoyl] phenyl] -2- (3-chloro-2-pyridyl) -5- (difluoromethyl) pyrazol-3-carboxamide (0.15 .8); N- [4,6dibromo-2 - [(di-2-propyl-lambda-4-sulfaniliden) carbamoyl] -phenyl] -2- (3-chloro-2pyridyl) -5- (trifluoromethyl) pyrazol-3-carboxamide ( 0.15.9), N- [4-chloro-2 - [(di-2-propillambda-4-sulfaniliden) carbamoyl] -6-cyano-phenyl] -2- (3-chloro-2-pyridyl) -5 ( trifluoromethyl) pyrazol-3-carboxamide (0.15.10); N- [4,6-dibromo-2 - [(diethylambda-4-sulfaniliden) carbamoyl] -phenyl] -2- (3-chloro-2-pyridyl) -5 (trifluoromethyl) pyrazol-3-carboxamide (0.15.11 );
    - others selected from: benclothiaz (0.16.1), biphenazate (0.16.2), cartap (0.16.3), flonicamide (0.16.4), pyridalyl (0.16.5), pymetrozine (0.16.6), sulfur (S.16.7), thiocyclam (0.16.8), cyienopyraphene (0.16.9),
    15/19 flupirazofos (0.16.10), kiflumetofen (0.16.11), amidoflumet (0.16.12), imicyafos (0.16.13), bistrifluron (O. 16.14), pyrifluquinazon (0.16.15) and acid ester cyclopropanacetic 1.1 '- [(3S, 4R, 4aR, 6S, 6aS, 12R, 12aS, 12bS) -4 - [[((2cyclopropylacetyl) oxy] methyl] -1,3,4,4a, 5,6,6a , 12,12a, 12b-decahydro-12-hydroxy4,6a, 12b-trimethyl-11 -oxo-9- (3-pyridyl) -2H, 11 H-naphtho [2,1-b] pyran [3 , 4-e] pyran-3,6diyl] (0.16.16).
    [2]
    2. MIXTURE, according to claim 1, characterized by the fact that component (1) and component (2) are present in a synergistically effective amount.
    [3]
    3. MIXTURE, according to claim 1 or 2, characterized by the fact that the component (1) and the component (2) are present in a total weight ratio of 10,000: 1 to 1: 100; where the total weight of the component (1) is calculated based on the amount of CFU of the component (1), where 1 χ 1O 10 UFC is equivalent to one gram of the total weight of the component (1); and the total weight of the component (2), in the case of microorganisms, is calculated based on the CFU amount of the component (2), where 1 χ 1O 10 CFU is equivalent to one gram of the total weight of the component (2).
    [4]
    4. MIXTURE, according to claims 1 to 3, characterized by the fact that component (2) is at least one pesticide II selected from Bradyrhizobium japonicum, B. elkanii, Bradyrhizobium spp., Bradyrhizobium sp. (Arachis), Bradyrhizobium sp. (Vigna), B. liaoningense, B. lipine; Azospirillum brasilense, A. amazonense, A. lipoferum, A. irakense, A. halopraeferens; Acidovorans Delftia, Glomus intraradices; Mesorhizobium spp, Mesorhizobium ciceri, M. huakii, M. loti; Rhizobium leguminosarum bv. phaseoli, R. leguminosarum bv. trifolii, R. leguminosarum bv. viciae, R. tropici, Sinorhizobium meliloti; Bacillus amyloliquefaciens, B. amyloliquefaciens ssp. plantarum, B. firmus, B. pumilus, B. subtilis, B. simplex, B. megateríum, B. altitudinis, B. mojavensis, B. mycoides, B. solisalsi,
    16/19
    Burkholderia spp., Coniothyrium minitans, Muscodor albus, Paecilomyces lilacinus, Paenibacillus alvei, Pasteuria Nishizawa, Pasteuria usgae, Penicillium bilaiae, Pseudomonas fluorescens, Pseudomonas putida: abscisic acid, jasonic acid, its jasonic acids, its jasonic acids, its jasonic acids, its compounds ; harpin protein.
    [5]
    5. MIXTURE, according to claim 4, characterized by the fact that component (2) is at least one pesticide II selected from Bradyrhizobium japonicum, B. elkanii, Azospiríllum brasilense; Bacillus amyloliquefaciens, B. amyloliquefaciens ssp. plantarum, B. firmus, B. pumilus, B. subtilis, B. simplex, B. megaterium; Burkholderia spp, Coniothyrium minitans, Muscodor albus, Paecilomyces lilacinus, Paenibacillus alvei, Penicillium bilaiae, Pasteuria Nishizawa: cis-jasmine, methyl jasmonate and harpine protein.
    [6]
    6. MIXTURE, according to claim 5, characterized by the fact that component (2) is at least one pesticide II selected from Bradyrhizobium japonicum, B. elkanii, Azospiríllum brasilense: cisjasmona, methyl jasmonate and protein of harpina.
    [7]
    7. MIXTURE, according to claim 5, characterized by the fact that component (2) is at least a pesticide II selected from Bacillus firmus, Bacillus pumilus, Burkholderia spp., Muscodor albus and Paecilomyces lilacinus.
    [8]
    8. MIXTURE, according to claims 1 to 7, characterized by the fact that component (2) is at least a pesticide II from the groups groups (A) to (Η), (N) and (O) selected from:
    (A) complex III inhibitors at site Q o selected from: pyraclostrobin, azoxystrobin, picoxystrobin, trifloxystrobin, dimoxystrobin, enestroburin, phenaminstrobin, fluoxastrobin, cresoxim-methyl, mandestrobin, metominostrobin, pyrethostrobin, pyrametostrostrin;
    17/19
    - complex II inhibitors selected from: fluxapiroxad, boscalid, benzovindiflupir, penflufen, pentiopirad, silkxane, fluopyram, bixafen, flutolanil, isofetamid, isopirasame; carboxine, benodanil, fenfuram, flutolanil, furametpir, mepronil, oxycarboxine, tifluzamide;
    - another inhibitor of respiration: siltiofam;
    (B) DMI fungicides selected from: ipconazole, diphenoconazole, protioconazole, prochloraz, triticonazole, flutriafol, cyproconazole, diniconazole, diniconazole-M, fluquinconazole, flusilazole, hexaconazole, imazalil, imibenconazole, tincolazole, methanol, methanol uniconazole;
    (C) nucleic acid synthesis inhibitors selected from: metalaxyl, mefenoxam;
    (D) Cell division and cytoskeleton inhibitors selected from: thiabendazole, thiophanate-methyl, carbendazim; etaboxam;
    (F) MAP / histidine kinase inhibitors: fludioxonil;
    (G) inhibitors of lipid membrane synthesis selected from: dimetomorf, zoxamide, flumorf, mandipropamide, pyrimorf, bentiavalicarb, iprovalicarb, oxatiapiproline, valifenalate;
    (H) Inhibitors with multilocated action selected from:
    tirame, ziram;
    (N) Herbicides selected from: glyphosate and dicamba;
    (O) insecticides selected from:
    - organo (uncle) phosphates selected from: acephate, chlorpyrifos,
    - carbamates selected from: metiocarb, tiodicarb;
    - pyrethroids selected from: teflutrin, bifenthrin, cypermethrin, alpha-cypermethrin, cyfluthrin, beta-cyfluthrin, lambda-cyhalothrin, deltamethrin, sphenolvalerate, etofenprox, fenvalerate, flucitrinate, permethrin;
    - macrocyclic lactone insecticides selected from:
    18/19 abamectin, spinosad;
    - nicotinic receptor agonist / antagonist compounds selected from: clothianidin, imidacloprid, thiametoxam, dinotefuran, acetamipride, flupiradifurone, thiacloprid, triflumezopyrim, nitenpiram, sulfoxaflor;
    - GABA antagonist compounds selected from: fipronil, etiprol, vaniliprol, pirafluprol, pyriprol, 5-amino-1- (2,6dichloro-4-methyl-phenyl) -4-sulfinamoyl-1H-pyrazole- amide 3-carbothioic;
    - ryanodine receptor inhibitors selected from: clorantraniliprol, cyantraniliprol, and flubendiamide.
    [9]
    9. MIXTURE according to claim 8, characterized by the fact that component (2) is at least one pesticide II selected from pyraclostrobin, azoxystrobin, trifloxistobine; fluxpyroxad, penflufen, silkxane, fluopyram; ipconazole; oxatiapiproline, valifenalate; fipronil; imidacloprid; chlorantraniliprol; and cyantraniliprol.
    [10]
    10. AGROCHEMICAL COMPOSITION, characterized by the fact that it comprises an auxiliary and a mixture, according to claims 1 to 9.
    [11]
    11. AGROCHEMICAL COMPOSITION, according to claim 10, characterized by the fact that another pesticide is still active as component (3).
    [12]
    12. AGROCHEMICAL COMPOSITION, according to claim 11, characterized by the fact that the other pesticide is selected from methyl jasmonate, cis-jasmine and harpine.
    [13]
    13. SET FOR THE PREPARATION OF A USEFUL AGRICULTURAL COMPOSITION, characterized by the fact that the set comprises (a) a composition comprising a component (1), according to claims 1 to 3 and at least one auxiliary; and
    19/19 (b) a composition comprising component (2) according to claims 1 to 9 and at least one auxiliary; and, optionally, (c) a composition comprising component (3) according to claims 11 and 12 and at least one auxiliary.
    [14]
    14. METHOD FOR THE CONTROL OF phytopathogenic FUNGI, insects and other pests and / or improvement of plant health and / or regulation of plant growth, characterized by the fact that it comprises treating plants, plant propagation material or soil with an effective amount of the mixture, according to claims 1 to 9 or the composition, according to claims 10 to 12 or the whole, according to claim 13.
    [15]
    15. VEGETABLE PROPAGATION MATERIAL, characterized by the fact that it comprises the mixture, according to claims 1 to 9 or the composition, according to claims 10 to 12 or the set, according to claim 13 in an amount from 0.01 g to 10,000 g per 100 kg of plant propagating material.
    1/1
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    法律状态:
    2018-01-23| B03A| Publication of an application: publication of a patent application or of a certificate of addition of invention|
    2018-06-05| B11A| Dismissal acc. art.33 of ipl - examination not requested within 36 months of filing|
    2018-08-21| B11Y| Definitive dismissal acc. article 33 of ipl - extension of time limit for request of examination expired|
    优先权:
    申请号 | 申请日 | 专利标题
    US201462002204P| true| 2014-05-23|2014-05-23|
    US62/002,204|2014-05-23|
    US201462002947P| true| 2014-05-26|2014-05-26|
    US62/002,947|2014-05-26|
    EP14175145.3|2014-07-01|
    EP14175145.3A|EP2962568A1|2014-07-01|2014-07-01|Mixtures comprising a bacillus amyliquefaciens ssp. plantarum strain and a pesticide|
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